In Situ Generation of Regularly Ordered 2D Ultrathin Covalent Organic Framework Films for Highly Sensitive Photoelectrochemical Bioanalysis

2020 ◽  
Vol 12 (41) ◽  
pp. 47090-47098
Author(s):  
Tingting Liu ◽  
Lin Cui ◽  
Huijuan Zhao ◽  
Xiaomei Zhang

2017 ◽  
Vol 9 (15) ◽  
pp. 13785-13792 ◽  
Author(s):  
Mohitosh Bhadra ◽  
Himadri Sekhar Sasmal ◽  
Arghya Basu ◽  
Siba P. Midya ◽  
Sharath Kandambeth ◽  
...  


2020 ◽  
Author(s):  
Junxia Ren ◽  
Yaozu Liu ◽  
Xin Zhu ◽  
Yangyang Pan ◽  
Yujie Wang ◽  
...  

<p><a></a><a></a><a></a><a></a><a></a><a></a><a></a><a>The development of highly-sensitive recognition of </a><a></a><a></a><a></a><a></a><a>hazardous </a>chemicals, such as volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs), is of significant importance because of their widespread social concerns related to environment and human health. Here, we report a three-dimensional (3D) covalent organic framework (COF, termed JUC-555) bearing tetraphenylethylene (TPE) side chains as an aggregation-induced emission (AIE) fluorescence probe for sensitive molecular recognition.<a></a><a> </a>Due to the rotational restriction of TPE rotors in highly interpenetrated framework after inclusion of dimethylformamide (DMF), JUC-555 shows impressive AIE-based strong fluorescence. Meanwhile, owing to the large pore size (11.4 Å) and suitable intermolecular distance of aligned TPE (7.2 Å) in JUC-555, the obtained material demonstrates an excellent performance in the molecular recognition of hazardous chemicals, e.g., nitroaromatic explosives, PAHs, and even thiophene compounds, via a fluorescent quenching mechanism. The quenching constant (<i>K</i><sub>SV</sub>) is two orders of magnitude better than those of other fluorescence-based porous materials reported to date. This research thus opens 3D functionalized COFs as a promising identification tool for environmentally hazardous substances.</p>



2021 ◽  
Vol 628 ◽  
pp. 119216
Author(s):  
Yawen Zhang ◽  
Hanchen Ye ◽  
Dongyun Chen ◽  
Najun Li ◽  
Qingfeng Xu ◽  
...  




2020 ◽  
Vol 8 (6) ◽  
pp. 3459-3467 ◽  
Author(s):  
Zedong Zhao ◽  
Wuji Chen ◽  
Sarawoot Impeng ◽  
Mengxiong Li ◽  
Rong Wang ◽  
...  

In situ formed LiF grains are confined and evenly distributed throughout a covalent organic framework (COF) film, which exhibits cooperative effectiveness to greatly stabilize the lithium metal.



2020 ◽  
Vol 44 (35) ◽  
pp. 14922-14927
Author(s):  
Masoumeh Sarabaegi ◽  
Mahmoud Roushani ◽  
Hadi Hosseini ◽  
S. Jafar Hoseini ◽  
Mehrangiz Bahrami

Schematic presentation of the COFCNF platform for the highly sensitive detection of tyrosinamide by using a solution containing [Fe(CN)6]3−/[Fe(CN)6]4− as a redox probe.



RSC Advances ◽  
2015 ◽  
Vol 5 (112) ◽  
pp. 92573-92576 ◽  
Author(s):  
Ying Chen ◽  
Haijun Cui ◽  
Jianqi Zhang ◽  
Kun Zhao ◽  
Defang Ding ◽  
...  

An oriented photoconductive COF film was synthesized byin situgrowth method.



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