High-Efficiency Nonfullerene Polymer Solar Cells with Band gap and Absorption Tunable Donor/Acceptor Random Copolymers

2018 ◽  
Vol 11 (2) ◽  
pp. 2189-2196 ◽  
Author(s):  
Da Hun Kim ◽  
Thi Thu Trang Bui ◽  
Shafket Rasool ◽  
Chang Eun Song ◽  
Hang Ken Lee ◽  
...  
Keyword(s):  
Solar Cells ◽  
Band Gap ◽  
High Efficiency ◽  
Polymer Solar Cells ◽  
Random Copolymers ◽  
Donor Acceptor

scholarly journals Molecular Engineering Enhances the Charge Carriers Transport in Wide Band-Gap Polymer Donors Based Polymer Solar Cells

Molecules ◽  
2020 ◽  
Vol 25 (18) ◽  
pp. 4101
Author(s):  
Siyang Liu ◽  
Shuwang Yi ◽  
Peiling Qing ◽  
Weijun Li ◽  
Bin Gu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Band Gap ◽  
High Efficiency ◽  
Polymer Solar Cells ◽  
Acid Methyl Ester ◽  
Wide Band ◽  
Molecular Engineering ◽  
Wide Band Gap ◽  
Photovoltaic Properties ◽  
Solvent Vapor

The novel and appropriate molecular design for polymer donors are playing an important role in realizing high-efficiency and high stable polymer solar cells (PSCs). In this work, four conjugated polymers (PIDT-O, PIDTT-O, PIDT-S and PIDTT-S) with indacenodithiophene (IDT) and indacenodithieno [3,2-b]thiophene (IDTT) as the donor units, and alkoxy-substituted benzoxadiazole and benzothiadiazole derivatives as the acceptor units have been designed and synthesized. Taking advantages of the molecular engineering on polymer backbones, these four polymers showed differently photophysical and photovoltaic properties. They exhibited wide optical bandgaps of 1.88, 1.87, 1.89 and 1.91 eV and quite impressive hole mobilities of 6.01 × 10−4, 7.72 × 10−4, 1.83 × 10−3, and 1.29 × 10−3 cm2 V−1 s−1 for PIDT-O, PIDTT-O, PIDT-S and PIDTT-S, respectively. Through the photovoltaic test via using PIDT-O, PIDTT-O, PIDT-S and PIDTT-S as donor materials and [6,6]-phenyl-C-71-butyric acid methyl ester (PC71BM) as acceptor materials, all the PSCs presented the high open circuit voltages (Vocs) over 0.85 V, whereas the PIDT-S and PIDTT-S based devices showed higher power conversion efficiencies (PCEs) of 5.09% and 4.43%, respectively. Interestingly, the solvent vapor annealing (SVA) treatment on active layers could improve the fill factors (FFs) extensively for these four polymers. For PIDT-S and PIDTT-S, the SVA process improved the FFs exceeding 71%, and ultimately the PCEs were increased to 6.05%, and 6.12%, respectively. Therefore, this kind of wide band-gap polymers are potentially candidates as efficient electron-donating materials for constructing high-performance PSCs.

Long-Term Thermal Stability of High-Efficiency Polymer Solar Cells Based on Photocrosslinkable Donor-Acceptor Conjugated Polymers

2011 ◽  
Vol 23 (14) ◽  
pp. 1660-1664 ◽  
Author(s):  
Gianmarco Griffini ◽  
Jessica D. Douglas ◽  
Claudia Piliego ◽  
Thomas W. Holcombe ◽  
Stefano Turri ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Solar Cells ◽  
Conjugated Polymers ◽  
High Efficiency ◽  
Polymer Solar Cells ◽  
Donor Acceptor ◽  
Thermal Stability Of

scholarly journals High-efficiency photovoltaic cells with wide optical band gap polymers based on fluorinated phenylene-alkoxybenzothiadiazole

2017 ◽  
Vol 10 (6) ◽  
pp. 1443-1455 ◽  
Author(s):  
Seo-Jin Ko ◽  
Quoc Viet Hoang ◽  
Chang Eun Song ◽  
Mohammad Afsar Uddin ◽  
Eunhee Lim ◽  
...  
Keyword(s):  
Solar Cells ◽  
Band Gap ◽  
High Performance ◽  
Optical Band Gap ◽  
High Efficiency ◽  
Bulk Heterojunction ◽  
Polymer Solar Cells ◽  
Photovoltaic Cells ◽  
Wide Band ◽  
Wide Band Gap

A new series of wide band gap photovoltaic polymers based on a fluorinated phenylene-alkoxybenzothiadiazole unit with an optical band gap of over 1.90 eV are designed and utilized for high-performance single- and multi-junction bulk heterojunction polymer solar cells.

A low band-gap copolymer composed of thienyl substituted anthracene and diketopyrrolopyrrole compatible with multiple electron acceptors for high efficiency polymer solar cells

2015 ◽  
Vol 6 (21) ◽  
pp. 4013-4019 ◽  
Author(s):  
Jae Woong Jung ◽  
Won Ho Jo
Keyword(s):  
Solar Cells ◽  
Band Gap ◽  
Electron Donor ◽  
High Efficiency ◽  
Polymer Solar Cells ◽  
Electron Acceptors ◽  
Low Band Gap ◽  
Low Band Gap Polymer

A low band-gap polymer composed of thienylanthracene and DPP exhibits promising PCEs of 7.02% with PC71BM, and 4.23% with non-fullerene acceptor di-PBI, demonstrating the potential for universal electron donor polymer of polymer solar cells.

Donor–acceptor conjugated polymers based on thieno[3,2-b]indole (TI) and 2,1,3-benzothiadiazole (BT) for high efficiency polymer solar cells

2016 ◽  
Vol 4 (23) ◽  
pp. 5448-5460 ◽  
Author(s):  
Hongyan Huang ◽  
Meng Qiu ◽  
Quan Li ◽  
Shuli Liu ◽  
Xinzhen Zhang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Conjugated Polymers ◽  
Electron Donor ◽  
High Efficiency ◽  
Polymer Solar Cells ◽  
Photovoltaic Performance ◽  
Donor Block ◽  
Donor Acceptor

Three conjugated polymers based on the thieno[3,2-b]indole (TI) unit as electron-donor block and benzothiadiazole (BT) as electron-accepting block and thiophene rings as spacers. Their photovoltaic performance were finely tuned by thiophene spacers.

Tailoring side chains of low band gap polymers for high efficiency polymer solar cells

Polymer ◽  
2010 ◽  
Vol 51 (14) ◽  
pp. 3031-3038 ◽  
Author(s):  
Weiwei Li ◽  
Ruiping Qin ◽  
Yi Zhou ◽  
Mattias Andersson ◽  
Fenghong Li ◽  
...  
Keyword(s):  
Solar Cells ◽  
Band Gap ◽  
High Efficiency ◽  
Polymer Solar Cells ◽  
Side Chains ◽  
Low Band Gap ◽  
Low Band Gap Polymers

High-efficiency quaternary polymer solar cells enabled with binary fullerene additives to reduce nonfullerene acceptor optical band gap and improve carriers transport

2018 ◽  
Vol 61 (12) ◽  
pp. 1609-1618 ◽  
Author(s):  
Weiping Li ◽  
Dong Yan ◽  
Feng Liu ◽  
Thomas Russell ◽  
Chuanlang Zhan ◽  
...  
Keyword(s):  
Solar Cells ◽  
Band Gap ◽  
Optical Band Gap ◽  
High Efficiency ◽  
Polymer Solar Cells ◽  
Nonfullerene Acceptor
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