Reversible Energy Storage in Layered Copper-Based Coordination Polymers: Unveiling the Influence of the Ligand’s Functional Group on Their Electrochemical Properties

2020 ◽  
Vol 124 (17) ◽  
pp. 9215-9224 ◽  
Author(s):  
Marco Amores ◽  
Keisuke Wada ◽  
Ken Sakaushi ◽  
Hiroshi Nishihara
Keyword(s):  
Energy Storage ◽  
Electrochemical Properties ◽  
Coordination Polymers ◽  
Functional Group

scholarly journals Reversible Energy Storage in Layered Copper-Based Coordination Polymers: Unveiling the Influence of the Ligand's Functional Group on Their Electrochemical Properties

2020 ◽  
Author(s):  
Marco Amores ◽  
Keisuke Wada ◽  
Ken Sakaushi ◽  
Hiroshi Nishihara
Keyword(s):  
Energy Storage ◽  
Electrochemical Properties ◽  
Coordination Polymers ◽  
Electrode Materials ◽  
Ex Situ ◽  
Suitable Model ◽  
Open Structures ◽  
Improved Performance ◽  
Multielectron Transfer ◽  
Structure Properties

Coordination polymers represent a suitable model to study redox mechanisms in materials where both metal cation and ligand undergo electrochemical reactions and are capable to proceed through reversible multielectron-transfer processes with insertion of cation and anion into their open structures. Designing new coordination polymers for electrochemical energy storage with improved performance relays also on the understanding of their structure-properties relationship. Here, we present a family of copper-based coordination polymer with hexafunctionalized benzene ligands forming a kagome-type layered structure, where the in uence of the functional groups in their structure and electrochemical properties is investigated. Their chemical and structural properties have been explored by means of PXRD, and FTIR and Raman spectroscopies, followed by investigation of their electrochemical performance in Li half-cells by CV and galvanostatic cycling techniques. Ex-situ PXRD, Raman, XPS and ToF-SIMS measurements of cycled electrodes have been carried out providing insights into the redox mechanism of these copper-based coordination polymers as positive electrode materials.<br>

scholarly journals Reversible Energy Storage in Layered Copper-Based Coordination Polymers: Unveiling the Influence of the Ligand's Functional Group on Their Electrochemical Properties

2020 ◽  
Author(s):  
Marco Amores ◽  
Keisuke Wada ◽  
Ken Sakaushi ◽  
Hiroshi Nishihara
Keyword(s):  
Energy Storage ◽  
Electrochemical Properties ◽  
Coordination Polymers ◽  
Electrode Materials ◽  
Ex Situ ◽  
Suitable Model ◽  
Open Structures ◽  
Improved Performance ◽  
Multielectron Transfer ◽  
Structure Properties

Coordination polymers represent a suitable model to study redox mechanisms in materials where both metal cation and ligand undergo electrochemical reactions and are capable to proceed through reversible multielectron-transfer processes with insertion of cation and anion into their open structures. Designing new coordination polymers for electrochemical energy storage with improved performance relays also on the understanding of their structure-properties relationship. Here, we present a family of copper-based coordination polymer with hexafunctionalized benzene ligands forming a kagome-type layered structure, where the in uence of the functional groups in their structure and electrochemical properties is investigated. Their chemical and structural properties have been explored by means of PXRD, and FTIR and Raman spectroscopies, followed by investigation of their electrochemical performance in Li half-cells by CV and galvanostatic cycling techniques. Ex-situ PXRD, Raman, XPS and ToF-SIMS measurements of cycled electrodes have been carried out providing insights into the redox mechanism of these copper-based coordination polymers as positive electrode materials.<br>

Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide

2021 ◽  
Author(s):  
Patrick Nimax ◽  
Nils Rotthowe ◽  
Florian Zoller ◽  
Tobias Blockhaus ◽  
Friedrich Ernst Wagner ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Mössbauer Spectroscopy ◽  
Electrochemical Properties ◽  
Coordination Polymers ◽  
Mossbauer Spectroscopy ◽  
Complex Compounds ◽  
Electrochemical Methods ◽  
Mößbauer Spectroscopy

Compounds of the 5-amino- (ATCC) and 5-nitro-1,2,3,4-tetracyanocyclopentadienide (NTCC) ligand with iron(II) and iron(III), silver(I) and potassium(I) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mößbauer spectroscopy...

Shock Waves Induced Enhancement of Electrochemical Properties of CoFe2O4 Nanoparticles for Energy Storage Applications

2021 ◽  
pp. 101539
Author(s):  
A. Sivakumar ◽  
S. Sahaya Jude Dhas ◽  
Abdulrahman I. Almansour ◽  
Raju Suresh Kumar ◽  
Natarajan Arumugam ◽  
...  
Keyword(s):  
Energy Storage ◽  
Shock Waves ◽  
Electrochemical Properties ◽  
Cofe2o4 Nanoparticles ◽  
Energy Storage Applications

Viologens: A versatile organic molecule for energy storage applications

2021 ◽  
Author(s):  
Kathiresan Murugavel ◽  
Ambrose Bebin ◽  
Angu Lakhsmi Natarajan ◽  
Deepa Elizabeth Mathew ◽  
D Sujatha ◽  
...  
Keyword(s):  
Energy Storage ◽  
Electrochemical Properties ◽  
Organic Molecule ◽  
Structural Diversity ◽  
Fine Tuning ◽  
Active Materials ◽  
Energy Storage Applications ◽  
Molecular Tailoring

Organic redox compounds illustrate to be a fascinating class of active materials in energy-storage applications. The structural diversity as well as molecular tailoring helps in fine-tuning of the electrochemical properties...

Hexylsulfanyl-substituted CoPc and GO-CoPc on Ni foam as electroactive material for supercapacitors

2019 ◽  
Vol 23 (11n12) ◽  
pp. 1616-1621
Author(s):  
Nevin Taşaltın ◽  
Cihat Taşaltın ◽  
Hamide Aydın ◽  
Utkan Şahintürk ◽  
Ayşe Gül Gürek
Keyword(s):  
Energy Storage ◽  
Electrochemical Properties ◽  
Current Density ◽  
Ni Foam ◽  
Electroactive Material ◽  
Energy Storage Applications

For energy storage applications, hexylsulfanyl-substituted CoPc and GO-CoPc electrodes were prepared on Ni foam, and then electrochemical properties of the materials were investigated. The GO-CoPc nanocomposite electrode exhibits 56 mFcm[Formula: see text] at 1.4 mAcm[Formula: see text] current density. The results show that the GO-CoPc nanocomposite electrode is a promising electroactive material for supercapacitors.

Sign in / Sign up

Export Citation Format

Share Document