Fabrication and Electrochemical Treatment Application of A Novel Lead Dioxide Anode with Superhydrophobic Surfaces, High Oxygen Evolution Potential, and Oxidation Capability

2010 ◽  
Vol 44 (5) ◽  
pp. 1754-1759 ◽  
Author(s):  
Guohua Zhao ◽  
Yonggang Zhang ◽  
Yanzhu lei ◽  
Baoying Lv ◽  
Junxia Gao ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Lead Dioxide ◽  
Electrochemical Treatment ◽  
High Oxygen ◽  
Superhydrophobic Surfaces ◽  
Lead Dioxide Anode ◽  
Treatment Application

The effect of Cobalt on the Kinetics of Oxygen evolution at a Lead Dioxide anode in Sulphuric Acid

1959 ◽  
Vol 12 (2) ◽  
pp. 127 ◽  
Author(s):  
DFA Koch
Keyword(s):  
Sulphuric Acid ◽  
Oxygen Evolution ◽  
Current Density ◽  
Lead Dioxide ◽  
Kinetic Constants ◽  
Kcal Mole ◽  
Lead Dioxide Anode ◽  
Kinetics Of ◽  
Evolution Of Oxygen ◽  
Rate Determining Steps

The overpotential (n)-log current density (log i) curves for the evolution of oxygen at a lead dioxide anode in 2N H2SO4 both in the absence and presence of cobaltous sulphate in solution have been used to determine the electrode kinetic constants α ; i0 for a series of temperatures and also ΔH0*:. At 25 �C in the absence of cobalt α=O.59, i0= 10-11, and ΔH0*= 15 kcal mole-1 When 13 mg/l cobaltous sulphate is added α= 1.0, i0= 10-15, and ΔH0*:=29 kcal mole-1. Possible mechanisms for the reaction are discussed on the basis of these values and the rate determining steps suggested (where M represents the PbO2 surface) are M +H2O =MOH +H+ +e in the absence of cobalt and 2CoOH++ = 2Co++ +H2O + O in its presence.

Fabrication and Electrochemical Treatment Application of an Al-Doped PbO2Electrode with High Oxidation Capability, Oxygen Evolution Potential and Reusability

2015 ◽  
Vol 162 (10) ◽  
pp. E258-E262 ◽  
Author(s):  
Yijing Xia ◽  
Qizhou Dai ◽  
Mili Weng ◽  
Yue Peng ◽  
Jinming Luo ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Electrochemical Treatment ◽  
High Oxidation ◽  
Treatment Application

The Lead Dioxide Anode. II. The Kinetics and Participation of the Lead Dioxide Electrode in Electrochemical Oxidation Reactions in Sulfuric Acid

1989 ◽  
Vol 42 (9) ◽  
pp. 1527 ◽  
Author(s):  
TH Randle ◽  
AT Kuhn
Keyword(s):  
Sulfuric Acid ◽  
Electrochemical Oxidation ◽  
Maximum Rate ◽  
Lead Dioxide ◽  
Chemical Oxidation ◽  
Oxidation Reactions ◽  
Electrochemical Regeneration ◽  
Electrode Surfaces ◽  
Lead Dioxide Electrode ◽  
Lead Dioxide Anode

Lead dioxide is a strong oxidizer in sulfuric acid, consequently electrochemical oxidation of solution species at a lead dioxide anode may occur by a two-step, C-E process (chemical oxidation of solution species by PbO2 followed by electrochemical regeneration of the reduced lead dioxide surface). The maximum rate of each step has been determined in sulfuric acid for specified lead dioxide surfaces and compared with the rates observed for the electrochemical oxidation of cerium(III) and manganese(II) on the same electrode surfaces. While the rate of electrochemical oxidation of a partially reduced PbO2 surface may be sufficient to support the observed rates of CeIII and MnII oxidation at the lead dioxide anode, the rate of chemical reaction between PbO2 and the reducing species is not. Hence it is concluded that the lead dioxide electrode functions as a simple, 'inert' electron-transfer agent during the electrochemical oxidation of CellI and MnII in sulfuric acid. In general, it will most probably be the rate of the chemical step which determines the feasibility or otherwise of the C-E mechanism.

