Moderately Crystalline Azine-Linked Covalent Organic Framework Membrane for Ultrafast Molecular Sieving

Author(s):  
Decheng Liu ◽  
Kai Li ◽  
Min Li ◽  
Zheng Wang ◽  
Meixia Shan ◽  
...  
2018 ◽  
Vol 6 (27) ◽  
pp. 13331-13339 ◽  
Author(s):  
Wenxiang Zhang ◽  
Liming Zhang ◽  
Haifeng Zhao ◽  
Bin Li ◽  
Heping Ma

A two-dimensional cationic covalent organic framework membrane with extraordinary separation properties and high permeability.


2016 ◽  
Vol 29 (2) ◽  
pp. 1603945 ◽  
Author(s):  
Sharath Kandambeth ◽  
Bishnu P. Biswal ◽  
Harshal D. Chaudhari ◽  
Kanhu Charan Rout ◽  
Shebeeb Kunjattu H. ◽  
...  

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Yang Li ◽  
Qianxun Wu ◽  
Xinghua Guo ◽  
Meicheng Zhang ◽  
Bin Chen ◽  
...  

2020 ◽  
Vol 8 (37) ◽  
pp. 19328-19336
Author(s):  
Hao Yang ◽  
Hong Wu ◽  
Yumeng Zhao ◽  
Meidi Wang ◽  
Yimeng Song ◽  
...  

Ultrathin heterostructured covalent organic framework membranes were fabricated through vapor–liquid interfacial synthesis for efficient liquid separations.


2020 ◽  
Vol 11 (21) ◽  
pp. 5434-5440 ◽  
Author(s):  
Digambar B. Shinde ◽  
Li Cao ◽  
A. D. Dinga Wonanke ◽  
Xiang Li ◽  
Sushil Kumar ◽  
...  

Pore surface engineering of ultrathin COF membranes by introducing different lengths of alkyl chains into the skeleton, which allows us to precisely control the pore size of COF membranes for OSN applications and molecular sieving.


Nanoscale ◽  
2020 ◽  
Vol 12 (30) ◽  
pp. 16136-16142
Author(s):  
Xuan Wang ◽  
Ming-Jie Dong ◽  
Chuan-De Wu

An effective strategy to incorporate accessible metalloporphyrin photoactive sites into 2D COFs by establishing a 3D local connection for highly efficient photocatalysis was developed.


2020 ◽  
Author(s):  
Junxia Ren ◽  
Yaozu Liu ◽  
Xin Zhu ◽  
Yangyang Pan ◽  
Yujie Wang ◽  
...  

<p><a></a><a></a><a></a><a></a><a></a><a></a><a></a><a>The development of highly-sensitive recognition of </a><a></a><a></a><a></a><a></a><a>hazardous </a>chemicals, such as volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs), is of significant importance because of their widespread social concerns related to environment and human health. Here, we report a three-dimensional (3D) covalent organic framework (COF, termed JUC-555) bearing tetraphenylethylene (TPE) side chains as an aggregation-induced emission (AIE) fluorescence probe for sensitive molecular recognition.<a></a><a> </a>Due to the rotational restriction of TPE rotors in highly interpenetrated framework after inclusion of dimethylformamide (DMF), JUC-555 shows impressive AIE-based strong fluorescence. Meanwhile, owing to the large pore size (11.4 Å) and suitable intermolecular distance of aligned TPE (7.2 Å) in JUC-555, the obtained material demonstrates an excellent performance in the molecular recognition of hazardous chemicals, e.g., nitroaromatic explosives, PAHs, and even thiophene compounds, via a fluorescent quenching mechanism. The quenching constant (<i>K</i><sub>SV</sub>) is two orders of magnitude better than those of other fluorescence-based porous materials reported to date. This research thus opens 3D functionalized COFs as a promising identification tool for environmentally hazardous substances.</p>


2021 ◽  
Vol 2 (7) ◽  
pp. 100495
Author(s):  
Chun-Te Kuo ◽  
Yubing Lu ◽  
Pezhman Arab ◽  
K. Shamara Weeraratne ◽  
Hani El-Kaderi ◽  
...  

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