Synthesis and Characterization of Novel Nanoparticles of Lithium Aluminum Iodate LiAl(IO3)4, and DFT Calculations of the Crystal Structure and Physical Properties

Here we report on the non-hydrothermal aqueous synthesis and characterization of nanocrystalline lithium aluminum iodate, LiAl(IO3)4. Morphological and compositional analyses were carried out by using scanning electron microscopy (SEM) and energy-dispersive X-ray measurements (EDX). The optical and vibrational properties of LiAl(IO3)4 have been studied by UV-Vis and IR spectroscopy. LiAl(IO3)4 is found to crystallize in the non-centrosymmetric, monoclinic P21 space group, contrary to what was reported previously. Theoretical simulations and Rietveld refinements of crystal structure support this finding, together with the relatively high Second Harmonic Generation (SGH) response that was observed. Electronic band structure calculations show that LiAl(IO3)4 crystal has an indirect band gap Egap=3.68 eV, in agreement with the experimental optical band gap Egap=3.433 eV. The complex relative permittivity and the refraction index of LiAl(IO3)4 have also been calculated as a function of energy, as well as its elastic constants and mechanical parameters. LiAl(IO3)4 is found to be a very compressible and ductile material. Our findings imply that LiAl(IO3)4 is a promising material for optoelectronic and non -linear optical applications.

Numerical Investigations on the Damage Behaviour of a Reconstructed Anode for Solid Oxide Fuel Cell Application

This paper addresses the damage behaviour of a nickel/yttria-stabilised zirconia (Ni-YSZ) anode, in order to understand microstructural degradation processes of Solid Oxide Fuel Cells (SOFCs) during long-term operation. Numerical investigations are carried out to analyse the failure mechanisms in detail. For this purpose, finite element (FE) models are generated from focused ion beam-scanning electron microscopy 3D image data, representing the anode microstructure with varying phase compositions. A brittle model and a ductile material model were assigned to the YSZ phase and the nickel phase, respectively. The porosity is found to affect the strength of the microstructure significantly, leading to low compressive strength results. A high Ni content generally increases the toughness of the overall structure. However, the orientation and the geometry of the nickel phase is essential. When the Ni phase is aligned parallel to the loading direction, a supporting effect on the microstructure is observed, resulting in a significant high toughness. On the contrary, a rapid failure of the sample occurs when the Ni phase is oriented perpendicular to the loading direction. Two main failure mechanisms are identified: (i) cracking at the Ni/YSZ interface and (ii) cracking of struts at the location of the smallest diameter.

Effect of Layer Thickness on the Physical and Mechanical Properties of Sand Powder 3D Printing Specimens

The application of sand powder three-dimensional (3D) printing technology in the field of rock mechanics and mining engineering has tremendous potential, but it is still in the preliminary exploration stage. This study investigated the effect of printing layer thickness on the physical and mechanical properties of rock-like specimens with sand powder 3D printing. Quartz sand powder was used as the printing material, and the specimens were prepared with three different layer thicknesses of 0.2, 0.3, and 0.4 mm. Uniaxial compression tests with a combination of digital image correlation (DIC), acoustic emission (AE) and 3D microscope observations were performed to analyze the mechanical properties and failure patterns of the specimens during loading. Experimental findings showed that increasing the layer thickness from 0.2 to 0.4 mm would result in a decrease in the weight, density, uniaxial compression strength, and elastic modulus of the specimens. The stress-strain curve, deformation and failure patterns, crack growth process, and AE characteristics of the specimens with a layer thickness of 0.2 mm are similar to the AE characteristics of rock-like material, whereas the specimens with layer thicknesses of 0.3 and 0.4 mm deform like a ductile material, which is not appropriate for simulation of coal or rock mass. In future studies, rock-like specimens should be prepared with a small layer thickness.

Evaluation of Testing Uncertainties for the Impact Resistance of Machine Guards

Machine guards provide protection against ejection of parts during operation, such as chips or workpiece fragments. They are considered safe if the impact resistance is at least as high as the resulting projectile energy in the worst case of damage. To protect the machine operator, the impact resistance of machine guards is determined according to ISO standards. The bisection method can be used to determine the impact resistance through impact tests. However, this method is inaccurate for a small number of impact tests and does not provide an indication of uncertainties in the determination. Moreover, the result of testing is validated in different ways depending from the standard utilized for testing.Relevant uncertainties affecting impact testing and a new probabilistic approach for assessing the impact resistance using the Recht & Ipson equation are presented. With multiple impact tests at different initial velocities a Recht & Ipson best-fit curve and a confidence interval for a ballistic limit can be obtained, which is used to determine the impact resistance by defining a velocity reduction coefficient. This method can be applied to any machine guard made of ductile material. This paper validates the Recht & Ipson method by performing impact tests with a standardized 2.5 kg projectile on polycarbonate sheets of different thicknesses. Determination of the ballistic limit showed good agreement with experimental results. With the ballistic limits, the velocity reduction coefficients have been found to determine the impact resistances. Therefore, an alternative method for standardized tests to determine the impact resistance was found.

