Novel Calcium sp3 Carbonate CaC2O5-I4̅2d May Be a Carbon Host in Earth’s Lower Mantle

Author(s):  
Jannes König ◽  
Dominik Spahr ◽  
Lkhamsuren Bayarjargal ◽  
Pavel N. Gavryushkin ◽  
Dinara Sagatova ◽  
...  
Keyword(s):  
2020 ◽  
Vol 224 (2) ◽  
pp. 961-972
Author(s):  
A G Semple ◽  
A Lenardic

SUMMARY Previous studies have shown that a low viscosity upper mantle can impact the wavelength of mantle flow and the balance of plate driving to resisting forces. Those studies assumed that mantle viscosity is independent of mantle flow. We explore the potential that mantle flow is not only influenced by viscosity but can also feedback and alter mantle viscosity structure owing to a non-Newtonian upper-mantle rheology. Our results indicate that the average viscosity of the upper mantle, and viscosity variations within it, are affected by the depth to which a non-Newtonian rheology holds. Changes in the wavelength of mantle flow, that occur when upper-mantle viscosity drops below a critical value, alter flow velocities which, in turn, alter mantle viscosity. Those changes also affect flow profiles in the mantle and the degree to which mantle flow drives the motion of a plate analogue above it. Enhanced upper-mantle flow, due to an increasing degree of non-Newtonian behaviour, decreases the ratio of upper- to lower-mantle viscosity. Whole layer mantle convection is maintained but upper- and lower-mantle flow take on different dynamic forms: fast and concentrated upper-mantle flow; slow and diffuse lower-mantle flow. Collectively, mantle viscosity, mantle flow wavelengths, upper- to lower-mantle velocities and the degree to which the mantle can drive plate motions become connected to one another through coupled feedback loops. Under this view of mantle dynamics, depth-variable mantle viscosity is an emergent flow feature that both affects and is affected by the configuration of mantle and plate flow.


Nature ◽  
1988 ◽  
Vol 336 (6200) ◽  
pp. 667-670 ◽  
Author(s):  
Pat Castillo
Keyword(s):  

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Carla Lupo ◽  
Evan Sheridan ◽  
Edoardo Fertitta ◽  
David Dubbink ◽  
Chris J. Pickard ◽  
...  

AbstractUsing spin-assisted ab initio random structure searches, we explore an exhaustive quantum phase diagram of archetypal interfaced Mott insulators, i.e. lanthanum-iron and lanthanum-titanium oxides. In particular, we report that the charge transfer induced by the interfacial electronic reconstruction stabilises a high-spin ferrous Fe2+ state. We provide a pathway to control the strength of correlation in this electronic state by tuning the epitaxial strain, yielding a manifold of quantum electronic phases, i.e. Mott-Hubbard, charge transfer and Slater insulating states. Furthermore, we report that the electronic correlations are closely related to the structural oxygen octahedral rotations, whose control is able to stabilise the low-spin state of Fe2+ at low pressure previously observed only under the extreme high pressure conditions in the Earth’s lower mantle. Thus, we provide avenues for magnetic switching via THz radiations which have crucial implications for next generation of spintronics technologies.


Author(s):  
Pavel N. Gavryushkin ◽  
Dinara N. Sagatova ◽  
Nursultan Sagatov ◽  
Konstantin D. Litasov
Keyword(s):  

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