Rational Modification of Two-Dimensional Donor–Acceptor Covalent Organic Frameworks for Enhanced Visible Light Photocatalytic Activity

Author(s):  
Chenxiang Lin ◽  
Xiaolin Liu ◽  
Baoqiu Yu ◽  
Chaozheng Han ◽  
Lei Gong ◽  
...  
2012 ◽  
Vol 476-478 ◽  
pp. 1541-1546 ◽  
Author(s):  
Yan Ming Cao ◽  
Fu Min Wang ◽  
Zhi Fang Jia ◽  
Ning Liu

A novel multilayered flower-like structure of BiOBr was fabricated by mild and facile polyvinylpyrrolidone (PVP) K30-assisted hydrothermal method using stable, less toxic inorganic salts Bi(NO3)3•5H2O and NaBr as the starting materials. Such three-dimensional (3D) BiOBr assemblies were constructed layer-by-layer from a large number of two-dimensional (2D) nanoplates. Rhodamine B (RhB) photocatalytic degradation experiments showed that the BiOBr flowers exhibited higher visible-light photocatalytic activity than that of irregular BiOBr nanoplates. Therefore, the resulting flower-like BiOBr are very promising photocatalysts for the treatment of organic pollutants


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