Aluminum Doping Effect on Surface Structure of Silver Ultrathin Films

Ultrathin silver films with low loss in the visible and near-infrared spectrum range have been widely used in the fields of metamaterials and optoelectronics. In this study, Al-doped silver films were prepared by the magnetron sputtering method and were characterized by surface morphology, electrical conductivity, and light transmittance analyses. Molecular dynamics simulations and first-principles density functional theory calculations were applied to study the surface morphologies and migration pathway for the formation mechanisms in Al-doped silver films. The results indicate that the migration barrier of silver on a pristine silver surface is commonly lower than that of an Al-doped surface, revealing that the aluminum atoms in the doping site decrease the surface mobility and are conducive to the formation of small islands of silver. When the islands are dense, they coalesce into a single layer, leading to a smoother surface. This might be the reason for the observably lower 3D growth mode of silver on an Al-doped silver surface. Our results with electronic structure insights on the mechanism of the Al dopants on surface morphologies might benefit the quality control of the silver thin films.

CO2 Injection Deformation Monitoring Based on UAV and InSAR Technology: A Case Study of Shizhuang Town, Shanxi Province, China

Carbon Capture, Utilization and Storage, also referred to as Carbon Capture, Utilization and Sequestration (CCUS), is one of the novel climate mitigation technologies by which CO2 emissions are captured from sources, such as fossil power generation and industrial processes, and further either reused or stored with more attention being paid on the utilization of captured CO2. In the whole CCUS process, the dominant migration pathway of CO2 after being injected underground becomes very important information to judge the possible storage status as well as one of the essential references for evaluating possible environmental affects. Interferometric Synthetic Aperture Radar (InSAR) technology, with its advantages of extensive coverage in surface deformation monitoring and all-weather traceability of the injection processes, has become one of the promising technologies frequently adopted in worldwide CCUS projects. In this study, taking the CCUS sequestration area in Shizhuang Town, Shanxi Province, China, as an example, unmanned aerial vehicle (UAV) photography measurement technology with a 3D surface model at a resolution of 5.3 cm was applied to extract the high-resolution digital elevation model (DEM) of the study site in coordination with InSAR technology to more clearly display the results of surface deformation monitoring of the CO2 injection area. A 2 km surface heaving dynamic processes before and after injection from June 2020 to July 2021 was obtained, and a CO2 migration pathway northeastward was observed, which was rather consistent with the monitoring results by logging and micro-seismic studies. Additionally, an integrated monitoring scheme, which will be the trend of monitoring in the future, is proposed in the discussion.

Edge Effect in Electronic and Transport Properties of 1D Fluorinated Graphene Materials

A systematic examination of the electronic and transport properties of 1D fluorine-saturated zigzag graphene nanoribbons (ZGNRs) is presented in this article. One publication (Withers et al., Nano Lett., 2011, 11, 3912–3916.) reported a controlled synthesis of fluorinated graphene via an electron beam, where the correlation between the conductivity of the resulting materials and the width of the fluorinated area is revealed. In order to understand the detailed transport mechanism, edge-fluorinated ZGNRs with different widths and fluorination degrees are investigated. Periodic density functional theory (DFT) is employed to determine their thermodynamic stabilities and electronic structures. The associated transport models of the selected structures are subsequently constructed. The combination of a non-equilibrium Green’s function (NEGF) and a standard Landauer equation is applied to investigate the global transport properties, such as the total current-bias voltage dependence. By projecting the corresponding lesser Green’s function on the atomic orbital basis and their spatial derivatives, the local current density maps of the selected systems are calculated. Our results suggest that specific fluorination patterns and fluorination degrees have significant impacts on conductivity. The conjugated π system is the dominate electron flux migration pathway, and the edge effect of the ZGNRs can be well observed in the local transport properties. In addition, with an asymmetric fluorination pattern, one can trigger spin-dependent transport properties, which shows its great potential for spintronics applications.

