Freezing-Tolerant Hydrogel Composed of Sulfonated Chitosan and Poly(vinyl alcohol) Featuring Excellent Stretchability and High Proton Conduction

Author(s):  
Qiao Qiao ◽  
Zhi-Rong Feng ◽  
Ya-Ru Kong ◽  
Yu-Ping Wu ◽  
Xiao-Ming Ren
1999 ◽  
Vol 1 (11) ◽  
pp. 2749-2753 ◽  
Author(s):  
Masahiro Suzuki ◽  
Takahide Yoshida ◽  
Satoshi Kobayashi ◽  
Toshiki Koyama ◽  
Mutsumi Kimura ◽  
...  

2020 ◽  
pp. 095400832096816
Author(s):  
Hailin Yu ◽  
Yinghan Wang

Aldehyde terminated sulfonated poly (arylene ether sulfone) (SPAES-CHO) is prepared by a series of nucleophilic substitution reaction based on SPAES in this paper. Novel SPAES-graft-SPVA (SPAES-g-SPVA) membranes are fabricated by acetal reaction between SPAES-CHO and different amounts of sulfonated poly (vinyl alcohol) (SPVA). The 1H-NMR and FTIR indicate the successful preparation of SPAES-CHO and SPAES-g-SPVA membranes. With the introduction of SPVA, the SPAES-g-SPVA membranes have much lower methanol permeability than pure SPAES membrane and Nafion117 membrane. The methanol permeability coefficients of the SPAES-g-SPVA membranes decrease from 3.41 × 10−7 cm2 s−1 to 1.67 × 10−7 cm2 s−1 with the increase of SPVA content. And the proton conductivity of all the membranes is higher than 15 mS cm−1 at 25°C. Moreover, SPAES-g-SPVA membranes exhibit high proton selectivity. Especially, SPAES-g-SPVA-30% membrane has the highest proton selectivity, which is nearly five times higher than Nafion117.


1986 ◽  
Vol 1 (6) ◽  
pp. 861-869 ◽  
Author(s):  
Paul D. Garrett ◽  
David T. Grubb

2019 ◽  
Vol 18 (1) ◽  
pp. 125-136 ◽  
Author(s):  
Luiza Jecu ◽  
Iuliana Raut ◽  
Elena Grosu ◽  
Mariana Calin ◽  
Violeta Purcar ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document