Quantitative Aerobic Oxidation of Primary Benzylic Alcohols to Aldehydes Catalyzed by Highly Efficient and Recyclable P123-Stabilized Pd Nanoclusters in Acidic Aqueous Solution

ACS Catalysis ◽  
2013 ◽  
Vol 3 (12) ◽  
pp. 3063-3066 ◽  
Author(s):  
Ruirui Dun ◽  
Xueguang Wang ◽  
Mingwu Tan ◽  
Zhen Huang ◽  
Xuemin Huang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Aerobic Oxidation ◽  
Acidic Aqueous Solution ◽  
Benzylic Alcohols ◽  
Highly Efficient

Bimetallic Pd/Al particles for highly efficient hydrodechlorination of 2-chlorobiphenyl in acidic aqueous solution

2011 ◽  
Vol 189 (1-2) ◽  
pp. 76-83 ◽  
Author(s):  
Bo Yang ◽  
Shubo Deng ◽  
Gang Yu ◽  
Hong Zhang ◽  
Jinhua Wu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Acidic Aqueous Solution ◽  
Highly Efficient

scholarly journals Reduction of benzylic alcohols and α-hydroxycarbonyl compounds by hydriodic acid in a biphasic reaction medium

2012 ◽  
Vol 8 ◽  
pp. 330-336 ◽  
Author(s):  
Michael Dobmeier ◽  
Josef M Herrmann ◽  
Dieter Lenoir ◽  
Burkhard König
Keyword(s):  
Aqueous Solution ◽  
Organic Synthesis ◽  
Reaction Times ◽  
Reaction Medium ◽  
Hydriodic Acid ◽  
Reducing Agent ◽  
Acidic Aqueous Solution ◽  
Keto Ester ◽  
Benzylic Alcohols ◽  
Biphasic Reaction

The synthetic protocol for the reduction of alcohols to hydrocarbons by using hydriodic acid, first described by Kiliani more than 140 years ago, was improved to be more applicable to organic synthesis. Instead of a strongly acidic, aqueous solution, a biphasic toluene–water reaction medium was used, which allowed the conversion of primary, secondary and tertiary benzylic alcohols, in good yields and short reaction times, into the corresponding hydrocarbons. Red phosphorous was used as the stoichiometric reducing agent. Keto, ester, amide or ether groups are tolerated, and catalytic amounts of hydriodic acid (0.2 equiv) in the presence of 0.6 equiv phosphorous are sufficient to achieve conversion.

Synthesis and characterization of copper(ii) 4′-phenyl-terpyridine compounds and catalytic application for aerobic oxidation of benzylic alcohols

2014 ◽  
Vol 43 (10) ◽  
pp. 4048-4058 ◽  
Author(s):  
Zhen Ma ◽  
Lijuan Wei ◽  
Elisabete C. B. A. Alegria ◽  
Luísa M. D. R. S. Martins ◽  
M. Fátima C. Guedes da Silva ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Catalytic Activity ◽  
Aerobic Oxidation ◽  
Synthesis And Characterization ◽  
Benzylic Alcohols ◽  
Mild Conditions ◽  
Catalytic Application ◽  
Alkaline Aqueous Solution

Cu(ii)-terpyridine complexes in combination with TEMPO exhibit catalytic activity, under mild conditions and in alkaline aqueous solution, for the aerobic oxidation of benzylic alcohols.

Highly efficient and selective photocatalytic CO2 to CO conversion in aqueous solution

2020 ◽  
Vol 56 (27) ◽  
pp. 3851-3854 ◽  
Author(s):  
Xiaomin Chai ◽  
Hai-Hua Huang ◽  
Huiping Liu ◽  
Zhuofeng Ke ◽  
Wen-Wen Yong ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Photocatalytic Performance ◽  
Aqueous Media ◽  
Highly Efficient ◽  
Co Conversion

A Co-based complex displayed the highest photocatalytic performance for CO2 to CO conversion in aqueous media.

Engineering the surface of cuprous oxide via surface coordination for efficient catalysis on aerobic oxidation of benzylic alcohols under ambient conditions

2021 ◽  
Vol 543 ◽  
pp. 148840
Author(s):  
Yunlian Yang ◽  
Wei Zhong ◽  
Ruonan Ma ◽  
Chunxin Lu ◽  
Zhongquan Shen ◽  
...  
Keyword(s):  
Cuprous Oxide ◽  
Aerobic Oxidation ◽  
Ambient Conditions ◽  
Benzylic Alcohols

Visible-light-responsive lanthanide coordination polymers for highly efficient photocatalytic aerobic oxidation of amines and thiols

2021 ◽  
Author(s):  
Zhifen Guo ◽  
Xin Liu ◽  
Yan Che ◽  
Hongzhu Xing ◽  
Peng Chen
Keyword(s):  
Visible Light ◽  
Molecular Oxygen ◽  
Coordination Polymers ◽  
Aerobic Oxidation ◽  
Synthesis And Characterization ◽  
Lanthanide Coordination Polymers ◽  
Highly Efficient ◽  
Photocatalytic Reactions ◽  
Energy Issues

Development of visible-light-induced photocatalytic reactions using molecular oxygen as terminal oxidant is intriguing in view of the current environmental and energy issues. We report herein the synthesis and characterization of...

scholarly journals Highly efficient electrochemiluminescence of quinoline and isoquinoline in aqueous solution

2019 ◽  
Vol 101 ◽  
pp. 19-22 ◽  
Author(s):  
Xiangxiang Qin ◽  
Xia Xu ◽  
Jing Lu ◽  
Yinggui Zhu
Keyword(s):  
Aqueous Solution ◽  
Highly Efficient
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