A New Mitochondrial Genome of Sogatella furcifera (Horváth) (Hemiptera: Delphacidae) and Mitogenome-Wide Investigation on Polymorphisms

White-backed planthopper (WBPH), Sogatella furcifera (Horváth), is one of the major sap-sucking rice pests in East Asia. We have determined a new complete mitochondrial genome of WBPH collected in the Korean peninsula using NGS technology. Its length and GC percentages are 16,613 bp and 23.8%, respectively. We observed one polymorphic site, a non-synonymous change, in the COX3 gene with confirmation heteroplasmy phenomenon within individuals of WBPH by PCR amplification and Sanger sequencing, the first report in this species. In addition, this heteroplasmy was not observed in wild WBPH populations, suggesting that it may be uncommon in fields. We analyzed single nucleotide polymorphisms, insertion, and deletions, and simple sequence repeats among the three WBPH mitogenomes from Korea and China and found diverse intraspecific variations, which could be potential candidates for developing markers to distinguish geographical populations. Phylogenetic analysis of 32 mitogenomes of Delphacidae including the three WBPH mitogenomes suggested that Delphacinae seems to be monophyletic and Sogatella species including WBPH are clearly formed as one clade. In the future, it is expected that complete mitogenomes of individuals of geographically dispersed WBPH populations will be used for further population genetic studies to understand the migration pathway of WBPH.

The hydrocarbon potential of the offshore Talara Basin, Peru

The offshore Talara Basin is the western extension of the hydrocarbon producing onshore fields since the mid-1800s area of Peru and is also located above the subduction zone of the active continental margin of South America. The offshore portion was evaluated using high quality 3D seismic where mapping horizons are all unconformities within the Eocene as well as the unconformities at the top Paleocene and top Cretaceous. Possible source rocks are the Cretaceous black marine shales of the Campanian Redondo Formation, the limestones of the Albian Muerto Formation, and the marine shales of the Paleogene. The primary target offshore is expected to be deep-water turbidites of Paleocene/Eocene age with a depositional source from the northeast from highlands created by the compressional uplift of the Andes. The main seals offshore are expected to be shales of the upper Eocene Lagunitos Formation and shales in the Chacra Formation, which are also seals in the onshore Litoral field. Thermal maturation modeling shows that two hydrocarbon kitchens exist in the offshore portion of the Talara basin, one in the north and one in the south. The probable Cretaceous source rocks reached the onset of maturity (VR = 0.63%) at a depth of 3,250 to 3,285 m (10,663 – 10,778 ft) between 30 and 39 Ma (Late Eocene to Oligocene). Importantly, the Cretaceous source rocks stay within the oil window once they enter it in the late Eocene. Satellite studies show a large offshore present-day oil seep in the southern part of the basin and 3D seismic shows direct hydrocarbon indicators (DHIs) imaged as flat spots and bottom simulating reflectors (BSR). Basin modeling suggests hydrocarbon migration pathways would have been updip (to the east) into the onshore traps and would therefore have first filled the offshore traps along the migration pathway. We conclude that the Talara Basin offshore offers excellent exploration opportunities in a proven productive area where multiple prospects have been mapped.

Seasonal occurrence of waterbirds in Minas Passage, Bay of Fundy, Nova Scotia, Canada, 2010 to 2012

