Quantum Chemical Characterization of Structural Single Fe(II) Sites in MIL-Type Metal–Organic Frameworks for the Oxidation of Methane to Methanol and Ethane to Ethanol

In this study, lanthanide elements (Ln3+) and 2,3,5,6-tetrafluoro-1,4-benzenedicarboxylic acid (TFBDC) based metal-organic frameworks (MOFs) were synthesized by precipitation and diffusion-controlled precipitation methods. Powders insoluble in aqueous media and polar solvents were obtained. The microstructure and properties of Ln3+ MOFs were evaluated and discussed. X-ray diffraction (XRD) analysis, infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and fluorescence spectroscopy (FLS) were carried out to characterize Ln3+ MOF's crystallinity, the microstructure, chemical composition and optical properties.

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A Comparison of Barostats for the Mechanical Characterization of Metal–Organic Frameworks

Journal of Chemical Theory and Computation ◽

10.1021/acs.jctc.5b00748 ◽

2015 ◽

Vol 11 (12) ◽

pp. 5583-5597 ◽

Cited By ~ 45

Author(s):

S.M.J. Rogge ◽

L. Vanduyfhuys ◽

A. Ghysels ◽

M. Waroquier ◽

T. Verstraelen ◽

...

Keyword(s):

Mechanical Characterization ◽

Metal Organic Frameworks ◽

Metal Organic

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Synthesis and characterization of zinc adeninate metal-organic frameworks (bioMOF1) as potential anti-inflammatory drug delivery material

10.1063/1.5034549 ◽

2018 ◽

Cited By ~ 1

Author(s):

Ken Aldren S. Usman ◽

Salvador C. Buenviaje ◽

Joselito M. Razal ◽

Marlon T. Conato ◽

Leon M. Payawan

Keyword(s):

Drug Delivery ◽

Metal Organic Frameworks ◽

Synthesis And Characterization ◽

Inflammatory Drug ◽

Metal Organic ◽

Anti Inflammatory

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Quantum Chemical Characterization of Hydrogen Bonding Sites in Three 4-(4-Halo-Phenyl)-6-(Furan-2-yl) Pyrimidin-2-Amine Derivatives

Computational Chemistry ◽

10.4236/cc.2017.53008 ◽

2017 ◽

Vol 05 (03) ◽

pp. 91-102 ◽

Cited By ~ 1

Author(s):

Yafigui Traore ◽

Kafoumba Bamba ◽

Nahossé Ziao ◽

Sopi Thomas Affi ◽

Mamadou Guy-Richard Kone

Keyword(s):

Hydrogen Bonding ◽

Quantum Chemical ◽

Chemical Characterization

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STUDY OF SYNTHESIS AND CHARACTERIZATION OF METAL-ORGANIC FRAMEWORKS MOF-5 AS HYDROGEN STORAGE MATERIAL

ALCHEMY Jurnal Penelitian Kimia ◽

10.20961/alchemy.12.1.934.14-26 ◽

2016 ◽

Vol 12 (1) ◽

pp. 14

Author(s):

Prapti Rahayu ◽

Witri Wahyu Lestari

Keyword(s):

Hydrogen Storage ◽

Metal Organic Frameworks ◽

Synthesis Method ◽

High Porosity ◽

Hydrogen Storage Material ◽

Storage Material ◽

Good Thermal Stability ◽

Metal Organic ◽

Organic Linker

Metal-organic frameworks (MOFs) are porous coordination polymer containing bi-or polidentate organic linker coordinated with inorganic part, such as metal oxide cluster or metal cation as node which called as secondary building unit (SBU) to form infinite structure. Due to high porosity and surface area, good thermal stability as well as the availability of unsaturated metal center or the linker influence attracts the interaction with gases, thus MOFs have potential to be applied as hydrogen storage material. One type of MOFs that have been widely studied is [Zn4O(benzene-1,4-dicarboxylate)3], namely, MOF-5.Various synthesis method have been developed to obtain optimum results. Characterization of MOF-5 from various synthesis method such as crystallinity, capacity, stability, and quantum dot behavior of MOF-5 have been summarized in this review.

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