Properties of Particles in the Fly Ash of a Biofuel-Fired Circulating Fluidized Bed (CFB) Boiler

2008 ◽  
Vol 22 (5) ◽  
pp. 3005-3015 ◽  
Author(s):  
Linda S. Johansson ◽  
Bo Leckner ◽  
Claes Tullin ◽  
Lars-Erik Åmand ◽  
Kent Davidsson
2011 ◽  
Vol 354-355 ◽  
pp. 413-416
Author(s):  
Yan Jin ◽  
Cui Ying Feng ◽  
Juan Juan Liu

Circulating fluidized bed (CFB) combustion techniques have been widely used in China. In order to improve CFB boiler performance it is necessary to study on microstructures of fly-ash. With the help of nitrogen adsorption instrument and scanning electron microscopy, the pore structure of fly-ash in circulating fluidized bed boilers are studied by nitrogen adsorption/desorption isotherms of fly-ash, hysteresis loop and pore distribution. The results indicated that different particle sizes of fly-ash in CFB boilers are of similar nitrogen adsorption isotherms, pore types and the pore size distribution, and the most probable pore radius of fly-ash is about 2nm. Adsorption isotherms of fly-ash is the second type, and the macro-porous and meso-porous types are tapered hole, parallel plate slit hole and the ink bottle shape hole. And meso-pore in proportion is the largest. Micro-pores are not discovered in fly-ash from CFB boilers.


2017 ◽  
Vol 11 (1) ◽  
pp. 176-186 ◽  
Author(s):  
Kae- Long Lin ◽  
Ta-Wui Cheng ◽  
Chih-Hsuan Ho ◽  
Yu-Min Chang ◽  
Kang-Wei Lo

A circulating fluidized bed (CFB) boiler generates energy by burning petroleum coke. Because burnt petroleum coke has a high sulfur content, limestone is added to the boiler to reduce the emittance of sulfur dioxide through desulfuration. The residue collected from the boiler is called CFB ash. CFB boilers in Taiwan can produce 328,000 tonnes of CFB fly ash per year. In this study, the pozzolanic characteristics of CFB fly ash were investigated by blending CFB fly ash and ordinary Portland cement (OPC). The CFB fly ash was mainly composed of CaO, SO3, and SiO2 in concentrations of 37.8%, 9.2%, and 2.2%, respectively. The crystals of CFB fly ash contained 3CaO.SiO2, 2CaO.SiO2, Ca(OH)2, C-S-H (Tobermolite), and Ettringite. The results revealed that applying the toxicity characteristic leaching procedure to CFB fly ash renders it suitable for use in blended cement. At later curing ages (90 days), the pore volumes of both the OPC and the CFB-fly-ash-blended cement pastes (CFBFABCP) decreased as the curing time increased. A possible explanation is that C3S and C2S were consumed to form C-S-H gel, resulting in an increase in the Q1 and Q2 groups identified by 29Si Nuclear Magnetic Resonance (NMR) spectroscopy. Furthermore, the peak of the Q0 group decreased, but those of the Q1 and Q2 peaks increased with an increasing curing time. The pozzolanic activity of the CFBFABCP containing 10% CFB fly ash indicates that it is a suitable substitute for OPC in blended cement.


Author(s):  
Matteo Bruzzone ◽  
Silvia Ravelli

It is well known that the Łagisza power plant in Poland is the world’s first supercritical circulating fluidized bed (CFB) boiler, whose commercial operation started on June 2009. It has attracted a great deal of interest and operational data are publicly available, therefore it has been chosen as the object of the present study aimed at assessing load and fuel flexibility of supercritical CFB plants. First, the thermal cycle was modelled, by means of the commercial code Thermoflex®, at nominal and part load conditions for validation purposes. After having verified the validity of the applied modelling and simulation tool, the advantage of having supercritical steam combined with CFB boiler over subcritical steam and pulverized coal (PC) boiler, respectively, was quantified in terms of electric efficiency. As a next step, the designed fuel, i.e. locally mined hard coal, was replaced with biomass: 100% biomass firing was taken into account in the case of subcritical CFB boiler whereas the maximum share of biomass with coal was set at 50% with supercritical CFB boiler, consistently with the guidelines provided by the world leading manufacturers of CFB units. A broad range of biomass types was tested to conceive mixtures of fuel capable of preserving quite high performance, despite the energy consumption in pretreatment. However, the overall efficiency penalty, due to biomass co-firing, was found to potentially undermine the benefit of supercritical steam conditions compared to conventional subcritical power cycles. Indeed, the use of low-quality biomass in thermal power generation based on steam Rankine cycle may frustrate efforts to push the steam cycle boundaries.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3106
Author(s):  
Tomasz Kalak ◽  
Kinga Marciszewicz ◽  
Joanna Piepiórka-Stepuk

Recently, more and more attention has been paid to the removal of nickel ions due to their negative effects on the environment and human health. In this research, fly ash obtained as a result of incineration of municipal sewage sludge with the use of circulating fluidized bed combustion (CFBC) technology was used to analyze the possibility of removing Ni(II) ions in adsorption processes. The properties of the material were determined using analytical methods, such as SEM-EDS, XRD, BET, BJH, thermogravimetry, zeta potential, SEM, and FT-IR. Several factors were analyzed, such as adsorbent dose, initial pH, initial concentration, and contact time. As a result of the conducted research, the maximum sorption efficiency was obtained at the level of 99.9%. The kinetics analysis and isotherms showed that the pseudo-second order equation model and the Freundlich isotherm model best suited this process. In conclusion, sewage sludge fly ash may be a suitable material for the effective removal of nickel from wastewater and the improvement of water quality. This research is in line with current trends in the concepts of circular economy and sustainable development.


2014 ◽  
Vol 629-630 ◽  
pp. 306-313 ◽  
Author(s):  
Mao Chieh Chi ◽  
Ran Huang ◽  
Te Hsien Wu ◽  
Toun Chun Fou

Circulating fluidized bed combustion (CFBC) fly ash is a promising admixture for construction and building materials due to its pozzolanic activity and self-cementitious property. In this study, CFBC fly ash and coal-fired fly ash were used in Portland cement to investigate the pozzolanic and cementitious characteristics of CFBC fly ash and the properties of cement-based composites. Tests show that CFBC fly ash has the potential instead of cementing materials and as an alternative of pozzolan. In fresh specimens, the initial setting time of mortars increases with the increasing amount of cement replacement by CFBC fly ash and coal-fire fly ash. In harden specimens, adding CFBC fly ash to replace OPC reduces the compressive strength. Meanwhile, CFBC fly ash would results in a higher length change when adding over 30%. Based on the results, the amount of CFBC fly ash replacement cement was recommended to be limited below 20%.


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