Differentiation and source of the Nipissing Diabase intrusions, Ontario, Canada

1993 ◽  
Vol 30 (6) ◽  
pp. 1123-1140 ◽  
Author(s):  
P. C. Lightfoot ◽  
H. de Souza ◽  
W. Doherty
Keyword(s):  
Trace Element ◽  
Crustal Contamination ◽  
Primitive Mantle ◽  
Magma Source ◽  
Magma Type ◽  
Ni Content ◽  
Chemical Signatures ◽  
Mid Ocean Ridge ◽  
Ocean Ridge

Major and trace element data are presented for 2.2 Ga Proterozoic diabase sills from across the Nipissing magmatic province of Ontario. In situ differentiation of the magma coupled with assimilation of Huronian Supergroup roof sediments is responsible for the variation in composition between quartz diabase and granophyric diabase seen within many of the differentiated intrusions. Uniform trace element and isotope ratio signatures, such as La/Sm (2.8 – 3.7) and εNdCHUR (−2.7 to −5.9) characterize chilled margins and undifferentiated quartz diabases. These chemical signatures suggest the existence of a single magma source that was parental to intrusions throughout the magmatic province; this magma has higher La/Sm and lower Ti/Y than primitive mantle and is displaced towards the composition of shales. Most chilled diabases and quartz diabases have a similar Mg# (0.64 and 0.60) and Ni content (98 and 127 ppm), and it is argued that the magma differentiated at depth and was emplaced as a uniform low-Mg magma. The Wanapitei intrusion and Kukagami Lake sill are an exception in that although the quartz diabase has La/Sm similar to the Nipissing magma type, which suggests that they came from the same source, the Mg# (0.68–0.71) and Ni content (130–141 ppm) are higher, which may suggest that they are either slightly more primitive examples of the normal Nipissing magma or that cumulus hypersthene has been resorbed. The light rare earth element enriched signature of the Nipissing magmas was perhaps introduced from the continental crust as the magma migrated from the mantle to the surface, but a remarkably constant and large amount (>20%) of crustal contamination would be required. An addition of 1 –3% shale to the source of a transitional mid-ocean ridge basalt type magma can broadly reproduce the compositional features of the Nipissing magma type. The source characteristics were perhaps imparted during subduction accompanying the terminal Kenoran orogeny.

Petrogenesis of a calc-alkaline lamprophyre (minette) from Thanewasna, western Bastar craton, Central India: Insights from mineral, bulk rock and in situ trace element geochemistry

2021 ◽  
pp. SP513-2020-258
Author(s):  
Muduru Lachhana Dora ◽  
Kirtikumar Randive ◽  
Rajkumar Meshram ◽  
Tushar Meshram ◽  
Srinivas Rao Baswani ◽  
...  
Keyword(s):  
Trace Element ◽  
Crustal Contamination ◽  
Central India ◽  
Primitive Mantle ◽  
Trace Element Geochemistry ◽  
Calc Alkaline ◽  
Element Geochemistry ◽  
Bastar Craton ◽  
Supplementary Material

