An External Electric Field Manipulated Second-Order Nonlinear Optical Switch of an Electride Molecule: A Long-Range Electron Transfer Forms a Lone Excess Electron Pair and Quenches Singlet Diradical

2016 ◽  
Vol 120 (25) ◽  
pp. 13656-13666 ◽  
Author(s):  
Jia-Jun Wang ◽  
Zhong-Jun Zhou ◽  
Hui-Min He ◽  
Di Wu ◽  
Ying Li ◽  
...  
RSC Advances ◽  
2019 ◽  
Vol 9 (29) ◽  
pp. 16718-16728 ◽  
Author(s):  
Bo Li ◽  
Daoling Peng ◽  
Feng Long Gu ◽  
Chaoyuan Zhu

The inorganic alkaline–earth alkalide M(NH3)6Na2 (M = Mg or Ca) can serve as a potential candidate for a nonlinear optical switch.


2021 ◽  
Author(s):  
Chu-Lin Qu ◽  
Zhong-Min Su ◽  
Feng-Wei Gao

 The present work aims to study the second-order NLO properties of m-AD and p-AD regioisomers. The βtot value of p-AD is larger than that of m-AD. Significantly, the external electric field effectively regulates the βtot values (0–3.70 × 104 a.u.) of p-AD.


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