scholarly journals An Under-Appreciated Source of Reproducibility Issues in Cross-Coupling: Solid-State Decomposition of Primary Sodium Alkoxides in Air

ACS Catalysis ◽  
2020 ◽  
pp. 502-508
Author(s):  
Robert Wethman ◽  
Joseph Derosa ◽  
Van T. Tran ◽  
Taeho Kang ◽  
Omar Apolinar ◽  
...  
Keyword(s):  
Solid State ◽  
Cross Coupling ◽  
Solid State Decomposition

Tackling Solubility Issues in Organic Synthesis: Solid-State Cross-Coupling of Insoluble Aryl Halides

2021 ◽  
Author(s):  
Tamae Seo ◽  
Naoki Toyoshima ◽  
Koji Kubota ◽  
Hajime Ito
Keyword(s):  
Solid State ◽  
Organic Synthesis ◽  
Cross Coupling ◽  
Aryl Halides

scholarly journals Convenient Access to Functionalized Non-Symmetrical Atropisomeric 4,4′-Bipyridines

Compounds ◽  
2021 ◽  
Vol 1 (2) ◽  
pp. 58-74
Author(s):  
Emmanuel Aubert ◽  
Emmanuel Wenger ◽  
Paola Peluso ◽  
Victor Mamane
Keyword(s):  
Solid State ◽  
Intermolecular Interactions ◽  
Medicinal Chemistry ◽  
Crystal Packing ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Halogen Bonds ◽  
Cross Coupling Reactions ◽  
Cyano Groups ◽  
Post Functionalization

Non-symmetrical chiral 4,4′-bipyridines have recently found interest in organocatalysis and medicinal chemistry. In this regard, the development of efficient methods for their synthesis is highly desirable. Herein, a series of non-symmetrical atropisomeric polyhalogenated 4,4′-bipyridines were prepared and further functionalized by using cross-coupling reactions. The desymmetrization step is based on the N-oxidation of one of the two pyridine rings of the 4,4′-bipyridine skeleton. The main advantage of this methodology is the possible post-functionalization of the pyridine N-oxide, allowing selective introduction of chlorine, bromine or cyano groups in 2- and 2′-postions of the chiral atropisomeric 4,4′-bipyridines. The crystal packing in the solid state of some newly prepared derivatives was analyzed and revealed the importance of halogen bonds in intermolecular interactions.

Solid state decomposition studies on metal salicylates

1987 ◽  
Vol 114 (1) ◽  
pp. 145-152 ◽  
Author(s):  
Pertti Kokkonen ◽  
Lauri H.J. Lajunen ◽  
Leena Palmu
Keyword(s):  
Solid State ◽  
Solid State Decomposition

Some comments on the use of Avrami-Erofeev expressions and solid state decomposition rate constants

1986 ◽  
Vol 104 ◽  
pp. 93-100 ◽  
Author(s):  
N. Fatemi ◽  
R. Whitehead ◽  
D. Price ◽  
D. Dollimore
Keyword(s):  
Solid State ◽  
Decomposition Rate ◽  
Rate Constants ◽  
Solid State Decomposition

Electron Tomography Analysis of Reaction Path during Formation of Nanoporous NiO by Solid State Decomposition

2014 ◽  
Vol 14 (5) ◽  
pp. 2453-2459 ◽  
Author(s):  
A. K. Shukla ◽  
P. Ercius ◽  
A. R. S. Gautam ◽  
J. Cabana ◽  
U. Dahmen
Keyword(s):  
Solid State ◽  
Reaction Path ◽  
Electron Tomography ◽  
Solid State Decomposition ◽  
Tomography Analysis

Microstructural and microchemical aspects of the solid-state decomposition of delta ferrite in austenitic stainless steels

1985 ◽  
Vol 16 (8) ◽  
pp. 1363-1369 ◽  
Author(s):  
J. Singh ◽  
G. R. Purdy ◽  
G. C. Weatherly
Keyword(s):  
Solid State ◽  
Stainless Steels ◽  
Austenitic Stainless Steels ◽  
Delta Ferrite ◽  
Solid State Decomposition

Synthesis, Electrochemistry, Spectroelectrochemistry, and Solid-State Structures of Palladium Biferrocenylphosphines and Their Use in C,C Cross-Coupling Reactions

2012 ◽  
Vol 31 (6) ◽  
pp. 2310-2326 ◽  
Author(s):  
Manja Lohan ◽  
Bianca Milde ◽  
Silvio Heider ◽  
J. Matthäus Speck ◽  
Sabrina Krauße ◽  
...  
Keyword(s):  
Solid State ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Solid State Structures

scholarly journals The role of MgB12H12 in the hydrogen desorption process of Mg(BH4)2

2015 ◽  
Vol 51 (4) ◽  
pp. 700-702 ◽  
Author(s):  
Yigang Yan ◽  
Arndt Remhof ◽  
Daniel Rentsch ◽  
Andreas Züttel
Keyword(s):  
Solid State ◽  
Hydrogen Desorption ◽  
Decomposition Process ◽  
Desorption Process ◽  
Solid State Decomposition

Throughout the solid-state decomposition process of Mg(BH4)2, the MgB12H12 phase does not exist in the solid residues after decomposition.

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