In Situ Measurement of pH and Dissolved H2in Mid-Ocean Ridge Hydrothermal Fluids at Elevated Temperatures and Pressures

2007 ◽  
Vol 107 (2) ◽  
pp. 601-622 ◽  
Author(s):  
Kang Ding ◽  
William E. Seyfried
Keyword(s):  
Elevated Temperatures ◽  
In Situ Measurement ◽  
Hydrothermal Fluids ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

Fluids in Submarine Mid-Ocean Ridge Hydrothermal Settings

Elements ◽  
2020 ◽  
Vol 16 (6) ◽  
pp. 389-394
Author(s):  
Esther M. Schwarzenbach ◽  
Matthew Steele-MacInnis
Keyword(s):  
Heat Budget ◽  
Oceanic Lithosphere ◽  
Life Forms ◽  
Hydrothermal Systems ◽  
Hydrothermal Fluids ◽  
Early Earth ◽  
Geologic Time ◽  
Mid Ocean Ridge ◽  
Time Changes ◽  
Ocean Ridge

Seawater interaction with the oceanic lithosphere crucially impacts on global geochemical cycles, controls ocean chemistry over geologic time, changes the petrophysical properties of the oceanic lithosphere, and regulates the global heat budget. Extensive seawater circulation is expressed near oceanic ridges by the venting of hydrothermal fluids through chimney structures. These vent fluids vary greatly in chemistry, from the metal-rich, acidic fluids that emanate from “black smokers” at temperatures up to 400 °C to the metal-poor, highly alkaline and reducing fluids that issue from the carbonate–brucite chimneys of ultramafic-hosted systems at temperatures below 110 °C. Mid-ocean ridge hydrothermal systems not only generate signifi-cant metal resources but also host unique life forms that may be similar to those of early Earth.

Differentiation and source of the Nipissing Diabase intrusions, Ontario, Canada

1993 ◽  
Vol 30 (6) ◽  
pp. 1123-1140 ◽  
Author(s):  
P. C. Lightfoot ◽  
H. de Souza ◽  
W. Doherty
Keyword(s):  
Trace Element ◽  
Crustal Contamination ◽  
Primitive Mantle ◽  
Magma Source ◽  
Magma Type ◽  
Ni Content ◽  
Chemical Signatures ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

Major and trace element data are presented for 2.2 Ga Proterozoic diabase sills from across the Nipissing magmatic province of Ontario. In situ differentiation of the magma coupled with assimilation of Huronian Supergroup roof sediments is responsible for the variation in composition between quartz diabase and granophyric diabase seen within many of the differentiated intrusions. Uniform trace element and isotope ratio signatures, such as La/Sm (2.8 – 3.7) and εNdCHUR (−2.7 to −5.9) characterize chilled margins and undifferentiated quartz diabases. These chemical signatures suggest the existence of a single magma source that was parental to intrusions throughout the magmatic province; this magma has higher La/Sm and lower Ti/Y than primitive mantle and is displaced towards the composition of shales. Most chilled diabases and quartz diabases have a similar Mg# (0.64 and 0.60) and Ni content (98 and 127 ppm), and it is argued that the magma differentiated at depth and was emplaced as a uniform low-Mg magma. The Wanapitei intrusion and Kukagami Lake sill are an exception in that although the quartz diabase has La/Sm similar to the Nipissing magma type, which suggests that they came from the same source, the Mg# (0.68–0.71) and Ni content (130–141 ppm) are higher, which may suggest that they are either slightly more primitive examples of the normal Nipissing magma or that cumulus hypersthene has been resorbed. The light rare earth element enriched signature of the Nipissing magmas was perhaps introduced from the continental crust as the magma migrated from the mantle to the surface, but a remarkably constant and large amount (>20%) of crustal contamination would be required. An addition of 1 –3% shale to the source of a transitional mid-ocean ridge basalt type magma can broadly reproduce the compositional features of the Nipissing magma type. The source characteristics were perhaps imparted during subduction accompanying the terminal Kenoran orogeny.

scholarly journals Dense melt residues drive mid-ocean-ridge “hotspots”

