A Three-Dimensional Porous Metal−Organic Framework with a Body-Centered Cubic Topology Constructed from 48-Membered Tetraicosanuclear Metallamacrocycle Based on in Situ Ligand Synthesis

2009 ◽  
Vol 9 (7) ◽  
pp. 2988-2990 ◽  
Author(s):  
Lin Hsiu-Mei ◽  
Chang Tsung-Yuan
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Porous Metal ◽  
Body Centered Cubic ◽  
Metal Organic ◽  
Ligand Synthesis ◽  
Organic Framework

Ordered macro-microporous metal-organic framework single crystals

Science ◽  
2018 ◽  
Vol 359 (6372) ◽  
pp. 206-210 ◽  
Author(s):  
Kui Shen ◽  
Lei Zhang ◽  
Xiaodong Chen ◽  
Lingmei Liu ◽  
Daliang Zhang ◽  
...  
Keyword(s):  
Single Crystals ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Single Crystalline ◽  
Metal Organic ◽  
Crystalline Nature ◽  
Opening Up ◽  
Diffusion Properties ◽  
Organic Framework

We constructed highly oriented and ordered macropores within metal-organic framework (MOF) single crystals, opening up the area of three-dimensional–ordered macro-microporous materials (that is, materials containing both macro- and micropores) in single-crystalline form. Our methodology relies on the strong shaping effects of a polystyrene nanosphere monolith template and a double-solvent–induced heterogeneous nucleation approach. This process synergistically enabled the in situ growth of MOFs within ordered voids, rendering a single crystal with oriented and ordered macro-microporous structure. The improved mass diffusion properties of such hierarchical frameworks, together with their robust single-crystalline nature, endow them with superior catalytic activity and recyclability for bulky-molecule reactions, as compared with conventional, polycrystalline hollow, and disordered macroporous ZIF-8.

A Three-Dimensional Porous Metal−Organic Framework Constructed from Two-Dimensional Sheets via Interdigitation Exhibiting Dynamic Features

2009 ◽  
Vol 48 (11) ◽  
pp. 4616-4618 ◽  
Author(s):  
Shengqian Ma ◽  
Daofeng Sun ◽  
Paul M. Forster ◽  
Daqiang Yuan ◽  
Wenjuan Zhuang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Porous Metal ◽  
Two Dimensional ◽  
Dynamic Features ◽  
Metal Organic ◽  
Organic Framework

Introduction of metal precursors by electrodeposition for the in situ growth of metal–organic framework membranes on porous metal substrates

2017 ◽  
Vol 5 (5) ◽  
pp. 1948-1951 ◽  
Author(s):  
Sheng Zhou ◽  
Yanying Wei ◽  
Libin Zhuang ◽  
Liang-Xin Ding ◽  
Haihui Wang
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
In Situ Growth ◽  
Metal Substrates ◽  
Metal Precursors ◽  
Metal Organic ◽  
Organic Framework

An efficient and generalizable strategy assisted by electrodeposition was developed for the in situ growth of various MOF membranes.

A three-dimensional non-interpenetrated porous metal–organic framework based on cationic 1-D chains

2014 ◽  
Vol 40 ◽  
pp. 148-150 ◽  
Author(s):  
Jian-Liang Zhou ◽  
Yuan-Yuan Wang ◽  
Min-Jia Zhou ◽  
Ling Qin ◽  
Ming-Dao Zhang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Three Dimensional ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

Control of interpenetration in a microporous metal–organic framework for significantly enhanced C2H2/CO2 separation at room temperature

2016 ◽  
Vol 52 (17) ◽  
pp. 3494-3496 ◽  
Author(s):  
Ganggang Chang ◽  
Bin Li ◽  
Hailong Wang ◽  
Tongliang Hu ◽  
Zongbi Bao ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Porous Metal ◽  
Co2 Separation ◽  
Reaction Conditions ◽  
Metal Organic ◽  
Organic Framework

A novel non-interpenetrated three-dimensional porous metal–organic framework UTSA-68 has been controllably synthesized by altering the reaction conditions.

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