AbstractThe lamproites and kimberlites are well known from the eastern Bastar craton, Central India. However, a Proterozoic lamprophyre dyke is discussed here, from the Western Bastar Craton (WBC). The field geology, petrographic, mineralogical, and whole-rock, and in situ trace element geochemistry of biotite were described for understanding its petrogenesis and lithospheric evolution in the WBC. The Thanewasna lamprophyre (TL) is undeformed and unmetamorphosed, intruded into ca.2.5 Ga charnockite and metagabbro but closely associated with ca. 1.62 Ga undeformed Mul granite. The TL has a characteristic porphyritic texture, dominated by phenocrysts of biotite, microphenocryst of amphibole, clinopyroxene, and a groundmass controlled by feldspar. Mineral chemistry of biotite and amphibole suggest a calc-alkaline (CAL) type, and pyroxene chemistry reveals an orogenic setting. The TL is characterized by high SiO2 and low TiO2, MgO, Ni, and Cr, consistent with its subcontinental lithospheric origin. The presence of crustal xenolith and ocelli texture followed by observed variations in Th/Yb, Hf/Sm, La/Nb, Ta/La, Nb/Yb, Ba/Nb indicate substantial crustal contamination. Whole-rock and in situ biotite analysis by LA-ICPMS show low concentrations of Ni (30-50 ppm) and Cr (70-150 ppm), point to the parental magma evolved nature. Enrichment in H2O, reflected in magmatic mica dominance, combined with high LILE, Th/Yb ratios, and striking negative Nb-Ta anomalies in trace element patterns, is consistent with a source that was metasomatized by hydrous fluids corresponding to those generated by subduction-related processes. Significant Zr-Hf and Ti anomalies in the primitive mantle normalized multi-element plots and the REE pattern of the TL, similar to the global calc-alkaline average trend, including eastern Dharwar craton lamprophyres. Our findings provide substantial petrological and geochemical constraints on petrogenesis and geodynamics. However, the geodynamic trigger that generated CAL magmatism and its role in Cu-Au metallogeny in the WBC, central India, is presently indistinct in the absence of isotopic studies. Nevertheless, the lamprophyre dyke is emplaced close to the Cu-(Au) deposit at Thanewasna.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5361958

Platinum-group element geochemistry of intraplate basalts from the Aleppo Plateau, NW Syria

2012 ◽  
Vol 150 (3) ◽  
pp. 497-508 ◽  
Author(s):  
GEORGE S.-K. MA ◽  
JOHN MALPAS ◽  
JIAN-FENG GAO ◽  
KUO-LUNG WANG ◽  
LIANG QI ◽  
...  
Keyword(s):  
Partial Melting ◽  
Middle Miocene ◽  
Primitive Mantle ◽  
Element Geochemistry ◽  
Alkali Basalts ◽  
Melt Extraction ◽  
Mid Ocean Ridge ◽  
Order Of Magnitude ◽  
Platinum Group ◽  
Ocean Ridge

AbstractEarly–Middle Miocene intraplate basalts from the Aleppo Plateau, NW Syria have been analysed for their platinum-group elements (PGEs). They contain extremely low PGE abundances, comparable with most alkali basalts, such as those from Hawaii, and mid-ocean ridge basalts. The low abundances, together with high Pd/Ir, Pt/Ir, Ni/Ir, Cu/Pd, Y/Pt and Cu/Zr are consistent with sulphide fractionation, which likely occurred during partial melting and melt extraction within the mantle. Some of the basalts are too depleted in PGEs to be explained solely by partial melting of a primitive mantle-like source. Such ultra-low PGE abundances, however, are possible if the source contains some mafic lithologies. Many of the basalts also exhibit suprachondritic Pd/Pt ratios of up to an order of magnitude higher than primitive mantle and chondrite, an increase too high to be attributable to fractionation of spinel and silicate minerals alone. The elevated Pd/Pt, associated with a decrease in Pt but not Ir and Ru, are also inconsistent with removal of Pt-bearing PGE minerals or alloys, which should have concurrently lowered Pt, Ir and Ru. In contrast, melting of a metasomatized source comprising sulphides whose Pt and to a lesser extent Rh were selectively mobilized through interaction with silicate melts, may provide an explanation.

A near-ridge origin for seamounts at the southern terminus of the Pratt-Welker Seamount Chain, northeast Pacific Ocean

1999 ◽  
Vol 36 (6) ◽  
pp. 1021-1031 ◽  
Author(s):  
Brian Cousens ◽  
Jarda Dostal ◽  
T S Hamilton
Keyword(s):  
Gulf Of Alaska ◽  
Trace Element Composition ◽  
Primitive Mantle ◽  
Sea Floor ◽  
Northeast Pacific ◽  
Mid Ocean Ridge ◽  
Mantle Sources ◽  
Juan De Fuca ◽  
Seamount Chain ◽  
Ocean Ridge

