Ionic Liquid-Based Deep Eutectic Solvent as Reaction Media for the Thermal Dehydrogenation of Ethylene Diamine-bis-borane

2020 ◽  
Vol 8 (12) ◽  
pp. 4910-4919
Author(s):  
Dhirendra Kumar Mishra ◽  
Gopal Pugazhenthi ◽  
Tamal Banerjee
Keyword(s):  
Ionic Liquid ◽  
Deep Eutectic Solvent ◽  
Ethylene Diamine ◽  
Thermal Dehydrogenation ◽  
Reaction Media

Quantum chemical and experimental insights for the ionic liquid facilitated thermal dehydrogenation of ethylene diamine bisborane

RSC Advances ◽  
2015 ◽  
Vol 5 (104) ◽  
pp. 85280-85290 ◽  
Author(s):  
Basudhrity Banerjee ◽  
Debashis Kundu ◽  
G. Pugazhenthi ◽  
Tamal Banerjee
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Quantum Chemical ◽  
Ethylene Diamine ◽  
Thermal Dehydrogenation

Ionic liquids (ILs) were screened on the basis of solubility of ethylene diamine bisborane (EDAB) using the COSMO-SAC model and LUMO–HOMO calculations. Thereafter, thermal dehydrogenation of EDAB was conducted with imidazolium-acetate based ILs.

scholarly journals Hydrogen storage in amine boranes: Ionic liquid supported thermal dehydrogenation of ethylene diamine bisborane

2013 ◽  
Vol 38 (8) ◽  
pp. 3283-3290 ◽  
Author(s):  
Sebastian Sahler ◽  
Hannelore Konnerth ◽  
Nicole Knoblauch ◽  
Martin H.G. Prechtl
Keyword(s):  
Ionic Liquid ◽  
Hydrogen Storage ◽  
Ethylene Diamine ◽  
Amine Boranes ◽  
Thermal Dehydrogenation

Enzymes-Catalyzed Knoevenagel Condensation Promoted by Ionic Liquid and Deep Eutectic Solvent

2021 ◽  
Author(s):  
Yun Wang ◽  
Hong Cheng ◽  
Jia-Rui He ◽  
Qiao-Xia Yao ◽  
Li-Ling Li ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Knoevenagel Condensation ◽  
Deep Eutectic Solvent

A novel deep eutectic solvent-based ionic liquid used as electrolyte for dye-sensitized solar cells

2009 ◽  
Vol 11 (1) ◽  
pp. 209-211 ◽  
Author(s):  
Huei-Ru Jhong ◽  
David Shan-Hill Wong ◽  
Chi-Chao Wan ◽  
Yung-Yun Wang ◽  
Tzu-Chien Wei
Keyword(s):  
Ionic Liquid ◽  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Deep Eutectic Solvent ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Application of Deep Eutectic Solvent (DES) as a Reaction Media for the Esterification of Acrylic Acid with n-Butanol

2015 ◽  
Vol 13 (3) ◽  
pp. 389-393 ◽  
Author(s):  
Emine Sert
Keyword(s):  
Catalytic Activity ◽  
Acrylic Acid ◽  
Batch Reactor ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Molar Ratio ◽  
Catalyst Loading ◽  
Toluene Sulfonic Acid ◽  
Effects Of Temperature ◽  
Reaction Media

Abstract Within the framework of green chemistry, catalysts should be met different criteria such as biodegradability, recyclability, flammability, non-toxicity and low price. Acidic deep eutectic solvent (DES) have been synthesized for this purpose, by mixing para-toluene sulfonic acid and choline chloride. The catalytic activity of DES was studied in the esterification of acrylic acid with n-butanol. The usage of DES as catalyst is simple, safe and cheap. The effects of temperature, catalyst loading, n-butanol/acrylic acid molar ratio on the conversion of acrylic acid were performed. The batch reactor experiments were carried out at temperatures of 338, 348, 358 and 368 K, molar ratio of butanol to acrylic acid of 1, 2,3 and catalyst loading of 10, 15, 20 and 90 g/L. 90.2% of acrylic acid conversion was achieved at a temperature of 358 K and catalyst loading of 20 g/L. Reusability of DES was investigated. Reusability and catalytic activity makes DES efficient as catalyst.

Synthesis of Nickel Hydroxide with Different Morphologies Using an Ionic Liquid

2010 ◽  
Vol 663-665 ◽  
pp. 1163-1166
Author(s):  
Cun Ying Xu ◽  
Yi Xin Hua
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Ionic Liquid ◽  
Volume Ratio ◽  
X Ray Diffraction ◽  
X Ray ◽  
Reaction Media ◽  
Solvothermal Conditions ◽  
Facile Route ◽  
Scanning Electron

A new and facile route has been developed to synthesize β-Ni(OH)2 nanostructures using ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4) as reaction media under solvothermal conditions. The β-Ni(OH)2 with different morphologies, such as nanoflakes, nanoplatelet and nanorods, can be obtained by controlling the volume ratio of the ionic liquid to water and reaction temperature. The as-prepared products were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM).

scholarly journals Interaction Study of Binary Solvent Systems Ionic Liquid and Deep Eutectic Solvent with Rotenone

2018 ◽  
Vol 47 (07) ◽  
pp. 1473-1482 ◽  
Author(s):  
Zetty Shafiqa Othman ◽  
Mamoru Koketsu ◽  
Nurul Huda Abd Karim ◽  
Saiful Irwan Zubairi ◽  
Nur Hasyareeda Hassan
Keyword(s):  
Ionic Liquid ◽  
Deep Eutectic Solvent ◽  
Binary Solvent ◽  
Interaction Study ◽  
Binary Solvent Systems ◽  
Solvent Systems
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