Self-Assembly of Hydrogen-Bonding Gradient Copolymers: Sequence Control via Tandem Living Radical Polymerization with Transesterification

The acrylate based gradient copolymers were successfully synthesized by concurrent tandem living radical polymerization using Al(acac)3 as cocatalyst with common alcohols.

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Single chain self-assembly: preparation of α,ω-donor–acceptor chains via living radical polymerization and orthogonal conjugation

Chemical Communications ◽

10.1039/c0cc00702a ◽

2010 ◽

Vol 46 (34) ◽

pp. 6291 ◽

Cited By ~ 63

Author(s):

Ozcan Altintas ◽

Peter Gerstel ◽

Nico Dingenouts ◽

Christopher Barner-Kowollik

Keyword(s):

Radical Polymerization ◽

Self Assembly ◽

Living Radical Polymerization ◽

Single Chain ◽

Donor Acceptor

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Synchronized Tandem Catalysis of Living Radical Polymerization and Transesterification: Methacrylate Gradient Copolymers with Extremely Broad Glass Transition Temperature

ACS Macro Letters ◽

10.1021/mz400484j ◽

2013 ◽

Vol 2 (11) ◽

pp. 985-989 ◽

Cited By ~ 33

Author(s):

Yusuke Ogura ◽

Takaya Terashima ◽

Mitsuo Sawamoto

Keyword(s):

Glass Transition ◽

Transition Temperature ◽

Glass Transition Temperature ◽

Radical Polymerization ◽

Living Radical Polymerization ◽

Tandem Catalysis ◽

Gradient Copolymers

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Gradient copolymers of styrene–methyl acrylate and styrene–acrylic acid by organostibine-mediated controlled/living radical polymerization and their glass transition behaviors

Polymer Chemistry ◽

10.1039/c3py00484h ◽

2013 ◽

Vol 4 (17) ◽

pp. 4639 ◽

Cited By ~ 8

Author(s):

Jinping Zhang ◽

Jun Li ◽

Liyan Huang ◽

Zhengping Liu

Keyword(s):

Glass Transition ◽

Acrylic Acid ◽

Radical Polymerization ◽

Methyl Acrylate ◽

Living Radical Polymerization ◽

Gradient Copolymers ◽

Controlled Living Radical Polymerization

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Synthesis and application of styrene/4-hydroxystyrene gradient copolymers made by controlled radical polymerization: Compatibilization of immiscible polymer blends via hydrogen-bonding effects

Polymer ◽

10.1016/j.polymer.2006.06.030 ◽

2006 ◽

Vol 47 (16) ◽

pp. 5799-5809 ◽

Cited By ~ 59

Author(s):

Jungki Kim ◽

Hongying Zhou ◽

SonBinh T. Nguyen ◽

John M. Torkelson

Keyword(s):

Hydrogen Bonding ◽

Polymer Blends ◽

Radical Polymerization ◽

Controlled Radical Polymerization ◽

Immiscible Polymer Blends ◽

Gradient Copolymers ◽

Immiscible Polymer

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Worm-like vesicle formation by photo-controlled/living radical polymerization-induced self-assembly of amphiphilic poly(methacrylic acid)-block-poly(methyl methacrylate-random-methacrylic acid)

Colloid & Polymer Science ◽

10.1007/s00396-016-3935-2 ◽

2016 ◽

Vol 294 (11) ◽

pp. 1857-1863 ◽

Cited By ~ 6

Author(s):

Eri Yoshida

Keyword(s):

Methyl Methacrylate ◽

Radical Polymerization ◽

Methacrylic Acid ◽

Self Assembly ◽

Living Radical Polymerization ◽

Vesicle Formation ◽

Poly Methyl Methacrylate ◽

Controlled Living Radical Polymerization

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Synthesis of fluorinated gradient copolymers via in situ transesterification with fluoroalcohols in tandem living radical polymerization

Polymer Chemistry ◽

10.1039/c7py00073a ◽

2017 ◽

Vol 8 (15) ◽

pp. 2299-2308 ◽

Cited By ~ 17

Author(s):

Yusuke Ogura ◽

Takaya Terashima ◽

Mitsuo Sawamoto

Keyword(s):

Methyl Methacrylate ◽

Radical Polymerization ◽

Living Radical Polymerization ◽

Titanium Alkoxide ◽

Tandem Catalysis ◽

In Situ Transesterification ◽

Gradient Copolymers

Fluorinated gradient copolymers were synthesized by the tandem catalysis of ruthenium-catalyzed living radical polymerization and titanium alkoxide-mediated transesterification of methyl methacrylate (MMA) with fluoroalcohols.

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