Three seamounts close to the south end of the Pratt-Welker Seamount Chain, Gulf of Alaska, have been sampled to test whether or not mantle plume-related volcanism extends south of Bowie Seamount. Lavas recovered from Oshawa, Drifters, and Graham seamounts are weathered, Mn-encrusted pillow lavas and sheet-flow fragments, commonly with glassy rims. The glasses and holocrystalline rocks are tholeiitic basalts, with light rare earth element depleted to flat primitive mantle normalized incompatible element patterns and radiogenic isotope compositions within the ranges of mid-ocean ridge and near-ridge seamount basalts from the Explorer and northern Juan de Fuca ridges. Chemically, the seamount lavas strongly resemble older, "shield-phase" tholeiitic rocks dredged from the flanks of southern Pratt-Welker seamounts, but are distinct from the younger alkaline intraplate lavas that cap Pratt-Welker edifices. The weathered, encrusted basalts were most likely erupted in a near-ridge environment, adjacent to Explorer Ridge, between 11 and 14 Ma. No evidence of plume-related activity is found in this area. Compared with northeast Pacific mid-ocean ridge and alkaline intraplate basalts, Graham seamount lavas have anomalously high 206Pb/204Pb, which does not appear to be a function of sea-floor alteration, magma contamination, or mixing between previously identified mantle components. All near-ridge seamounts in the northeast Pacific exhibit isotopic heterogeneity that does not correlate with major or trace element composition, suggesting that the mantle sources of all near-ridge seamounts have been variably depleted by prior, but recent melting events.

scholarly journals Differentiating between Inherited and Autocrystic Zircon in Granitoids

2020 ◽  
Vol 61 (8) ◽  
Author(s):  
Hugo K H Olierook ◽  
Christopher L Kirkland ◽  
Kristoffer Szilas ◽  
Julie A Hollis ◽  
Nicholas J Gardiner ◽  
...  
Keyword(s):  
Trace Element ◽  
Source Region ◽  
Wall Rock ◽  
Magma Source ◽  
Trace Element Data ◽  
Element Data ◽  
Age Constraints ◽  
Erroneous Interpretation ◽  
Zircon Fraction

Abstract Inherited zircon, crystals that did not form in situ from their host magma but were incorporated from either the source region or assimilated from the wall-rock, is common but can be difficult to identify. Age, chemical and/or textural dissimilarity to the youngest zircon fraction are the primary mechanisms of distinguishing such grains. However, in Zr-undersaturated magmas, the entire zircon population may be inherited and, if not identifiable via textural constraints, can lead to erroneous interpretation of magmatic crystallization age and magma source. Here, we present detailed field mapping of cross-cutting relationships, whole-rock geochemistry and zircon textural, U–Pb and trace element data for trondhjemite, granodiorite and granite from two localities in a complex Archean gneiss terrane in SW Greenland, which reveal cryptic zircon inheritance. Zircon textural, U–Pb and trace element data demonstrate that, in both localities, trondhjemite is the oldest rock (3011 ± 5 Ma, 2σ), which is intruded by granodiorite (2978 ± 4 Ma, 2σ). However, granite intrusions, constrained by cross-cutting relationships as the youngest component, contain only inherited zircon derived from trondhjemite and granodiorite based on ages and trace element concentrations. Without age constraints on the older two lithologies, it would be tempting to consider the youngest zircon fraction as recording crystallization of the granite but this would be erroneous. Furthermore, whole-rock geochemistry indicates that the granite contains only 6 µg g–1 Zr, extremely low for a granitoid with ∼77 wt% SiO2. Such low Zr concentration explains the lack of autocrystic zircon in the granite. We expand on a differentiation tool that uses Th/U ratios in zircon versus that in the whole-rock to aid in the identification of inherited zircon. This work emphasizes the need for field observations, geochemistry, grain characterization, and precise geochronology to accurately determine igneous crystallization ages and differentiate between inherited and autocrystic zircon.

