Rate-Dependent, Li-Ion Insertion/Deinsertion Behavior of LiFePO4 Cathodes in Commercial 18650 LiFePO4 Cells

2014 ◽  
Vol 6 (5) ◽  
pp. 3282-3289 ◽  
Author(s):  
Qi Liu ◽  
Hao He ◽  
Zhe-Fei Li ◽  
Yadong Liu ◽  
Yang Ren ◽  
...  
Keyword(s):  
Li Ion ◽  
Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4585
Author(s):  
Marian Bulla ◽  
Stefan Kolling ◽  
Elham Sahraei

The present study is focused on the development of a material model where the orthotropic-visco-elastic and orthotropic-visco-plastic mechanical behavior of a polymeric material is considered. The increasing need to reduce the climate-damaging exhaust gases in the automotive industry leads to an increasing usage of electric powered drive systems using Lithium-ion (Li-ion) batteries. For the safety and crashworthiness investigations, a deeper understanding of the mechanical behavior under high and dynamic loads is needed. In order to prevent internal short circuits and thermal runaways within a Li-ion battery, the separator plays a crucial role. Based on results of material tests, a novel material model for finite element analysis (FEA) is developed using the explicit solver Altair Radioss. Based on this model, the visco-elastic-orthotropic, as well as the visco-plastic-orthotropic, behavior until failure can be modeled. Finally, a FE simulation model of the separator material is performed, using the results of different tensile tests conducted at three different velocities, 0.1 mm·s−1, 1.0 mm·s−1 and 10.0 mm·s−1 and different orientations of the specimen. The purpose is to predict the anisotropic, rate-dependent stiffness behavior of separator materials in order to improve FE simulations of the mechanical behavior of batteries and therefore reduce the development time of electrically powered vehicles and consumer goods. The present novel material model in combination with a well-suited failure criterion, which considers the different states of stress and anisotropic-visco-dependent failure limits, can be applied for crashworthiness FE analysis. The model succeeded in predicting anisotropic, visco-elastic orthotropic and visco-plastic orthotropic stiffness behavior up to failure.


2019 ◽  
Vol 21 (10) ◽  
pp. 5416-5423 ◽  
Author(s):  
Simon Rano ◽  
Christel Laberty-Robert ◽  
Kieu Ngo ◽  
Carlos M. Sánchez-Sánchez ◽  
Vincent Vivier

Transient electrochemical experiments associated with the collisions between hydrothermally synthesized LiCoO2 (LCO) nanoparticles/aggregates of different sizes and a polarized gold ultramicroelectrode (UME) were used as a new additive-free analytical tool applied to characterize Li ion insertion compounds.


Batteries ◽  
2018 ◽  
Vol 4 (4) ◽  
pp. 71 ◽  
Author(s):  
Yusuke Abe ◽  
Tomoaki Saito ◽  
Seiji Kumagai

Two prelithiation processes (shallow Li-ion insertion, and thrice-repeated deep Li-ion insertion and extraction) were applied to the hard carbon (HC) negative electrode (NE) used in lithium-ion batteries (LIBs). LIB full-cells were assembled using Li(Ni0.5Co0.2Mn0.3)O2 positive electrodes (PEs) and the prelithiated HC NEs. The assembled full-cells were charged and discharged under a low current density, increasing current densities in a stepwise manner, and then constant under a high current density. The prelithiation process of shallow Li-ion insertion resulted in the high Coulombic efficiency (CE) of the full-cell at the initial charge-discharge cycles as well as in a superior rate capability. The prelithiation process of thrice-repeated Li-ion insertion and extraction attained an even higher CE and a high charge-discharge specific capacity under a low current density. However, both prelithiation processes decreased the capacity retention during charge-discharge cycling under a high current density, ascertaining a trade-off relationship between the increased CE and the cycling performance. Further elimination of the irreversible capacity of the HC NE was responsible for the higher utilization of both the PE and NE, attaining higher initial performances, but allowing the larger capacity to fade throughout charge-discharge cycling.


2019 ◽  
Vol 114 ◽  
pp. 37-44 ◽  
Author(s):  
Daw Gen Lim ◽  
Yunpu Zhao ◽  
Palanisamy Manikandan ◽  
Ryan A. Adams ◽  
Jeffrey P. Youngblood ◽  
...  

Author(s):  
Narinthorn Wiriya ◽  
Yutthanakon Kanaphan ◽  
Rattiya Hongtong ◽  
Songyoot Kaewmala ◽  
Jeffrey Nash ◽  
...  

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