In Situ Fe K-edge X-ray Absorption Spectroscopy of a Nitrosyl Iron(II) Porphyrin Adduct Adsorbed on a High-Area Carbon Electrode in Aqueous Electrolytes

2001 ◽  
Vol 40 (14) ◽  
pp. 3256-3258 ◽  
Author(s):  
In Tae Bae ◽  
Yuriy Tolmachev ◽  
Yibo Mo ◽  
Daniel Scherson ◽  
W. Robert Scheidt ◽  
...  
1992 ◽  
Vol 324 (1-2) ◽  
pp. 243-258 ◽  
Author(s):  
M.E. Herron ◽  
S.E. Doyle ◽  
S. Pizzini ◽  
K.J. Roberts ◽  
J. Robinson ◽  
...  

2019 ◽  
Author(s):  
Jisue Moon ◽  
Carter Abney ◽  
Dmitriy Dolzhnikov ◽  
James M. Kurley ◽  
Kevin A. Beyer ◽  
...  

The local structure of dilute CrCl<sub>3</sub> in a molten MgCl<sub>2</sub>:KCl salt was investigated by <i>in situ</i> x-ray absorption spectroscopy (XAS) at temperatures from room temperature to 800<sup>o</sup>C. This constitutes the first experiment where dilute Cr speciation is explored in a molten chloride salt, ostensibly due to the compounding challenges arising from a low Cr concentration in a matrix of heavy absorbers at extreme temperatures. CrCl<sub>3</sub> was confirmed to be the stable species between 200 and 500<sup>o</sup>C, while mobility of metal ions at higher temperature (>700<sup>o</sup>C) prevented confirmation of the local structure.


2019 ◽  
Vol 48 (21) ◽  
pp. 7122-7129 ◽  
Author(s):  
Chia-Jui Chang ◽  
You-Chiuan Chu ◽  
Hao-Yu Yan ◽  
Yen-Fa Liao ◽  
Hao Ming Chen

The state-of-art RuO2 catalyst for the oxygen evolution reaction (OER) is measured by using in situ X-ray absorption spectroscopy (XAS) to elucidate the structural transformation during catalyzing the reaction in acidic and alkaline conditions.


2006 ◽  
Vol 77 (2) ◽  
pp. 023105 ◽  
Author(s):  
Simon R. Bare ◽  
George E. Mickelson ◽  
Frank S. Modica ◽  
Andrzej Z. Ringwelski ◽  
N. Yang

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