Photoalignment of an Azobenzene-Based Chromonic Liquid Crystal Dispersed in Triacetyl Cellulose: Single-Layer Alignment Films with an Exceptionally High Order Parameter

2015 ◽  
Vol 7 (21) ◽  
pp. 11074-11078 ◽  
Author(s):  
Masaki Matsumori ◽  
Ayami Takahashi ◽  
Yasushi Tomioka ◽  
Takaaki Hikima ◽  
Masaki Takata ◽  
...  

2021 ◽  
pp. 1-6
Author(s):  
Xuewen Xie ◽  
Peng Huang ◽  
Miao Xu ◽  
Yunsheng Ding ◽  
Longzhen Qiu ◽  
...  


Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1262
Author(s):  
Mikhail A. Osipov ◽  
Maxim V. Gorkunov ◽  
Alexander A. Antonov

Density functional theory of rod-coil diblock copolymers, developed recently by the authors, has been generalised and used to study the liquid crystal ordering and microphase separation effects in the hexagonal, lamellar and nematic phases. The translational order parameters of rod and coil monomers and the orientational order parameters of rod-like fragments of the copolymer chains have been determined numerically by direct minimization of the free energy. The phase diagram has been derived containing the isotropic, the lamellar and the hexagonal phases which is consistent with typical experimental data. The order parameter profiles as functions of temperature and the copolymer composition have also been determined in different anisotropic phases. Finally, the spatial distributions of the density of rigid rod fragments and of the corresponding orientational order parameter in the hexagonal phase have been calculated.



2014 ◽  
Vol 22 (1) ◽  
Author(s):  
T. Devi ◽  
B. Choudhury ◽  
A. Bhattacharjee ◽  
R. Dabrowski

AbstractOptical studies have been carried out on two fluorinated isothiocyanato nematic liquid crystal (LC) compounds 4′-butylcyclohexyl-3, 5-difluoro-4-isothiocyanatobiphenyl and 4′-pentylcyclohexyl-3, 5-difluoro-4-isothiocynatobiphenyl. Transition temperatures of the two samples were confirmed using a polarizing microscope. The two LC compounds were found to exhibit fairly high clearing temperatures. Measurements of refractive indices of the two compounds were done by using thin prism method with He-Ne laser beam of wavelength 630 nm. Birefringence of the two LC compounds was calculated from the measured refractive indices. Both the compounds are found to display fairly high values of birefringence. Validation of a modified four-parameter model, based on Vuks equation describing the temperature dependence of refractive indices of the two liquid crystals, is also presented in this paper. The model is validated by fitting the experimentally measured values of refractive indices, birefringence and average refractive indices of the two nematic LCs with the theoretical values. In this paper, the calculation of order parameters of the LCs is presented by using two methods: direct extrapolation method based solely on the birefringence data and by using modified Vuks method based on Haller’s extrapolation. As observed from the obtained results, this procedure of calculating order parameter gives very reasonable results.



2021 ◽  
Author(s):  
Brandon Vreeland ◽  
Comrun Yousefzadeh ◽  
Andre van Rynbach ◽  
Douglas Bryant ◽  
Philip J. Bos




2020 ◽  
Author(s):  
Roberto Boyero-García ◽  
Óscar Zurrón-Cifuentes ◽  
Luis Plaja ◽  
Carlos Hernandez-Garcia


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