Probing the Structure of Water at the Interface with Graphene Oxide Using Sum Frequency Generation Vibrational Spectroscopy

2022 ◽  
Author(s):  
Yongming Hong ◽  
Jiali He ◽  
Cuiyun Zhang ◽  
Xinping Wang
Keyword(s):  
Graphene Oxide ◽  
Vibrational Spectroscopy ◽  
Sum Frequency Generation ◽  
Sum Frequency ◽  
Structure Of Water ◽  
Frequency Generation

Bulk Contributions Modulate the Sum-Frequency Generation Spectra of Interfacial Water on Model Sea-Spray Aerosols

2018 ◽  
Author(s):  
Sandeep K. Reddy ◽  
Raphael Thiraux ◽  
Bethany A. Wellen Rudd ◽  
Lu Lin ◽  
Tehseen Adel ◽  
...  
Keyword(s):  
Single Layer ◽  
Sum Frequency Generation ◽  
Second Order ◽  
Interfacial Structure ◽  
Sea Spray ◽  
Third Order ◽  
Systematic Analysis ◽  
Sum Frequency ◽  
Structure Of Water ◽  
Frequency Generation

Vibrational sum-frequency generation (vSFG) spectroscopy is used to determine the molecular structure of water at the interface of palmitic acid monolayers. Both measured and calculated spectra display speci c features due to third-order contributions to the vSFG response which are associated with nite interfacial electric potentials. We demonstrate that theoretical modeling enables to separate the third-order contributions, thus allowing for a systematic analysis of the strictly surface-sensitive, second-order component of the vSFG response. This study provides fundamental, molecular-level insights into the interfacial structure of water in a neutral surfactant system with relevance to single layer bio-membranes and environmentally relevant sea-spray aerosols. These results emphasize the key role that computer simulations can play in interpreting vSFG spectra and revealing microscopic details of water at complex interfaces, which can be difficult to extract from experiments due to the mixing of second-order, surface-sensitive and third-order, bulk-dependent contributions to the vSFG response.

Sum Frequency Generation Vibrational Spectroscopy of 1,3-Butadiene Hydrogenation on 4 nm Pt@SiO2, Pd@SiO2, and Rh@SiO2 Core–Shell Catalysts

Nano Letters ◽  
2014 ◽  
Vol 15 (1) ◽  
pp. 39-44 ◽  
Author(s):  
James M. Krier ◽  
William D. Michalak ◽  
Xiaojun Cai ◽  
Lindsay Carl ◽  
Kyriakos Komvopoulos ◽  
...  
Keyword(s):  
Vibrational Spectroscopy ◽  
Sum Frequency Generation ◽  
Core Shell ◽  
Sum Frequency ◽  
Frequency Generation ◽  
Butadiene Hydrogenation

Study of FeOx/Au inverse model catalysts by in situ sum frequency generation vibrational spectroscopy

2009 ◽  
Vol 96 (2) ◽  
pp. 345-356 ◽  
Author(s):  
Orsolya Hakkel ◽  
Zoltán Pászti ◽  
Tamás Keszthelyi ◽  
Krisztina Frey ◽  
László Guczi
Keyword(s):  
Vibrational Spectroscopy ◽  
Sum Frequency Generation ◽  
Inverse Model ◽  
Model Catalysts ◽  
Sum Frequency ◽  
Frequency Generation

Sum frequency generation study on the structure of water in the vicinity of an amphoteric polymer brush

2012 ◽  
Vol 91 ◽  
pp. 215-218 ◽  
Author(s):  
Takuya Kondo ◽  
Makoto Gemmei-Ide ◽  
Hiromi Kitano ◽  
Kohji Ohno ◽  
Hidenori Noguchi ◽  
...  
Keyword(s):  
Polymer Brush ◽  
Sum Frequency Generation ◽  
Sum Frequency ◽  
Structure Of Water ◽  
Frequency Generation

scholarly journals Surface-specific vibrational spectroscopy of the water/silica interface: screening and interference

2017 ◽  
Vol 19 (25) ◽  
pp. 16875-16880 ◽  
Author(s):  
Jan Schaefer ◽  
Grazia Gonella ◽  
Mischa Bonn ◽  
Ellen H. G. Backus
Keyword(s):  
Molecular Structure ◽  
Vibrational Spectroscopy ◽  
Sum Frequency Generation ◽  
Sum Frequency ◽  
Sum Frequency Generation Spectroscopy ◽  
Frequency Generation

Surface-specific vibrational sum-frequency generation spectroscopy (V-SFG) is used to obtain information about the molecular structure at charged interfaces.

Sign in / Sign up

Export Citation Format

Share Document