We determined patterns of seasonal abundance and diversity of seabirds and coastal waterfowl in Minas Passage, Bay of Fundy, Nova Scotia, Canada using quantitative, shore-based point surveys from mid-March to late August and mid-October to December 2010 to 2012. This area experiences the world’s highest tides and greatest tidal currents. We showed that species and seasonal cycles of waterbirds in Minas Passage reflect patterns typical of the inner Bay of Fundy and the northeast Atlantic coast of North America. The study highlights the importance of Minas Passage as an important local migration pathway for waterbirds including Black Scoter (Melanitta americana) and Red-throated Loon (Gavia stellata) passing through the Bay of Fundy. Large numbers of sea ducks (Black Scoter, Surf Scoter [Melanitta perspicillata], White-winged Scoter (Melanitta fusca), and Long-tailed Duck [Clangula hyemalis]), and Red-throated Loon were observed at the site in spring and fall, corresponding to known peak movements elsewhere in the Bay of Fundy. Fewest species and smallest abundances of waterbirds overall occurred in summer and early winter, while most species and largest abundances occurred in April-May and early November. Of the 46 species observed, resident breeders such as Herring Gull (Larus argentatus), Great Black-backed Gull (Larus marinus), Common Eider (Somateria mollissima), Black Guillemot (Cepphus grylle), and Double-crested Cormorant (Phalacrocorax auritus), were most abundant in spring to early summer during breeding and migrants including Red-throated Loon, Black Scoter, Ring-billed Gull (Larus delawarensis), Surf Scoter, and Northern Gannet (Morus bassanus) occurred in moderate numbers during migration periods.

Genetic and demographic predictors of general reading ability in two cohorts

Reading ability is a complex skill requiring multiple proficiencies (e.g., phonological awareness, decoding, and comprehension). Reading ability has genetic and environmental components that create the potential for significant gene-gene and gene-environment interactions, but the evidence for these interactions is limited. We used data from the Avon Longitudinal Study of Parents and Children and the Genes, Reading and Dyslexia Study to assess the contributions of genetic and demographic features to a continuous latent reading ability score. We then used this score as the phenotype on which to predicate genome-wide single nucleotide polymorph screening, followed by feature selection using an elastic net analysis. Results from the elastic net models showed that genetic and demographic features predicted reading ability for both cohorts. Five single nucleotide polymorphisms were associated with latent reading in the Avon Longitudinal Study of Parents and Children, as well as in the Genes, Reading and Dyslexia cohorts. For both cohorts, larger vocabularies were positively associated with latent reading ability. Genes within the neuron migration pathway were overrepresented in the Avon Longitudinal Study of Parents and Children cohort. We provide support that genes involved in early brain development have an impact on latent reading ability performance. Our findings also indicate high generalizability of genetic findings between cohorts, using our approach.

Natal origin and migration pathways of Mekong catfish (Pangasius krempfi) using strontium isotopes and trace element concentrations in environmental water and otoliths

To improve our knowledge of the migration pathway of a highly threatened fish species along the Mekong River, strontium isotope ratios (87Sr/86Sr) and 18 trace element concentrations were measured in the water and in the otoliths of an anadromous catfish, Pangasius krempfi, to infer its natal origin and potential migration pathways. Water was sampled at 18 locations along the mainstream, tributaries and distributaries of the Mekong River. To check for accuracy and precision, measurements of the 87Sr/86Sr ratios and trace element concentrations were then compared in two laboratories that use different analytical methods. Differences in trace element concentrations between locations were not significant and could not, therefore, be used to discriminate between migration pathways. However, the Mekong mainstream, tributaries and distributaries could all be discriminated using Sr isotopes. The 87Sr/86Sr profiles recorded in P. krempfi otoliths showed that there were three contingents with obligate freshwater hatching and variable spawning sites along the Mekong mainstream, from Phnom Penh (Cambodia) to Nong Khai (Thailand) or further. After hatching, the fish migrated more or less rapidly to the Mekong Delta and then settled for most of their lifetime in brackish water. Spawning habitats and migration routes may be threatened by habitat shifts and the increasing number of hydropower dams along the river, especially the contingents born above Khone Falls (Laos). The conservation of P. krempfi, as well as other migratory fish in the Mekong River, requires agreements, common actions and management by all countries along the Mekong River. This study highlighted the importance of using both Sr/Ca and 87Sr/86Sr ratios to understand life history of anadromous fishes as the 87Sr/86Sr ratio in the water was shown to be less effective than the Sr/Ca ratio in identifying movements between different saline areas.