Study of the Effect of Plastic Waste Fibers Incorporation on the Behavior of Self Compacting Concrete

The use of waste and by-products has been for many decades for the manufacturing of building materials such as concrete and mortars. That responds simultaneously to reasons of economy of natural resources in aggregates (C&D waste) and the possibility of recovering industrial waste additions as replacement in composites. The present study focuses on the use of plastic waste fibers embedded in the cement matrix of self-compacting concrete SCC to improve its properties, either rheological mainly, the stability at fresh state or mechanical responses such as compressive and tensile strengths at hard state. This incorporation of plastic fiber reinforcement on the structure matrix could result an alternative SCC composite as a ductile material with enhanced properties. In this context, the self-compacting composites by adding a variable percentage of plastic fibers at 0.5, 1, 1.5% is formulated. Hence, the effect of plastic fibers waste on the rheological and mechanical properties of SCC is assessed. The obtained results in the present study let us to conclude the beneficial effect of such inclusion of plastic fibers on this new confected SCC fiber composition with acceptable rheological, physical and mechanical properties compared to those of a normal SCC concrete.

Microseepage through Evaporite Sequences – a Gulf of Suez Example

Salt is one of the most effective agents for trapping oil and gas. As a ductile material it can move and deform surrounding sediments and create traps. However, effective sealing of reservoirs for movement of hydrocarbons along breaching faults or fracture swarms (i.e. macroseepage) is a completely different mechanism than the molecular movement of hydrocarbons through grain boundaries and microfractures as found in microseepage. Forum Exploration chose to evaluate the applicability of passive surface geochemistry for mapping hydrocarbons in their onshore West Gebel El Zeit lease due to difficulties in seismic imaging through salt and anhydrites sequences. Two economic producing wells had been drilled in the lease, but due to compartmentalization and complexity in the area, three dry wells had also been drilled. Target formations included the Kareem Formation at ∼2,700 m and the Rudeis Formation at ∼3,000 m.The geochemical survey encompassed 100 passive geochemical modules. Passive samplers were also deployed around two producing wells and one dry well. Calibration data generated positive thermogenic signatures around the two producing wells in contrast to the background or baseline signature developed around the dry well. The Rudeis Formation calibration signature ranged from ∼nC5 - ∼nC9 while the Kareem Formation calibration signature ranged from ∼nC6 – nC12. This suggested the Rudeis calibration signature was lighter than the Kareem. This correlated with independent API gravity testing on produced oil samples (41o API gravity oil for the Rudeis, 35o API gravity oil for the Kareem).A post-survey well, Fh85-8, was drilled based on combined geochemical and seismic data results. The well was an oil discovery, with initial production of 800 BOPD. The evidence presented in this Gulf of Suez example shows that microseepage can occur through salt sequences. As such, ultrasensitive passive surface geochemical surveys provide a powerful tool for derisking salt plays.

The effects of heterogeneous mechanical properties on the response of a ductile material

We investigate numerically the small-strain, elastic–plastic response of statistically isotropic materials with non-uniform spatial distributions of mechanical properties. The numerical predictions are compared to simple bounds derived analytically. We explore systematically the effects of heterogeneity on the macroscopic stiffness, strength, asymmetry, stability and size dependence. Monte Carlo analyses of the response of statistical volume elements are conducted at different strain triaxiality using computational homogenisation, and allow exploring the macroscopic yield behaviour of the heterogeneous material. We illustrate quantitatively how the pressure-sensitivity of the yield surface of the solid increases with heterogeneity in the elastic response. We use the simple analytical models developed here to derive an approximate scaling law linking the fatigue endurance threshold of metallic alloys to their stiffness, yield strength and tensile strength.

The Effect of Dialkyl Peroxide Crosslinking on the Properties of LLDPE and UHMWPE

Peroxide has been considered a chemical agent that can be used to tune the properties of polymeric materials. This research evaluated the influence of different concentrations of dialkyl peroxides on the mechanical, thermal, and morphological properties of linear low-density polyethylene (LLDPE) and ultra-high molecular weight polyethylene (UHMWPE). The neat polymer, as well as those with the addition of 1% and 2% by mass of dialkyl peroxides, were subjected to compression molding and immersion in water for 1 h, under controlled temperatures of 90 °C. The values of the gel content found in the samples indicated that the addition of peroxide to the LLDPE and to the UHMWPE promoted the formation of a reticulated network. The structure obtained by the crosslinking led to less reorganization of the chains during the crystallization process, resulting in the formation of imperfect crystals and, consequently, in the reduction in melting temperatures, crystallization and enthalpy. The mechanical properties were altered with the presence of the crosslinker. The polymers presented had predominant characteristics of a ductile material, with the occurrence of crazing with an increased peroxide content.

Green Ceramic Machining: Determination of the Recommended Feed Rate for Y-TZP Milling

Manufacturing of advanced ceramic parts exhibiting complex geometries is laborious and expensive. Traditionally, the machining is carried out on a so-called ‘green ceramic’: a compact composed of ceramic powder held with the help of a binder. This difficulty is due not only to the composition of the material, but also to the lack of methods that determine optimal machining parameters. The goal of this paper is to apply the method based on ductile material behavior to determine a feed rate working range to ensure a machining quality. Indeed, a previous study demonstrated the limits of this method in determining cutting speed. In this case, two material removal mechanisms are observed: a mechanism dominated by pulling of the material and a proper machining mechanism. This demonstrates that the specific cutting energy is a reliable indicator for machining quality assessment. In the studied case, the recommended machining parameters to ensure quality machining of Y-TZP green ceramic with a 3 mm diameter cylindrical tool are: a cutting speed of 250 m/min, a feed per tooth of 0.037 mm/tooth, an axial depth of cut of 0.7 mm, and a radial depth of cut of 3 mm.