scholarly journals Chain Alignment of a Rigid Ring Polymer in the Lyotropic Liquid Crystal Phase: Cyclic Amylose Tris(n-butylcarbamate) in Tetrahydrofuran and Ethyl Lactate

2021 ◽  
Author(s):  
Daigo Kabata ◽  
Akiyuki Ryoki ◽  
Shinichi Kitamura ◽  
Ken Terao
Soft Matter ◽  
2019 ◽  
Vol 15 (22) ◽  
pp. 4460-4466
Author(s):  
Weiheng Huang ◽  
Shenghui Wei ◽  
Daan Frenkel ◽  
Ningdong Huang

In situ investigations on the formation of a lyotropic liquid crystal phase through supramolecular assembly in solution suggest a multi-step pathway.


Langmuir ◽  
1993 ◽  
Vol 9 (11) ◽  
pp. 2789-2798 ◽  
Author(s):  
Randal M. Hill ◽  
Mengtao He ◽  
Zuchen Lin ◽  
H. Ted Davis ◽  
L. E. Scriven

1991 ◽  
Vol 227 ◽  
Author(s):  
Stephen Z. D. Cheng ◽  
Fred E. Arnold ◽  
Mark Eashoo ◽  
Song-Koo Lee ◽  
Steve L. C. Hsu ◽  
...  

ABSTRACTOrgano-soluble rigid-rod and segmented rigid-rod polyimides and their copolyimides exhibit isotropic solutions in hot m-cresol, but form gels upon cooling. A lyotropic liquid crystal phase is observed below the gel/sol transition. Mechanical gel formation is caused by liquid-liquid phase separation, while the liquid crystal phase may be formed through a nucleation process after gelation. High performance fibers can be spun from the hot isotropic solutions using a dry-jet wet spinning method. After the fibers are drawn at high temperatures, they display tensile strength higher than 3.2 GPa and an initial modulus higher than 130 GPa. In particular, the fibers retain relatively high mechanical properties at elevated temperatures. Solution casted films exhibit very low thermal expansion coefficients and dielectric constants. Their structure, morphology and property relationships will also be discussed.


1994 ◽  
Vol 15 (5) ◽  
pp. 575-590
Author(s):  
A. Zheliaskova ◽  
A. Derzhanski ◽  
G. Degovics ◽  
P. Laggner

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