New Insights into Decoupled Cation and Anion Transport and Dynamic Heterogeneity in a Diethyl(methyl)(isobutyl)phosphonium Hexafluorophosphate Organic Ionic Plastic Crystal

2021 ◽  
pp. 9853-9858
Author(s):  
Haijin Zhu ◽  
Gongyue Huang ◽  
Luke A. O’Dell ◽  
Maria Forsyth
Keyword(s):  
Anion Transport ◽  
Plastic Crystal ◽  
Methyl Isobutyl ◽  
Dynamic Heterogeneity

Structure and Transport Properties of a Plastic Crystal Ion Conductor: Diethyl(methyl)(isobutyl)phosphonium Hexafluorophosphate

2012 ◽  
Vol 134 (23) ◽  
pp. 9688-9697 ◽  
Author(s):  
Liyu Jin ◽  
Kate M. Nairn ◽  
Craig M. Forsyth ◽  
Aaron J. Seeber ◽  
Douglas R. MacFarlane ◽  
...  
Keyword(s):  
Transport Properties ◽  
Plastic Crystal ◽  
Methyl Isobutyl ◽  
Ion Conductor

scholarly journals Cation and Anion Transport in a Dicationic Imidazolium-Based Plastic Crystal Ion Conductor

2014 ◽  
pp. 140218100421006 ◽  
Author(s):  
Bryce E. Kidd ◽  
Mark D. Lingwood ◽  
Minjae Lee ◽  
Harry W. Gibson ◽  
Louis A. Madsen
Keyword(s):  
Anion Transport ◽  
Plastic Crystal ◽  
Ion Conductor

The Effects of Vacancies and their Mobility on the Dynamic Heterogeneity in 1,3-Dimethylimidazolium Hexafluorophosphate Organic Ionic Plastic Crystal

2021 ◽  
Author(s):  
Hyungshick Park ◽  
Chung Bin Park ◽  
Bong June Sung
Keyword(s):  
Long Range ◽  
Plastic Crystal ◽  
Dynamic Heterogeneity ◽  
Plastic Crystals ◽  
Solid Phases ◽  
Translational Order

Organic ionic plastic crystals (OIPCs) are the crystals of electrolytes with a long-range translational order. The rotational modes of ions in OIPCs are, however, activated even in solid phases such...

Determination of Some Nitrophenols by Atomic Absorption Spectrometry (AAS) After Extraction of Ionic Associates Involving the Bipyridylocopper(II) or Phenanthrolinocopper(II) Complex

1994 ◽  
Vol 59 (10) ◽  
pp. 2227-2234 ◽  
Author(s):  
Václav Stužka ◽  
Jaromír Souček
Keyword(s):  
Molecular Weight ◽  
Atomic Absorption Spectrometry ◽  
Atomic Absorption ◽  
Methyl Isobutyl Ketone ◽  
Absorption Spectrometry ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
Indirect Determination ◽  
Ionic Associates

A new method has been developed for the indirect determination of nitroso- and nitrophenols by atomic absorption spectrometry (AAS) after extraction of ionic associates involving bipyridylocopper(II) (CuDP) or phenanthrolinocopper(II) (CuPH) complexes. Nitrobenzene and methyl isobutyl ketone appeared to be suitable for the extraction. It was possible to determine several tenths to hundredths of a milligram of nitrophenol in a litre. Extractable associates with CuDP and CuPH are formed by phenols possessing two substituents or by higher molecular weight phenols such as naphthol or hydroxyquinoline. Monosubstituted phenols fail to form associates of this kind.

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