Insights of the Electrochemical Reversibility of P2-Type Sodium Manganese Oxide Cathodes via Modulation of Transition Metal Vacancies

Author(s):  
Zhumei Xiao ◽  
Wenhua Zuo ◽  
Xiangsi Liu ◽  
Jisheng Xie ◽  
Huajin He ◽  
...  

2017 ◽  
Vol 5 (34) ◽  
pp. 18214-18220 ◽  
Author(s):  
Chao Luo ◽  
Alex Langrock ◽  
Xiulin Fan ◽  
Yujia Liang ◽  
Chunsheng Wang

Ni/Fe doping and atomic layer deposition are two effective methods to stabilize P2-type sodium manganese oxide cathodes.



2021 ◽  
Vol 481 ◽  
pp. 229010
Author(s):  
Eun Jeong Kim ◽  
Kenza Mofredj ◽  
David M. Pickup ◽  
Alan V. Chadwick ◽  
John T.S. Irvine ◽  
...  


Author(s):  
Yuexia Ling ◽  
Jiang Zhou ◽  
Shan Guo ◽  
Hongwei Fu ◽  
Yifan Zhou ◽  
...  


Author(s):  
Larisa A. Zemskova ◽  
Alexey V. Voit ◽  
Darya H. Shlyk ◽  
Nikolaiy N. Barinov

Perspectives of use of activated carbon materials modified with transition metal oxides for purification of water from arsenic were considered. Sorption isotherms for two types of hybrid sorbents based on carbon fibers modified with manganese oxide as birnessite as well as on fiber and chitosan-carbon materials on its basic modified with molybdenum determining affinity of the sorbents to arsenate-ions are presented.





2022 ◽  
Author(s):  
Caihong Shi ◽  
Liguang Wang ◽  
Xian Chen ◽  
Jun Li ◽  
Shun Wang ◽  
...  

As the most promising alternate for lithium-ion batteries (LIBs), sodium-ion batteries (SIBs) still face many issues that hinder their large-scale commercialization. Layered transition metal oxide cathodes have attracted widespread attention...



Science ◽  
2020 ◽  
Vol 370 (6516) ◽  
pp. 596-600 ◽  
Author(s):  
Xitang Qian ◽  
Long Chen ◽  
Lichang Yin ◽  
Zhibo Liu ◽  
Songfeng Pei ◽  
...  

Proton transport in nanochannels under humid conditions is crucial for the application in energy storage and conversion. However, existing materials, including Nafion, suffer from limited conductivity of up to 0.2 siemens per centimeter. We report a class of membranes assembled with two-dimensional transition-metal phosphorus trichalcogenide nanosheets, in which the transition-metal vacancies enable exceptionally high ion conductivity. A Cd0.85PS3Li0.15H0.15 membrane exhibits a proton conduction dominant conductivity of ~0.95 siemens per centimeter at 90° Celsius and 98% relative humidity. This performance mainly originates from the abundant proton donor centers, easy proton desorption, and excellent hydration of the membranes induced by cadmium vacancies. We also observed superhigh lithium ion conductivity in Cd0.85PS3Li0.3 and Mn0.77PS3Li0.46 membranes.



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