2022 ◽  
Author(s):  
Jordan J.J. Phethean ◽  
Martha Papadopoulou ◽  
Alexander L. Peace
Keyword(s):  
Latent Heat ◽  
Elevated Temperatures ◽  
Thermal Expansivity ◽  
Alternative Mechanism ◽  
Mantle Plumes ◽  
Mantle Dynamics ◽  
Mid Ocean Ridge ◽  
Fast Spreading ◽  
Spreading Centers ◽  
Ocean Ridge

ABSTRACT The geodynamic origin of melting anomalies found at the surface, often referred to as “hotspots,” is classically attributed to a mantle plume process. The distribution of hotspots along mid-ocean-ridge spreading systems around the globe, however, questions the universal validity of this concept. Here, the preferential association of hotspots with slow- to intermediate-spreading centers and not fast-spreading centers, an observation contrary to the expected effect of ridge suction forces on upwelling mantle plumes, is explained by a new mechanism for producing melting anomalies at shallow (<2.3 GPa) depths. By combining the effects of both chemical and thermal density changes during partial melting of the mantle (using appropriate latent heat and depth-dependent thermal expansivity parameters), we find that mantle residues experience an overall instantaneous increase in density when melting occurs at <2.3 GPa. This controversial finding is due to thermal contraction of material during melting, which outweighs the chemical buoyancy due to melting at shallow pressures (where thermal expansivities are highest). These dense mantle residues are likely to locally sink beneath spreading centers if ridge suction forces are modest, thus driving an increase in the flow of fertile mantle through the melting window and increasing magmatic production. This leads us to question our understanding of sub–spreading center dynamics, where we now suggest a portion of locally inverted mantle flow results in hotspots. Such inverted flow presents an alternative mechanism to upwelling hot mantle plumes for the generation of excess melt at near-ridge hotspots, i.e., dense downwelling of mantle residue locally increasing the flow of fertile mantle through the melting window. Near-ridge hotspots, therefore, may not require the elevated temperatures commonly invoked to account for excess melting. The proposed mechanism also satisfies counterintuitive observations of ridge-bound hotspots at slow- to intermediate-spreading centers, yet not at fast-spreading centers, where large dynamic ridge suction forces likely overwhelm density-driven downwelling. The lack of observations of such downwelling in numerical modeling studies to date reflects the generally high chemical depletion buoyancy and/or low thermal expansivity parameter values employed in simulations, which we find to be unrepresentative for melting at <2.3 GPa. We therefore invite future studies to review the values used for parameters affecting density changes during melting (e.g., depletion buoyancy, latent heat of melting, specific heat capacity, thermal expansivity), which quite literally have the potential to turn our understanding of mantle dynamics upside down.

Seawater dissolved gases associated with hydrothermal fluids in convergent margins (Brandsfield-South Shetland, Antarctica) and mid-ocean ridge and intraplate settings (Azores, Portugal)

2020 ◽  
Author(s):  
María Asensio-Ramos ◽  
Cecilia Amonte ◽  
Esther Santofimia ◽  
Gladys V. Melián ◽  
Enrique López ◽  
...  
Keyword(s):  
Water Column ◽  
Sea Water ◽  
Volcanic Eruptions ◽  
Isotopic Signature ◽  
Hydrothermal Systems ◽  
Hydrothermal Fluids ◽  
Convergent Margins ◽  
Dissolved Gases ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