Lead Dioxide Anode for Commercial Use

1958 ◽  
Vol 105 (2) ◽  
pp. 100 ◽  
Author(s):  
J. C. Grigger ◽  
H. C. Miller ◽  
F. D. Loomis
Keyword(s):  
Lead Dioxide ◽  
Commercial Use ◽  
Lead Dioxide Anode

2D Electron Gas and Oxygen Vacancy Induced High Oxygen Evolution Performances for Advanced Co 3 O 4 /CeO 2 Nanohybrids

2019 ◽  
Vol 31 (21) ◽  
pp. 1900062 ◽  
Author(s):  
Ying Liu ◽  
Chao Ma ◽  
Qinghua Zhang ◽  
Wei Wang ◽  
Pengfei Pan ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Oxygen Evolution ◽  
Electron Gas ◽  
High Oxygen ◽  
2D Electron Gas

A DFT computational study of the mechanism of super-high oxygen evolution potential of W doped SnO2 anodes

2019 ◽  
Vol 855 ◽  
pp. 113499
Author(s):  
Aqing Chen ◽  
Selvakumar V. Nair ◽  
Bojan Miljkovic ◽  
Harry E. Ruda ◽  
Zhenguo Ji
Keyword(s):  
Oxygen Evolution ◽  
Computational Study ◽  
High Oxygen

Electrocatalytic degradation of the herbicide metamitron using lead dioxide anode: influencing parameters, intermediates, and reaction pathways

2019 ◽  
Vol 26 (26) ◽  
pp. 27032-27042 ◽  
Author(s):  
Yang Yang ◽  
Leilei Cui ◽  
Mengyao Li ◽  
Liman Zhang ◽  
Yingwu Yao
Keyword(s):  
Lead Dioxide ◽  
Reaction Pathways ◽  
Electrocatalytic Degradation ◽  
Lead Dioxide Anode ◽  
Influencing Parameters

High oxygen evolution reaction activity on lithiated nickel oxides - Activity descriptors

2019 ◽  
Vol 318 ◽  
pp. 809-819
Author(s):  
Ravi Sankannavar ◽  
K.C. Sandeep ◽  
Sachin Kamath ◽  
Akkihebbal K. Suresh ◽  
A. Sarkar
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Oxygen ◽  
Nickel Oxides

Construction of tetrahedral CoO4 vacancies for activating the high oxygen evolution activity of Co3−xO4−δ porous nanosheet arrays

Nanoscale ◽  
2020 ◽  
Vol 12 (20) ◽  
pp. 11079-11087 ◽  
Author(s):  
Shenghua Ye ◽  
Yu Zhang ◽  
Wei Xiong ◽  
Tingting Xu ◽  
Peng Liao ◽  
...  
Keyword(s):  
Carbon Fiber ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Oxygen ◽  
Unique Structure ◽  
Carbon Fiber Cloth ◽  
Nanosheet Arrays ◽  
Low Crystalline

Low-crystalline Co3O4 porous nanosheet arrays (PNAs) with tetrahedral CoO4 vacancies, grown on carbon fiber cloth (CFC) (Co3−xO4−δ PNAs/CFC), were synthesized. This unique structure endows Co3−xO4−δ PNAs/CFC with improved activity for the oxygen evolution reaction.

Preparation and electrochemical treatment application of Ti/Sb–SnO2-Eu&rGO electrode in the degradation of clothianidin wastewater

Chemosphere ◽  
2021 ◽  
Vol 265 ◽  
pp. 129126
Author(s):  
Dan Guo ◽  
Yongbo Guo ◽  
Yixuan Huang ◽  
Yongyang Chen ◽  
Xiaochun Dong ◽  
...  
Keyword(s):  
Electrochemical Treatment ◽  
Treatment Application
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