Photocatalytic Transfer Hydrogenation in Water: Insight into Mechanism and Catalyst Speciation

2021 ◽  
Author(s):  
David M. Kaphan ◽  
Kelsey R. Brereton ◽  
Rachel C. Klet ◽  
Ryan J. Witzke ◽  
Alexander J. M. Miller ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Insight Into

The origin of different driving forces between O–H/N–H functional groups in metal ligand cooperation: mechanistic insight into Mn(i) catalysed transfer hydrogenation

2020 ◽  
Vol 10 (1) ◽  
pp. 169-179 ◽  
Author(s):  
Li Zhou ◽  
Datai Liu ◽  
Haiyi Lan ◽  
Xiujian Wang ◽  
Cunyuan Zhao ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Functional Groups ◽  
Driving Forces ◽  
Transfer Hydrogenation ◽  
Bifunctional Catalysts ◽  
Mechanistic Insight ◽  
Insight Into ◽  
Metal Ligand

The origin of different catalytic activity between two structurally similar Lewis basic bifunctional catalysts.

scholarly journals Insight into catalyst speciation and hydrogen co-evolution during enantioselective formic acid-driven transfer hydrogenation with bifunctional ruthenium complexes from multi-technique operando reaction monitoring

2019 ◽  
Vol 220 ◽  
pp. 45-57 ◽  
Author(s):  
Daniel B. G. Berry ◽  
Anna Codina ◽  
Ian Clegg ◽  
Catherine L. Lyall ◽  
John P. Lowe ◽  
...  
Keyword(s):  
Formic Acid ◽  
Maximum Rate ◽  
Hydrogen Transfer ◽  
Ruthenium Complexes ◽  
Transfer Hydrogenation ◽  
Reaction Monitoring ◽  
Optimal Conditions ◽  
Insight Into

Operando spectroscopy shows a transition from dehydrogenation to hydrogen transfer during the reaction, and allows measuring optimal conditions for maximum rate and efficiency.

New Insight into the Reactivity of Pyridine-Functionalized Phosphine Complexes of Ruthenium(II) with Respect to Olefin Metathesis and Transfer Hydrogenation

2008 ◽  
Vol 27 (6) ◽  
pp. 1193-1206 ◽  
Author(s):  
Emmanuelle Mothes ◽  
Stephane Sentets ◽  
Maria Asuncion Luquin ◽  
René Mathieu ◽  
Noël Lugan ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Transfer Hydrogenation ◽  
Phosphine Complexes ◽  
Insight Into

scholarly journals An Insight into Transfer Hydrogenation Reactions Catalysed by Iridium(III) Bis-N-heterocyclic Carbenes

2015 ◽  
Vol 2015 (26) ◽  
pp. 4388-4395 ◽  
Author(s):  
Nestor García ◽  
E. A. Jaseer ◽  
Julen Munarriz ◽  
Pablo J. Sanz Miguel ◽  
Victor Polo ◽  
...  
Keyword(s):  
Heterocyclic Carbenes ◽  
Transfer Hydrogenation ◽  
Hydrogenation Reactions ◽  
Insight Into

scholarly journals Mechanistic insight into the catalytic hydrogenation of nonactivated aldehydes with a Hantzsch ester in the presence of a series of organoboranes: NMR and DFT studies

RSC Advances ◽  
2019 ◽  
Vol 9 (18) ◽  
pp. 10201-10210 ◽  
Author(s):  
Go Hamasaka ◽  
Hiroaki Tsuji ◽  
Masahiro Ehara ◽  
Yasuhiro Uozumi
Keyword(s):  
Dft Calculations ◽  
Catalytic Hydrogenation ◽  
Transfer Hydrogenation ◽  
Dft Studies ◽  
Mechanistic Studies ◽  
Mechanistic Insight ◽  
Insight Into

Mechanistic studies on the organoborane-catalyzed transfer hydrogenation of nonactivated aldehydes with a Hantzsch ester as a synthetic NADPH analogue were performed by NMR experiments and DFT calculations.

Sign in / Sign up

Export Citation Format

Share Document