LaNiO3 Perovskite Synthesis through the EDTA–Citrate Complexing Method and Its Application to CO Oxidation

A series of LaNiO3 materials were synthesized by the EDTA–citrate complexing method, modifying different physicochemical conditions. The LaNiO3 samples were calcined between 600 and 800 °C and characterized by XRD, SEM, XPS, CO-TPD, TG, DT, and N2 adsorption. The results evidence that although all the samples presented the same crystal phase, LaNiO3 as expected, some microstructural and superficial features varied as a function of the calcination temperature. Then, LaNiO3 samples were tested as catalysts of the CO oxidation process, a reaction never thoroughly analyzed employing this material. The catalytic results showed that LaNiO3 samples calcined at temperatures of 600 and 700 °C reached complete CO conversions at ~240 °C, while the sample thermally treated at 800 °C only achieved a 100% of CO conversion at temperatures higher than 300 °C. DRIFTS and XRD were used for studying the reaction mechanism and the catalysts’ structural stability, respectively. Finally, the obtained results were compared with different Ni-containing materials used in the same catalytic process, establishing that LaNiO3 has adequate properties for the CO oxidation process.

Probing a Microviscosity Change at the Nematic-Isotropic Liquid Crystal Phase Transition by a Ratiometric Flapping Fluorophore

Understanding the microviscosity of soft condensed matter is important to clarify the mechanisms of chemical, physical or biological events occurring at the nanoscale. Here, we report that flapping fluorophores (FLAP)...

Crystal phase-selective synthesis of intermetallic palladium borides and phase-regulated (electro)catalytic properties

Three crystal phases of Pd-B intermetallics, including Pd6B, Pd5B2 and Pd2B, are synthesized, and their phase-dependent catalytic activities toward electrochemical water splitting and Suzuki coupling reaction are studied. In both...

One-pot hydrothermal synthesis of CuBi2O4/BiOCl p-n heterojunction with enhanced photocatalytic performance for the degradation of tetracycline hydrochloride under visible light irradiation

In our part, we synthesized the CuBi2O4/ BiOCl p-n heterojunction photocatalyst by convenient one-pot hydrothermal method. And the morphology, crystal phase, element composition and optical properties of as-synthesized CuBi2O4/BiOCl were...