Highly Efficient Organic Room-Temperature Phosphorescent Luminophores through Tuning Triplet States and Spin–Orbit Coupling with Incorporation of a Secondary Group

2019 ◽  
Vol 10 (22) ◽  
pp. 7141-7147 ◽  
Author(s):  
Bowen Li ◽  
Yanbin Gong ◽  
Lu Wang ◽  
Hang Lin ◽  
Qianqian Li ◽  
...  
2018 ◽  
Vol 2 (10) ◽  
pp. 1853-1858 ◽  
Author(s):  
Haichao Liu ◽  
Yu Gao ◽  
Jungang Cao ◽  
Tingxuan Li ◽  
Yating Wen ◽  
...  

A novel mechanism of folding-induced spin–orbit coupling enhancement is responsible for the efficient room temperature phosphorescence of a thianthrene emitter.


2021 ◽  
Vol 127 (4) ◽  
Author(s):  
Josep Ingla-Aynés ◽  
Franz Herling ◽  
Jaroslav Fabian ◽  
Luis E. Hueso ◽  
Fèlix Casanova

2020 ◽  
Vol 34 (19n20) ◽  
pp. 2040058
Author(s):  
A. Kregar ◽  
A. Ramšak

The spin-sensitive charge oscillation, controlled by an external magnetic field, was recently proposed as a mechanism of transformations of qubits, defined as two-electron spin-charge Wannier molecules in a square quantum dot.1 The paper expands this idea by including the effects of Rashba-type spin-orbit coupling. The problem is studied theoretically by mapping the system to an analytic effective Hamiltonian for 8 low-energy states, comprising singlet and triplet on each dot diagonal. The validity of mapping is confirmed by comparing the energy and spin of full and mapped system, and also by the reproduction of charge-oscillation dynamics in the presence of magnetic flux. The newly introduced Rashba coupling significantly enriches the system dynamics, affecting the magnitude of charge oscillations and allowing the controlled transitions between singlet and triplet states due to the spin rotations, induced by spin-orbit coupling. The results indicate the possibility for use of the studied system for quantum information processing, while possible extensions of the system to serve as a qubit in a universal quantum computer, fulfilling all five Di Vincenzo criteria, is also discussed.


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