Influence of Metal–Organic Framework Porosity on Hydrogen Generation from Nanoconfined Ammonia Borane

2017 ◽  
Vol 121 (49) ◽  
pp. 27369-27378 ◽  
Author(s):  
Jing-Yang Chung ◽  
Chi-Wei Liao ◽  
Yi-Wei Chang ◽  
Bor Kae Chang ◽  
Hao Wang ◽  
...  
Keyword(s):  
Hydrogen Generation ◽  
Metal Organic Framework ◽  
Ammonia Borane ◽  
Metal Organic ◽  
Organic Framework

Sub-3 nm Rh nanoclusters confined within a metal–organic framework for enhanced hydrogen generation

2019 ◽  
Vol 55 (32) ◽  
pp. 4699-4702 ◽  
Author(s):  
Hui Zhang ◽  
Maolin Huang ◽  
Jie Wen ◽  
Yanping Li ◽  
Airong Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Generation ◽  
Metal Organic Framework ◽  
Confinement Effect ◽  
Reduction Methods ◽  
Metal Organic ◽  
Organic Framework

Rh@UIO-66, prepared by using the double-solvent host–guest strategy and excess reduction methods, exhibited a higher catalytic activity in AB hydrolysis compared with Rh/UIO-66 because the ultrafine Rh nanoparticles were confined to UIO-66 channels. This confinement effect played a key role in enhancing the catalytic activity for AB hydrolysis.

A metal–organic framework as a chemical guide to control hydrogen desorption pathways of ammonia borane

Nanoscale ◽  
2014 ◽  
Vol 6 (12) ◽  
pp. 6526-6530 ◽  
Author(s):  
Hyung Mo Jeong ◽  
Weon Ho Shin ◽  
Jung Hyo Park ◽  
Jung Hoon Choi ◽  
Jeung Ku Kang
Keyword(s):  
Reaction Pathway ◽  
Metal Organic Framework ◽  
Ammonia Borane ◽  
Hydrogen Desorption ◽  
Metal Organic ◽  
Desorption Reaction ◽  
Improved Characteristics ◽  
Organic Framework

The ammonia borane-encapsulated metal–organic framework-5 provides improved characteristics, where the MOF-5 acts as a chemical guide to control the hydrogen desorption reaction pathway.

Metal–organic framework-derived nickel phosphides as efficient electrocatalysts toward sustainable hydrogen generation from water splitting

RSC Advances ◽  
2015 ◽  
Vol 5 (14) ◽  
pp. 10290-10295 ◽  
Author(s):  
Tian Tian ◽  
Lunhong Ai ◽  
Jing Jiang
Keyword(s):  
Water Splitting ◽  
Current Density ◽  
High Performance ◽  
Hydrogen Generation ◽  
Metal Organic Framework ◽  
Cathodic Current Density ◽  
Cathodic Current ◽  
Nickel Phosphides ◽  
Metal Organic ◽  
Organic Framework

Ni-based metal–organic framework (MOF)-derived Ni2P nanoparticles exhibited high-performance for electrochemical HER, as manifested by a low overpotential and a large cathodic current density.

Design of metal-organic framework-based photocatalysts for hydrogen generation

2020 ◽  
Vol 413 ◽  
pp. 213266 ◽  
Author(s):  
Shengjun Liu ◽  
Cheng Zhang ◽  
Yudie Sun ◽  
Qian Chen ◽  
Lifang He ◽  
...  
Keyword(s):  
Hydrogen Generation ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Novel stable metal–organic framework photocatalyst for light-driven hydrogen production

CrystEngComm ◽  
2018 ◽  
Vol 20 (23) ◽  
pp. 3228-3233 ◽  
Author(s):  
Qi Yu ◽  
Hong Dong ◽  
Xin Zhang ◽  
Ya-Xin Zhu ◽  
Jian-Hui Wang ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Hydrogen Production ◽  
Hydrogen Generation ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

A novel stable Dye-based Dy-MOF exhibits efficient photocatalytic activity for hydrogen generation.

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