Hydroxo Iron(III) Sites in a Metal–Organic Framework: Proton-Coupled Electron Transfer and Catalytic Oxidation of Alcohol with Molecular Oxygen

2019 ◽  
Vol 11 (49) ◽  
pp. 45621-45628 ◽  
Author(s):  
Chong-Wei Ding ◽  
Wenzhi Luo ◽  
Jie-Yi Zhou ◽  
Xin-Jie Ma ◽  
Guang-Hui Chen ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Catalytic Oxidation ◽  
Molecular Oxygen ◽  
Metal Organic Framework ◽  
Proton Coupled Electron Transfer ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Bulk-to-Surface Proton-Coupled Electron Transfer Reactivity of the Metal–Organic Framework MIL-125

2018 ◽  
Vol 140 (47) ◽  
pp. 16184-16189 ◽  
Author(s):  
Caroline T. Saouma ◽  
Sarah Richard ◽  
Simon Smolders ◽  
Murielle F. Delley ◽  
Rob Ameloot ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Metal Organic Framework ◽  
Proton Coupled Electron Transfer ◽  
Metal Organic ◽  
Organic Framework

Selective chemochromic and chemically-induced photochromic response of a metal–organic framework

2020 ◽  
Vol 56 (44) ◽  
pp. 5929-5932 ◽  
Author(s):  
Peng Li ◽  
Qi Sui ◽  
Meng-Yue Guo ◽  
Shuai-Liang Yang ◽  
Ran Bu ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Electron Acceptor ◽  
Photoinduced Electron Transfer ◽  
Color Change ◽  
Metal Organic Framework ◽  
Confined Space ◽  
Chemically Induced ◽  
Metal Organic ◽  
Organic Framework

The MOF provides unique confined space furnished with electron acceptor sites, and exposure to amines/alcohols causes specific and size-selective direct/UV-assisted color change owing to spontaneous/photoinduced electron transfer.

scholarly journals A Cu(ii) metal–organic framework as a recyclable catalyst for ARGET ATRP

2016 ◽  
Vol 7 (47) ◽  
pp. 7199-7203 ◽  
Author(s):  
Hui-Chun Lee ◽  
Markus Antonietti ◽  
Bernhard V. K. J. Schmidt
Keyword(s):  
Electron Transfer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Metal Organic Framework ◽  
Recyclable Catalyst ◽  
Atom Transfer ◽  
Arget Atrp ◽  
Metal Organic ◽  
Organic Framework

A Cu(ii) MOF can serve as an comprehensive catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP) in the synthesis of benzyl methacrylate, styrene, isoprene and 4-vinylpyridine.

Iron-Decorated, Guanidine Functionalized Metal-Organic Framework as a Non-heme Iron-Based Enzyme Mimic System for Catalytic Oxidation of Organic Substrates

2019 ◽  
Vol 149 (5) ◽  
pp. 1237-1249 ◽  
Author(s):  
Ahmad Shaabani ◽  
Reza Mohammadian ◽  
Hassan Farhid ◽  
Masoumeh Karimi Alavijeh ◽  
Mostafa M. Amini
Keyword(s):  
Catalytic Oxidation ◽  
Metal Organic Framework ◽  
Enzyme Mimic ◽  
Heme Iron ◽  
Organic Substrates ◽  
Non Heme Iron ◽  
Metal Organic ◽  
Iron Based ◽  
Organic Framework

Ionic liquid-mediated catalytic oxidation of β-caryophyllene by ultrathin 2D metal-organic framework nanosheets under 1 atm O2

2020 ◽  
Vol 496 ◽  
pp. 111196
Author(s):  
Shiye Li ◽  
Lihan Shi ◽  
Li Zhang ◽  
Hongmei Huang ◽  
Yi Xiao ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Catalytic Oxidation ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Photoresponsivity and antibiotic sensing properties of an entangled tris(pyridinium)-based metal–organic framework

2020 ◽  
Vol 49 (22) ◽  
pp. 7488-7495 ◽  
Author(s):  
Peng Li ◽  
Meng-Yue Guo ◽  
Lu-Lu Gao ◽  
Xue-Mei Yin ◽  
Shuai-Liang Yang ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Metal Organic Framework ◽  
Sensing Properties ◽  
Luminescent Sensor ◽  
Donor Acceptor ◽  
Metal Organic ◽  
Nitrofuran Antibiotics ◽  
Organic Framework

Novel 2D → 2D entanglement affords close donor–acceptor contacts for electron transfer based photochromism and photomodulable fluorescence of a MOF, which also serves as a regenerable and sensitive luminescent sensor for nitrofuran antibiotics.

Facile fabrication of magnetically recyclable metal–organic framework nanocomposites for highly efficient and selective catalytic oxidation of benzylic C–H bonds

2014 ◽  
Vol 50 (61) ◽  
pp. 8374-8377 ◽  
Author(s):  
Yifa Chen ◽  
Xianqiang Huang ◽  
Xiao Feng ◽  
Jikun Li ◽  
Yingyu Huang ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Metal Organic Framework ◽  
Highly Efficient ◽  
Selective Catalytic Oxidation ◽  
Metal Organic ◽  
Facile Fabrication ◽  
Organic Framework

Chemically-bonded HKUST-1@Fe3O4 shows exceptional activity for the oxidation of benzylic C–H bonds.

An electron-transfer photochromic metal–organic framework (MOF) compound with a long-lived charge-separated state and high-contrast photoswitchable luminescence

RSC Advances ◽  
2016 ◽  
Vol 6 (29) ◽  
pp. 24190-24194 ◽  
Author(s):  
Xiu-Shuang Xing ◽  
Zi-Wei Chen ◽  
Li-Zhen Cai ◽  
Cai Sun ◽  
Lin-Rong Cai ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Metal Organic Framework ◽  
Pyridine Derivative ◽  
High Contrast ◽  
Photochromic Compounds ◽  
Metal Organic ◽  
A Charge ◽  
Organic Framework

A new photochromic MOF compound exhibits a charge-separated state with lifetime exceeding the reported values of the analogues and a luminescence contrast higher than those of most known pyridine derivative-based photochromic compounds.

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