Fluorous Gradient Copolymers via in-Situ Transesterification of a Perfluoromethacrylate in Tandem Living Radical Polymerization: Precision Synthesis and Physical Properties

2018 ◽  
Vol 51 (3) ◽  
pp. 864-871 ◽  
Author(s):  
Yusuke Ogura ◽  
Mikihito Takenaka ◽  
Mitsuo Sawamoto ◽  
Takaya Terashima
Keyword(s):  
Physical Properties ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
In Situ Transesterification ◽  
Gradient Copolymers ◽  
Precision Synthesis

Synthesis of fluorinated gradient copolymers via in situ transesterification with fluoroalcohols in tandem living radical polymerization

2017 ◽  
Vol 8 (15) ◽  
pp. 2299-2308 ◽  
Author(s):  
Yusuke Ogura ◽  
Takaya Terashima ◽  
Mitsuo Sawamoto
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Titanium Alkoxide ◽  
Tandem Catalysis ◽  
In Situ Transesterification ◽  
Gradient Copolymers

Fluorinated gradient copolymers were synthesized by the tandem catalysis of ruthenium-catalyzed living radical polymerization and titanium alkoxide-mediated transesterification of methyl methacrylate (MMA) with fluoroalcohols.

Sequence-Regulated Copolymers via Tandem Catalysis of Living Radical Polymerization and In Situ Transesterification

2012 ◽  
Vol 134 (9) ◽  
pp. 4373-4383 ◽  
Author(s):  
Kazuhiro Nakatani ◽  
Yusuke Ogura ◽  
Yuta Koda ◽  
Takaya Terashima ◽  
Mitsuo Sawamoto
Keyword(s):  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Tandem Catalysis ◽  
In Situ Transesterification

scholarly journals One-pot synthesis for gradient copolymers via concurrent tandem living radical polymerization: mild and selective transesterification of methyl acrylate through Al(acac)3 with common alcohols

RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 26049-26055
Author(s):  
Tam Thi-Thanh Huynh ◽  
Si Eun Kim ◽  
Soon Cheon Kim ◽  
Jin Chul Kim ◽  
Young Il Park ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Methyl Acrylate ◽  
Living Radical Polymerization ◽  
One Pot ◽  
Gradient Copolymers ◽  
One Pot Synthesis

The acrylate based gradient copolymers were successfully synthesized by concurrent tandem living radical polymerization using Al(acac)3 as cocatalyst with common alcohols.

scholarly journals Self-Assembly of Hydrogen-Bonding Gradient Copolymers: Sequence Control via Tandem Living Radical Polymerization with Transesterification

2017 ◽  
Vol 50 (8) ◽  
pp. 3215-3223 ◽  
Author(s):  
Yusuke Ogura ◽  
Müge Artar ◽  
Anja R. A. Palmans ◽  
Mitsuo Sawamoto ◽  
E. W. Meijer ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Radical Polymerization ◽  
Self Assembly ◽  
Living Radical Polymerization ◽  
Gradient Copolymers

Visible-light-induced living radical polymerization using in situ bromine-iodine transformation as an internal boost

2017 ◽  
Vol 8 (16) ◽  
pp. 2538-2551 ◽  
Author(s):  
Xiaodong Liu ◽  
Qinghua Xu ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
Xiulin Zhu
Keyword(s):  
Visible Light ◽  
Radical Polymerization ◽  
Living Radical Polymerization

A new visible-light-induced methodology, termed as “bromine-iodine transformation activated living radical polymerization”, was successfully established to build a “bridge” between ATRP and iodine-mediated LRP techniques.

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