Age and radiogenic isotopic systematics of the Borden carbonatite complex, Ontario, Canada

1987 ◽  
Vol 24 (1) ◽  
pp. 24-30 ◽  
Author(s):  
Keith Bell ◽  
John Blenkinsop ◽  
S. T. Kwon ◽  
G. R. Tilton ◽  
R. P. Sage
Keyword(s):  
Upper Mantle ◽  
Volcanic Rocks ◽  
Crustal Contamination ◽  
Growth Curves ◽  
Carbonatite Complex ◽  
Northern Ontario ◽  
Mantle Origin ◽  
Mid Ocean Ridge ◽  
Ocean Ridge ◽  
Isotope Correlation

Rb–Sr and U–Pb data from the Borden complex of northern Ontario, a carbonatite associated with the Kapuskasing Structural Zone, indicate a mid-Proterozoic age. A 207Pb/206Pb age of 1872 ± 13 Ma is interpreted as the emplacement age of this body, grouping it with other ca. 1900 Ma complexes that are the oldest known carbonatites associated with the Kapuskasing structure. A 206Pb–238U age of 1894 ± 29 Ma agrees with the Pb–Pb age but has a high mean square of weighted deviates (MSWD) of 42. A Rb–Sr apatite–carbonate–mica whole-rock isochron date of 1807 ± 13 Ma probably indicates later resetting of the Rb–Sr system.An εSr(T) value of −6.2 ± 0.5 (87Sr/86Sr = 0.70184 ± 0.00003) and an εNd(T) value of +2.8 ± 0.4 for Borden indicate derivation of the Sr and Nd from a source with a time-integrated depletion in the large-ion lithophile (LIL) elements. These closely resemble the ε values for Sr and Nd from the Cargill and Spanish River complexes, two other 1900 Ma plutons. The estimated initial 207Pb/204Pb and 206Pb/204Pb ratios from Borden calcites plot significantly below growth curves for average continental crust in isotope correlation diagrams, a pattern similar to those found in mid-ocean ridge basalts (MORB) and most ocean-island volcanic rocks, again suggesting a source depleted in LIL elements. The combined Nd and Sr, and probably Pb, data strongly favour a mantle origin for the Borden complex with little or no crustal contamination and support the model of Bell et al. that many carbonatites intruded into the Canadian Shield were derived from an ancient, LIL-depleted subcontinental upper mantle.

Relative contribution of crust and mantle to flood basalt magmatism, Mahabaleshwar area, Deccan Traps

1984 ◽  
Vol 310 (1514) ◽  
pp. 627-641 ◽  
Keyword(s):  
Trace Element ◽  
Incompatible Element ◽  
Crustal Contamination ◽  
Flood Basalt ◽  
Oceanic Islands ◽  
Magma Type ◽  
Relative Contribution ◽  
History Of ◽  
Crustal Contribution ◽  
Element Enrichment

The 1200 m section of flat-lying basalts in the Mahabaleshwar area is divided into three formations on the basis of the trace elements Sr, Ba, Rb, Zr and Nb. The lowermost unit, the Poladpur Formation, is characterized by high Ba, Rb, and Zr/Nb, and low Sr. These features are accompanied by high K and Si, high and variable 87 Sr/ 86 Sr initial ratios (0.7043 - 0.7196), and low and variable e N d values (+ 2.6 to -17.4). The formation is interpreted as having developed by contamination of the overlying Ambenali magma-type with ancient granitic crust, with simultaneous fractionation of a gabbroic mineral assemblage. The more basic members of the formation are found towards the base of the succession and are more contaminated than the upper flows. The succeeding Ambenali Formation, characterized by the Ambenali magma type, has low Ba, Rb, Sr and Zr/Nb, and low and rather uniform 87 Sr/ 86 Sr initial ratios (0.7038-0.7043) coupled with high and relatively uniform e N d (+4.7 to +6.4). It is interpreted as being essentially uncontaminated and derived from a mantle source with a history of slight trace-element enrichment relative to m.o.r.b.-source. The uppermost group of flows, the Mahabaleshwar Formation, is, like the Poladpur, enriched in Ba, Rb, K and Si relative to the Ambenali, but has lower Zr/Nb and higher Sr. 87 Sr/ 86 Sr initial ratios (0.7040-0.7056) are slightly higher than in the Ambenali, and e N d lies in the range +7.1 to -3.0. In this formation Sr correlates positively with the other incompatible elements and with 87 Sr/ 86 Sr initial ratios. This is in strong contrast to the relations observed in the Poladpur, and we believe that the behaviour of Sr may be a simple pointer to the distinction between mantle and crustal contributions. Assuming that late-stage crystal fractionation processes can be allowed for, if Sr correlates positively with elements such as K, Rb and Ba then mantle enrichment processes are clearly implied. Conversely, as for example in the Poladpur, if the correlation is negative, crustal contamination is suspected because Sr is unlikely to behave as an incompatible element in most crustal derived melts or fluids because of buffering by residual plagioclase. Furthermore, the relative uniformity of the Mahabaleshwar Formation, the position on the Sr and Nd isotope diagram close to the ‘mantle array’, the fact that in terms of both incompatible element concentrations and isotopes the rocks are similar to tholeiites from oceanic islands such as Hawaii and Kerguelen, are all factors that reinforce the conclusion that these are mantle derived magmas which have suffered insignificant crustal contamination. They are, however, derived from a mantle which is trace-element enriched relative to the Ambenali source. Thus in the succession as a whole the crustal contribution appears to be small. Maximum amounts of contamination in the Poladpur Formation are difficult to determine but the average amount is probably in the region of 6-12 percentage mass. The whole sequence therefore contains a crustal contribution of about 2-3%.

