Metal complexes of the new ligand 1,2,6,7-tetracyano-3,5-diimino-3,5-dihydropyrrolizinide, M(II)(C11N7H2)2, as basic units for molecular materials. Electrochemical and metal-phthalocyanine-like electronic properties of the nickel(II) complex and x-ray crystal structures of its adducts with dioxane and tetrathiafulvalene

1991 ◽  
Vol 30 (15) ◽  
pp. 3081-3087 ◽  
Author(s):  
Mario. Bonamico ◽  
Vincenzo. Fares ◽  
Alberto. Flamini ◽  
Nicola. Poli
Keyword(s):  
Metal Complexes ◽  
Electronic Properties ◽  
Crystal Structures ◽  
Metal Phthalocyanine ◽  
Molecular Materials ◽  
X Ray

Intermolecular interactions and electronic properties in phosphino-(oligothiophene) palladium(II) and platinum(II) complexes

2007 ◽  
Vol 85 (5) ◽  
pp. 383-391 ◽  
Author(s):  
Tracey L Stott ◽  
Michael O Wolf ◽  
Brian O Patrick
Keyword(s):  
Solid State ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Crystal Structures ◽  
Structural Properties ◽  
Absorption Spectra ◽  
Intermolecular Interactions ◽  
Electronic Spectra ◽  
X Ray ◽  
Π Stacking

A series of Pt(II) and Pd(II) complexes containing diphenylphosphino-substituted oligothiophene ligands ranging from 1 to 3 thiophene rings in length have been prepared. Crystal structures of four of these complexes were determined via single X-ray crystal diffraction and the solid-state packing arrangements found to vary with both the metal and the thiophene-containing ligand. In some cases, π-stacking between thiophene rings are found for the oligothiophene ligands. Solution and solid-state absorption spectra of these complexes are reported.Key words: oligothiophenes, metal complexes, structural properties, electronic spectra.

Second and third row transition metal complexes of 1,1′-bi-2-naphthol and the X-ray crystal structures of (Bu4nN)[MoO2(acac)(BINO)] (1) and (Bu4nN)2(H2BINO)2[Mo2O7] (2)

Polyhedron ◽  
1997 ◽  
Vol 16 (8) ◽  
pp. 1323-1329 ◽  
Author(s):  
William P. Griffith ◽  
Helena I.S. Nogueira ◽  
Andrew J.P. White ◽  
David J. Williams
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Transition Metal Complexes ◽  
X Ray

Neutral and anionic transition metal complexes supported by decafluorodiphenylamido ligands: X-ray crystal structures of {Na(THF)2}{Ti[N(C6F5)2]4}, {K(η6-C6H5Me)2}{ZrCl2[N(C6F5)2]3}, K{VCl[N(C6F5)2]3}, Fe[N(C6F5)2]2(THF)2 and Co[N(C6F5)2]2(py)2

Polyhedron ◽  
2003 ◽  
Vol 22 (1) ◽  
pp. 153-163 ◽  
Author(s):  
Garth R Giesbrecht ◽  
John C Gordon ◽  
David L Clark ◽  
Cybele A Hijar ◽  
Brian L Scott ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Transition Metal Complexes ◽  
X Ray
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