ESR Study and Radical Observation in Transition Metal-Mediated Polymerization: Unified View of Atom Transfer Radical Polymerization Mechanism

2003 ◽  
pp. 161-179
Author(s):  
Aileen R. Wang ◽  
Shiping Zhu ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Transition Metal ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Polymerization Mechanism ◽  
Unified View

Thermo-regulated phase separable catalysis (TPSC)-based atom transfer radical polymerization in a thermo-regulated ionic liquid

2014 ◽  
Vol 50 (66) ◽  
pp. 9266-9269 ◽  
Author(s):  
Xiangyang Du ◽  
Jinlong Pan ◽  
Mengting Chen ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Transition Metal ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Metal Catalysts ◽  
Transition Metal Catalysts ◽  
Atom Transfer ◽  
Aget Atrp ◽  
First Time

A thermo-regulated phase separable catalysis (TPSC) system for AGET ATRP based on a thermo-regulated ionic liquid was developed for the first time. The corresponding transition metal catalysts could be easily recovered and reused several times with negligible loss of catalytic activity.

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