Element fluxes associated with subduction related magmatism

1991 ◽  
Vol 335 (1638) ◽  
pp. 393-405 ◽  
Keyword(s):  
Trace Element ◽  
Incompatible Element ◽  
Mantle Wedge ◽  
Isotope Ratios ◽  
Noticeable Effect ◽  
Arc Magmas ◽  
Mid Ocean Ridge ◽  
Ocean Ridge ◽  
Arc Magma ◽  
Subducted Sediment

Destructive plate margin magmas may be subdivided into two groups on the basis of their rare earth element (REE) ratios. Most island arc suites have low Ce/Yb, and remarkably restricted isotope ratios of 87 Sr/ 86 Sr = 0.7033, 143 Nd/ 144 Nd = 0.51302, 206 Pb/ 204 Pb = 18.76 , 207 Pb/ 204 Pb = 15.57, and 208 Pb/ 204 Pb = 38.4. However, they also have Rb/Sr (0.03), Th/U (2.2) and Ce/Yb (8.5) ratios which are significantly less than accepted estimates for the bulk continental crust. The high Ce/Yb suites have higher incompatible element contents, more restricted heavy REE, and much more variable isotope ratios. Such rocks are found in the Aeolian Islands, Grenada, Indonesia and Philippines, and their isotope and trace element features have been attributed both to contributions from subducted sediment, and/or old trace element enriched material in the mantle wedge. It is argued that for isotope and trace element models the slab component can usefully be taken to consist of subducted sediment and altered mid-ocean ridge basalts, since these may contain ca. 80% of the water in the subducted slab, and the distinctive trace element features of arc magmas are generally attributed to the movement of material in hydrous fluids. The isotope data indicate that not more than 15% of the Sr and Th in an average arc magma were derived from subducted material, and that the rest were derived from the mantle wedge. The fluxes of elements which cannot be characterized isotopically are more difficult to constrain, but for most minor and trace elements the slab derived contribution in arc magmas is too small to have a noticeable effect on the residual slab.

Isotopic and trace element constraints on the genesis of a boninitic sequence in the Thetford Mines ophiolitic complex, Quebec, Canada

1997 ◽  
Vol 34 (9) ◽  
pp. 1258-1271 ◽  
Author(s):  
Valérie Olive ◽  
Réjean Hébert ◽  
Michel Loubet
Keyword(s):  
Trace Element ◽  
Trace Element Composition ◽  
Nd Isotope ◽  
Geodynamic Environment ◽  
The Pacific ◽  
Geochemical Study ◽  
Mid Ocean Ridge ◽  
Isochron Diagram ◽  
Component C ◽  
Ocean Ridge

