Gd-Doped Ni-Oxychloride Nanoclusters: New Nanoscale Electrocatalysts for High-Performance Water Oxidation through Surface and Structural Modification

Author(s):  
Tanveer ul Haq ◽  
Yousef Haik ◽  
Irshad Hussain ◽  
Habib ur Rehman ◽  
Tareq A. Al-Ansari
Author(s):  
Shuya Zhao ◽  
Yurui Xue ◽  
Zhongqiang Wang ◽  
Zhiqiang Zheng ◽  
Xiaoyu Luan ◽  
...  

Developing highly active, stable and low-cost electrocatalysts capable of an efficient oxygen evolution reaction (OER) is urgent and challenging.


2021 ◽  
pp. 2000896
Author(s):  
Noor‐Ul‐Ain Babar ◽  
Majad Khan ◽  
Khurram Saleem Joya

2021 ◽  
pp. 120510
Author(s):  
Shaista Ibrahim ◽  
Uzaira Rafique ◽  
Mohsin Saleem ◽  
Waheed Iqbal ◽  
Saghir Abbas ◽  
...  

2021 ◽  
Author(s):  
Luke Sibimol ◽  
Manjunath Chatti ◽  
Asha Yadav ◽  
Brittany Kerr ◽  
Jiban Kangsabanik ◽  
...  

Proton-exchange membrane water electrolysers provide many advantages for the energy-efficient production of H<sub>2</sub>, but the current technology relies on high loadings of expensive iridium at the anodes, which are often unstable in operation. To address this, the present work scrutinises the properties of antimony-metal (Co, Mn, Ni, Fe, Ru) oxides synthesised as flat thin films by a solution-based method for the oxygen evolution reaction in 0.5 M H<sub>2</sub>SO<sub>4</sub>. Among the non-noble-metal catalysts, only cobalt-antimony and manganese-antimony oxides demonstrate high stability and reasonable activity under ambient conditions, but slowly lose activity at elevated temperatures. The ruthenium-antimony system is highly active, requiring an overpotential of 0.39 ± 0.03 and 0.34 ± 0.01 V to achieve 10 mA cm<sup>-2</sup> at 24 ± 2 and 80 °C, respectively, and remaining remarkably stable during one-week tests at 80 °C. The <i>S</i>-number for this catalyst is higher than that for the high-performance benchmark Ir-based systems. Density functional theory analysis and physical characterisation reveal that this high stability is supported by the enhanced hybridisation of the oxygen p- and metal d-orbitals induced by antimony, and can arise from two distinct structural scenarios: either formation of an antimonate phase, or nanoscale intermixing of metal and antimony oxide crystallites.


2019 ◽  
Vol 791 ◽  
pp. 1220-1230 ◽  
Author(s):  
Xiaoqiong Hao ◽  
Zhongqing Jiang ◽  
Xiaoning Tian ◽  
Xiaogang Hao ◽  
Thandavarayan Maiyalagan ◽  
...  

Small ◽  
2017 ◽  
Vol 13 (18) ◽  
pp. 1604161 ◽  
Author(s):  
Cheng-Zong Yuan ◽  
Zhong-Ti Sun ◽  
Yi-Fan Jiang ◽  
Zheng-Kun Yang ◽  
Nan Jiang ◽  
...  

2020 ◽  
Vol 30 (38) ◽  
pp. 2070252
Author(s):  
Yu‐Rim Hong ◽  
Kang Min Kim ◽  
Jeong Ho Ryu ◽  
Sungwook Mhin ◽  
Jungin Kim ◽  
...  

2019 ◽  
Vol 166 (4) ◽  
pp. A480-A486 ◽  
Author(s):  
Boya Tang ◽  
Jiang Zhou ◽  
Guozhao Fang ◽  
Shan Guo ◽  
Xun Guo ◽  
...  

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