Rigidity-Induced Delayed Fluorescence by Ortho Donor-Appended Triarylboron Compounds: Record-High Efficiency in Pure Blue Fluorescent Organic Light-Emitting Diodes

2017 ◽  
Vol 9 (28) ◽  
pp. 24035-24042 ◽  
Author(s):  
Young Hoon Lee ◽  
Sunghee Park ◽  
Jihun Oh ◽  
Jong Won Shin ◽  
Jaehoon Jung ◽  
...  
Author(s):  
Jingwen Xu ◽  
Xing Wu ◽  
Jingjing Guo ◽  
Zujin Zhao ◽  
Ben Zhong Tang

In comparison with green and red OLEDs, which have well developed with satisfactory electroluminescence (EL) performances, high-efficiency blue OLEDs still need further exploration. Herein, by reasonably strengthening the rigidity of...


2021 ◽  
Author(s):  
Kenkera Naveen ◽  
Hyuna Lee ◽  
Ramanaskanda Braveenth ◽  
Durai Karthik ◽  
Ki Yang ◽  
...  

Abstract In the field of organic light emitting diodes (OLEDs), organo-boron based thermally activated delayed fluorescence (TADF) emitters have reached great achievement. However, it is still challenging to achieve pure blue color (CIE y < 0.20) along with high efficiencies. To overcome these hurdles, hyperfluorescence (HF) suggest a key strategy in future OLED applications. Here, we report two TADF materials, pMDBA-DI and mMDBA-DI. Further, a pure blue multi resonance type tert-butyl substituted fluorescence emitter, t-Bu-ν-DABNA was also synthesized. Among our synthesized TADF materials based pure blue HF devices, mMDBA-DI as TADF sensitized host with t-Bu-ν-DABNA fluorescence emitter exhibited a high external quantum efficiency of 40.7% (Lambertian assumption) along with narrow emission with full width at half maximum of 19 nm (CIE y = 0.15). Moreover, we analyzed that such high device efficiency is mainly attributed to the high orientation factor, enhanced photoluminescence quantum yield, and a good TADF characteristic of t-Bu-ν-DABNA with high Förster resonance energy transfer.


2015 ◽  
Vol 3 (43) ◽  
pp. 11385-11396 ◽  
Author(s):  
Dongxue Ding ◽  
Zhen Zhang ◽  
Ying Wei ◽  
Pengfei Yan ◽  
Hui Xu

Spatial optimization of host materials for highly efficient blue organic light-emitting diodes was rationally performed on the basis of a series of ternary and quaternary phosphine oxide materials.


2020 ◽  
Vol 8 (15) ◽  
pp. 5265-5272 ◽  
Author(s):  
Ji Han Kim ◽  
Kyung Hyung Lee ◽  
Jun Yeob Lee

Yellow thermally activated delayed fluorescence materials were synthesized using two types of acceptors of 2,4,6-triphenylpyrimidine-5-carbonitrile and 4-(3-cyanophenyl)-2,6-diphenylpyrimidine-5-carbonitrile combined with a strong donor.


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