The Mont Ham Massif (part of the Thetford Mines ophiolite, south Quebec) represents a magmatic sequence made up of tholeiitic and boninitic derived products. A geochemical study confirms the multicomponent mixing models that have been classically advanced for the source of boninites, with slab-derived components added to the main refractory harzburgitic peridotite. An isochron diagram of the boninitic rocks is interpreted as a mixing trend between two components: (i) a light rare earth element (LREE) enriched component (A), interpreted as slab-derived fluid–melts equilibrated with sedimentary materials (εNd = −3, 147Sm/144Nd = 0.140), and (ii) a LREE-depleted component (B) (0.21 < 147Sm/144Nd < 0.23), interpreted as slab-derived fluid–melt equilibrated with recycled Iapetus oceanic crust and equated to the Nd-isotope characteristics of the Iapetus mantle (εNd = 9). A multicomponent source is also necessary to explain the Nd-isotope and trace element composition of the tholeiites, which are explained by the melting of a more fertile, lherzolitic mantle and (or) mid-ocean ridge basalt source (component C), characterized by a large-ion lithophile element depleted pattern and an Iapetus mantle Nd isotopic composition (εNd = 9), mixed in adequate proportions with the two previously infered slab-derived components (A and B). The genesis of the boninites of Mont Ham is not significantly different from those of boninites located in the Pacific. An intraoceanic subduction zone appears to be an appropriate geodynamic environment for the Mont Ham ophiolitic sequence.

scholarly journals Variations of Source Composition and Melting Degrees of Olivine-Phyric Rocks from Kamchatsky Mys: Results of Geochemical Modeling of Trace Element Contents in Melts

Petrology ◽  
2021 ◽  
Vol 29 (1) ◽  
pp. 14-23
Author(s):  
N. Nekrylov ◽  
A. A. Korneeva ◽  
D. P. Savelyev ◽  
T. N. Antsiferova
Keyword(s):  
Trace Element ◽  
Geochemical Modeling ◽  
Magmatic Evolution ◽  
Mid Ocean Ridge ◽  
Trace Element Contents ◽  
Fractional Melting ◽  
Element Contents ◽  
Ocean Ridge ◽  
Batch Melting ◽  
Good Agreement

Abstract We conducted the geochemical modeling of trace element contents for primary melts of olivine-phyric rocks from Kamchatsky Mys. This modeling reveals substantial chemical heterogeneity of their source while the average source composition is close to the enriched DMM (E-DMM). The average estimation of the melting degree is in the range from 9.1 ± 3.8% for the model of modal batch melting to 15.4 ± 5.2% for the model of accumulated fractional melting, which is slightly higher than the estimation for primitive mid-ocean ridge basalt (MORB) glasses (7.4 ± 2.2% and 12.5 ± 3.8% respectively). It is in a good agreement with high melting degrees estimated earlier for other rocks of the Kamchatsky Mys ophiolites. Low pressure of mantle melting caused by the elevated speed of decompression relative to the average MORB could explain elevated melting degrees estimated for Kamhcatsky Mys ophiolites as well as their characteristic Sr-anomalies and sulfide saturation on the earliest stages of magmatic evolution.

scholarly journals Supplemental Material: A model involving amphibolite lower crust melting and subsequent melt extraction for leucogranite generation

2021 ◽  
Author(s):  
Liqiang Wang ◽  
et. al
Keyword(s):  
Trace Element ◽  
Lower Crust ◽  
Partition Coefficients ◽  
Geochemical Modeling ◽  
Magma Source ◽  
Isotopic Data ◽  
Melt Extraction ◽  
Isotopic Compositions ◽  
Age Determinations

Table S1: Isotopic data of U-Pb age determinations on zircons of the Anglonggangri biotite-muscovite and garnet-muscovite granites; Table S2: 40Ar-39Ar dating results for muscovite from the pegmatite in the Anglonggangri area; Table S3: Whole-rock major and trace element compositions of the Anglonggangri biotite-muscovite and garnet-muscovite granites; Table S4: Whole-rock Pb isotopic compositions of the Anglonggangri biotite-muscovite and garnet-muscovite granites; Table S5: Zircon in situ Lu-Hf isotopic compositions of the Anglonggangri biotite-muscovite granite; Table S6: Partition coefficients and assumed magma source compositions used in geochemical modeling; Table S7: Partition coefficients and assumed compositions used in geochemical modeling and the calculated results.

Sign in / Sign up

Export Citation Format

Share Document