Heavy Water Enables High-Voltage Aqueous Electrochemistry via the Deuterium Isotope Effect

2019 ◽  
Vol 11 (1) ◽  
pp. 303-310 ◽  
Author(s):  
Shengying Cai ◽  
Tianwen Bai ◽  
Hao Chen ◽  
Wenzhang Fang ◽  
Zhen Xu ◽  
...  
Keyword(s):  
Isotope Effect ◽  
Heavy Water ◽  
High Voltage ◽  
Deuterium Isotope Effect ◽  
Aqueous Electrochemistry

Notizen: Solvent Deuterium Isotope Effect on Hydrolysis of Nd3+ Ion

1977 ◽  
Vol 32 (12) ◽  
pp. 1493-1495 ◽  
Author(s):  
Masunobu Maeda ◽  
Toshihiko Amaya ◽  
Hidetake Kaeihana
Keyword(s):  
Isotope Effect ◽  
Heavy Water ◽  
Formation Constant ◽  
Water System ◽  
Glass Electrode ◽  
Mononuclear Complex ◽  
Deuterium Isotope Effect ◽  
Light Water ◽  
Water Solutions ◽  
Hydrolysis Of

The hydrolysis equilibria of Nd3+ ion in light- and heavy-water solutions containing 3 mol dm-3 (Li)ClO4 as an ionic medium were studied at 25 °C by measuring the lyoniumion concentration with a glass electrode. Analysis of the emf data indicated the formation of only the mononuclear complex Nd(OL)2+ in both light and heavy water. The formation constant *β2,1 was smaller in D2O (log *β2,1 = —16.54 ± 0.04) than in H2O (log *β2,1 = —15.90 ± 0.06). The formation constant K2,1 for the heavy-water system (log K2,1 = 12.28) had a larger value than that for the light-water system (log K2,1 = 11.86).

Partial kinetic ‘resolution’ resulting from a deuterium isotope effect

1991 ◽  
Vol 0 (12) ◽  
pp. 801-802 ◽  
Author(s):  
Panayiotis Anastasis ◽  
Raymond Duffin ◽  
Christopher Gilmore ◽  
Karl Overton
Keyword(s):  
Isotope Effect ◽  
Kinetic Resolution ◽  
Deuterium Isotope Effect

Deuterium isotope effect in the interaction of N-nitrosodimethylamine, ethanol, and related compounds with cytochrome P-450IIE1

1991 ◽  
Vol 4 (4) ◽  
pp. 408-413 ◽  
Author(s):  
Chung S. Yang ◽  
Hiroyuki Ishizaki ◽  
Maojung Lee ◽  
Addi Fadel ◽  
David Wade
Keyword(s):  
Isotope Effect ◽  
Deuterium Isotope Effect ◽  
Related Compounds
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