Large Piezoelectric Response in Lead-Free (Bi0.5Na0.5)TiO3-Based Perovskite Thin Films by Ferroelastic Domain Switching: Beyond the Morphotropic Phase Boundary Paradigm

2021 ◽  
Author(s):  
Takao Shimizu ◽  
Miyu Hasegawa ◽  
Keisuke Ishihama ◽  
Akinori Tateyama ◽  
Wakiko Yamaoka ◽  
...  
Keyword(s):  
Thin Films ◽  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Domain Switching ◽  
Lead Free ◽  
Piezoelectric Response ◽  
Boundary Paradigm

Piezoelectric Properties of Lead-Free (Na,Bi)TiO3–BaTiO3(001) Epitaxial Thin Films around the Morphotropic Phase Boundary

2010 ◽  
Vol 3 (11) ◽  
pp. 111501 ◽  
Author(s):  
Takakiyo Harigai ◽  
Yoshiaki Tanaka ◽  
Hideaki Adachi ◽  
Eiji Fujii
Keyword(s):  
Thin Films ◽  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Piezoelectric Properties ◽  
Lead Free ◽  
Epitaxial Thin Films

Optimized energy storage performances in morphotropic phase boundary (Na0.8K0.2)0.5Bi0.5TiO3-based lead-free ferroelectric thin films

2021 ◽  
Author(s):  
Jie Ding ◽  
Yiling Zhang ◽  
Yizan Zhai ◽  
Zhen Su ◽  
Jinjun Liu ◽  
...  
Keyword(s):  
Thin Films ◽  
Energy Storage ◽  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Ferroelectric Thin Films ◽  
Lead Free

Shifting of the morphotropic phase boundary and superior piezoelectric response in Nb-doped Pb(Zr,Ti)O3 epitaxial thin films

2009 ◽  
Vol 57 (14) ◽  
pp. 4288-4295 ◽  
Author(s):  
Zhi-Xiang Zhu ◽  
Jing-Feng Li ◽  
Yunya Liu ◽  
Jiangyu Li
Keyword(s):  
Thin Films ◽  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Piezoelectric Response ◽  
Epitaxial Thin Films

Hydrothermal epitaxy of lead free (Na,K)NbO3-based piezoelectric films

2013 ◽  
Vol 1547 ◽  
pp. 45-52
Author(s):  
Albertus D. Handoko ◽  
Gregory K. L. Goh
Keyword(s):  
Thin Films ◽  
Solid Solution ◽  
Phase Boundary ◽  
Hydrothermal Method ◽  
Morphotropic Phase Boundary ◽  
Solid Solutions ◽  
Lead Zirconate Titanate ◽  
Piezoelectric Properties ◽  
Lead Zirconate ◽  
Lead Free

ABSTRACTLead free niobate solid solutions can exhibit piezoelectric properties comparable to that of lead zirconate titanate piezoelectrics in the vicinity of its morphotropic phase boundary (MPB). Here we describe how (Na,K)NbO3 and (Na,K)NbO3-LiTaO3 solid solution thin films can be grown epitaxially by the hydrothermal method at temperatures of 200 °C or below in water and be made ferro- and piezoelectrically active by a simple 2 step post growth treatment.

Piezoelectric effect in epitaxial PbZr1−xTixO3 thin films near morphotropic phase boundary region

2005 ◽  
Vol 20 (4) ◽  
pp. 787-790 ◽  
Author(s):  
Yong Kwan Kim ◽  
Sang Sub Kim ◽  
Bongki Lee ◽  
Hyunjung Shin ◽  
Sunggi Baik
Keyword(s):  
Thin Films ◽  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Volume Fraction ◽  
Scanning Force Microscopy ◽  
Boundary Region ◽  
Structural Instability ◽  
Piezoelectric Response ◽  
Storage Devices ◽  
Pzt Films

The relationship between crystal structure and piezo-response was investigated in epitaxially grown PbZr1−xTixO3 (PZT) thin films on Pt(001)/MgO(001) with a thin PbTiO3 interlayer. Insertion of the interlayer resulted in significant relaxation ofthe strain that could be developed in the course of deposition of the PZT films, consequently leading us to single out only the effect of composition. Composition of the morphotropic phase boundary (MPB), at which tetragonal and rhombohedral phases are mixed with the same volume fraction, was found to be ∼0.55 in Ti/(Zr + Ti) ratio in our films, which is close to the value for bulk polycrystalline PZT (∼0.50). The piezoelectric response peaks were two times higher in the MPB regime than in the single phase regime due to structural instability caused by the coexistence of two phases. The results indicate that epitaxial PZT films having the MPB composition are advantageous over those of other compositions for nano-storage devices based on scanning force microscopy.

Evidence of morphotropic phase boundary displacement in lead-free (Bi0.5Na0.5)1−xBaxTiO3 polycrystalline thin films

2011 ◽  
Vol 65 (17-18) ◽  
pp. 2714-2716 ◽  
Author(s):  
Iñigo Bretos ◽  
David Alonso-San José ◽  
Ricardo Jiménez ◽  
Jesús Ricote ◽  
M. Lourdes Calzada
Keyword(s):  
Thin Films ◽  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Lead Free ◽  
Boundary Displacement ◽  
Polycrystalline Thin Films

Ferroelectric and piezoelectric properties of lead-free Bi0.5Na0.5TiO3–Bi0.5K0.5TiO3–BaTiO3-thin films near the morphotropic phase boundary

2014 ◽  
Vol 586 ◽  
pp. 549-554 ◽  
Author(s):  
Susant Kumar Acharya ◽  
Tae-Min Kim ◽  
Jung-Hwan Hyung ◽  
Byung-Guk Ahn ◽  
Sang-Kwon Lee
Keyword(s):  
Thin Films ◽  
Phase Boundary ◽  
Morphotropic Phase Boundary ◽  
Piezoelectric Properties ◽  
Lead Free ◽  
Ferroelectric And Piezoelectric Properties
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