<p>The occurrence of hydrothermal emissions implies the existence of heat sources related to magma reservoirs both in convergent margins (Bransfield-South Shetland) and in mid-ocean ridge and intra-plate settings (Azores). The importance of these systems lies in (a) producing important mineralizations,  (b) favouring extremophilic ecosystems, (c) being precursors of underwater volcanic eruptions, (d) playing a major role they play in the matter and energy exchange between the geosphere and the hydrosphere and (d) their impact on the geochemistry of the oceans. In subduction margins, rifts, transforming faults or volcanic buildings in hot spots, emissions of hot fluids related to magmas and/or circulation in hydrothermal systems can occur. The fluids associated with magmas are fundamentally gases (CO<sub>2</sub>, H<sub>2</sub>O, H<sub>2</sub>, SO<sub>2</sub>, H<sub>2</sub>S, He, etc.). Hydrothermal fluids constitute a complex system where seawater percolates through fissures and fractures in sediments and rocks at different depths and heats up upon contact with magmas and hot volcanic rocks, leaching a large amount of chemical elements. The identification of acoustic plumes in the water column is the first step in the exploration of unknown underwater emissions. The new acoustic detection technologies, which operate with a wide frequency range, are one of the most innovative tools for detecting gas plumes and other fluids in the water column, especially in deep waters. Once detected, physical-chemical parameters (temperature, salinity, turbidity, cations, anions, dissolved gases, isotopic signature, etc.) that allow their characterization and classification will be determined. This type of studies is particularly useful when it is not possible to collect free gases, fumarolic and/or bubbling gases, as in the case of submarine activity. In this work, we show the results obtained regarding the chemical composition of dissolved gases (He, H<sub>2</sub>, CO<sub>2</sub> (aq), O<sub>2</sub>, N<sub>2</sub>, CH<sub>4</sub> and He) and isotopic signature of the dissolved CO<sub>2</sub> (δ<sup>13</sup>C-CO<sub>2</sub>) in sea water sampled in sites of hydrothermal interest. With this purpose, we carried out two oceanographic surveys (EXPLOSEA1 and EXPLOSEA2) in 2019: the first in Antarctica aboard the Spanish Research Vessel (RV) Hespérides and the second in North Atlantic Ocean aboard the Spanish RV Sarmiento de Gamboa. To do so, 13 and 10 water vertical profiles were studied in the RV Hespérides and the RV Sarmiento de Gamboa, respectively, using a SBE 911plus CTD system where there was evidence of acoustic plumes or where appropriate, emission buildings of fluids were present. Water samples were kept in glass bottles for subsequent analysis. The establishment of the physicochemical characteristics of volcanic hydrothermal fluids and the characterization of the nature and origin of the different types of fluid emissions will help to classify the hydrothermal fluids in order to understand the phenomena that take place in them and their surroundings.</p>

scholarly journals Supplemental Material: Geothermal energy and ore-forming potential of 600 °C mid-ocean-ridge hydrothermal fluids

2020 ◽  
Author(s):  
Enikő Bali ◽  
et al.
Keyword(s):  
Geothermal Energy ◽  
Hydrothermal Fluids ◽  
Magmatic Fluid ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

Methods, materials, detailed results of heating experiments, magmatic fluid or modified seawater, Figures S1–S5, and Tables S1–S3.<br>

scholarly journals The trisulfur radical ion S3•− controls platinum transport by hydrothermal fluids

2021 ◽  
Vol 118 (34) ◽  
pp. e2109768118
Author(s):  
Gleb S. Pokrovski ◽  
Maria A. Kokh ◽  
Elsa Desmaele ◽  
Clément Laskar ◽  
Elena F. Bazarkina ◽  
...  
Keyword(s):  
Elevated Temperatures ◽  
High Capacity ◽  
Selective Extraction ◽  
Hydrothermal Fluids ◽  
Thermodynamic Simulations ◽  
Poorly Soluble ◽  
Chloride Sulfate ◽  
Economic Concentration ◽  
Shallow Crust

Platinum group elements (PGE) are considered to be very poorly soluble in aqueous fluids in most natural hydrothermal–magmatic contexts and industrial processes. Here, we combined in situ X-ray absorption spectroscopy and solubility experiments with atomistic and thermodynamic simulations to demonstrate that the trisulfur radical ion S3•− forms very stable and soluble complexes with both PtII and PtIV in sulfur-bearing aqueous solution at elevated temperatures (∼300 °C). These Pt-bearing species enable (re)mobilization, transfer, and focused precipitation of platinum up to 10,000 times more efficiently than any other common inorganic ligand, such as hydroxide, chloride, sulfate, or sulfide. Our results imply a far more important contribution of sulfur-bearing hydrothermal fluids to PGE transfer and accumulation in the Earth’s crust than believed previously. This discovery challenges traditional models of PGE economic concentration from silicate and sulfide melts and provides new possibilities for resource prospecting in hydrothermal shallow crust settings. The exceptionally high capacity of the S3•− ion to bind platinum may also offer new routes for PGE selective extraction from ore and hydrothermal synthesis of noble metal nanomaterials.

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