Gas-solid chromatography: method of measuring surface free energy characteristics of short fibers. 2. Through retention volumes measured near zero surface coverage

1982 ◽  
Vol 21 (4) ◽  
pp. 666-669 ◽  
Author(s):  
Carol Saint Flour ◽  
Eugene Papirer

2009 ◽  
Vol 136 (5) ◽  
pp. 668-674 ◽  
Author(s):  
Hyo-Beom Ahn ◽  
Sug-Joon Ahn ◽  
Shin-Jae Lee ◽  
Tae-Woo Kim ◽  
Dong-Seok Nahm


2007 ◽  
Vol 35 (1) ◽  
pp. 100290 ◽  
Author(s):  
DMR Mitchell ◽  
NM Wasiuddin ◽  
CM Fogle ◽  
MM Zaman ◽  
EA O'Rear


Langmuir ◽  
1992 ◽  
Vol 8 (4) ◽  
pp. 1195-1198 ◽  
Author(s):  
Elek Lindner ◽  
Ernest Arias


Polymers ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 59
Author(s):  
Alexey V. Shapagin ◽  
Natalia A. Gladkikh ◽  
Arkadiy A. Poteryaev ◽  
Valentina Yu. Stepanenko ◽  
Uliana V. Nikulova ◽  
...  

The development of universal finishing compositions for fibers of various natures is an urgent task for polymer composite materials science. The developed finishes can be used for the fiber reinforcement of polymer matrices with a wide range of surface free energy characteristics. Epoxy systems modified with diaminesilane in a wide concentration range were examined by optical interferometry, FTIR spectroscopy, DSC and the sessile drop technique. It was shown that the partial curing of epoxy resin by diaminesilane at room temperature under an inert atmosphere, followed by contact with air, leads to a significant increase of the surface free energy of the system. Varying the concentration of diaminesilane allows us to effectively regulate the surface free energy of the composition. This makes it possible to use fibers finished with epoxyaminosilane compositions in composite materials based on a various thermosetting and thermoplastic binders with a surface tension of up to 75 mJ/m2.



2016 ◽  
Vol 124 (4) ◽  
pp. 377-386 ◽  
Author(s):  
Akimasa Tsujimoto ◽  
Wayne W. Barkmeier ◽  
Toshiki Takamizawa ◽  
Hidehiko Watanabe ◽  
William W. Johnson ◽  
...  


1983 ◽  
Vol 17 (1) ◽  
pp. 39-46 ◽  
Author(s):  
H.A.H. Mohammad ◽  
J.T. Fell


1987 ◽  
Vol 65 (8) ◽  
pp. 1935-1939 ◽  
Author(s):  
N. Gurnagul ◽  
D. G. Gray

The adsorption at low surface coverage of a series of n-alkanes on various bleached kraft paper surfaces was measured by gas chromatography. Differences in surface area of the paper samples were readily measured from the gas chromatographic retention volumes. The standard free energy, the enthalpy, and the entropy of adsorption varied linearly with the number of carbon atoms in the n-alkanes. The heats of adsorption were close to the heats of liquefaction, indicating the non-specific interactions of the hydrocarbons with the bleached kraft surfaces. The London component of the surface free energy was estimated from the gas chromatographic results to be 47.9 mN/m.





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