Synthesis, Ab Initio X-ray Powder Diffraction Crystal Structure, and Magnetic Properties of Mn3(OH)2(C6H2O4S)2 Metal–Organic Framework

2012 ◽  
Vol 52 (2) ◽  
pp. 608-616 ◽  
Author(s):  
Romain Sibille ◽  
Thomas Mazet ◽  
Erik Elkaïm ◽  
Bernard Malaman ◽  
Michel François
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Ab Initio ◽  
Powder Diffraction ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

Prediction of the Conditions for Breathing of Metal Organic Framework Materials Using a Combination of X-ray Powder Diffraction, Microcalorimetry, and Molecular Simulation

2008 ◽  
Vol 130 (38) ◽  
pp. 12808-12814 ◽  
Author(s):  
Philip L. Llewellyn ◽  
Guillaume Maurin ◽  
Thomas Devic ◽  
Sandra Loera-Serna ◽  
Nilton Rosenbach ◽  
...  
Keyword(s):  
Molecular Simulation ◽  
Powder Diffraction ◽  
Metal Organic Framework ◽  
X Ray ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Single crystal structure and photocatalytic behavior of grafted uranyl on the Zr-node of a pyrene-based metal–organic framework

CrystEngComm ◽  
2020 ◽  
Vol 22 (11) ◽  
pp. 2097-2102 ◽  
Author(s):  
Julia G. Knapp ◽  
Xuan Zhang ◽  
Tatyana Elkin ◽  
Laura E. Wolfsberg ◽  
Sylvia L. Hanna ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Uranyl Ion ◽  
Single Crystal Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Photo Oxidation ◽  
Metal Organic ◽  
Organic Framework

The zirconium MOF NU-1000 was post-synthetically modified through solvothermal deposition to include the uranyl ion and characterized via single-crystal X-ray diffraction; photo-oxidation was also performed.

A 2-D Metal–Organic Framework Based on Linear Trinuclear Copper Cluster Units: Syntheses, Structures and Magnetic Properties

2018 ◽  
Vol 42 (4) ◽  
pp. 198-201 ◽  
Author(s):  
Liping Wang ◽  
Erpeng Zhang ◽  
Xiaoli Zhou ◽  
Yufei Wang ◽  
Yanli Liu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Copper Cluster ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

The coordination polymer [Cu3(tci)2(phen)2] n (H3tci = 1,3,5-tris(2-carboxyethyl)isocyanurate; phen = 1,10-phenanthroline) has been synthesised. Single-crystal X-ray diffraction studies have shown that the polymer displays a 2-D metal–organic framework based on linear trinuclear copper cluster units, and its magnetic properties indicate antiferromagnetic interactions.

scholarly journals Reference diffraction patterns, microstructure, and pore-size distribution for the copper (II) benzene-1,3,5-tricarboxylate metal organic framework (Cu-BTC) compounds

2014 ◽  
Vol 30 (1) ◽  
pp. 2-13 ◽  
Author(s):  
W. Wong-Ng ◽  
J.A. Kaduk ◽  
D.L. Siderius ◽  
A.L. Allen ◽  
L. Espinal ◽  
...  
Keyword(s):  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Powder Diffraction ◽  
Small Angle ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Organic ◽  
Diffraction Patterns ◽  
Organic Framework

Cu-paddle-wheel-based Cu3(BTC)2 (nicknamed Cu-BTC, where BTC ≡ benzene 1,3,5-tricarboxylate) is a metal organic framework (MOF) compound that adopts a zeolite-like topology. We have determined the pore-size distribution using the Gelb and Gubbins technique, the microstructure using small-angle neutron scattering and (ultra) small-angle X-ray scattering (USAXS\SAXS) techniques, and X-ray powder diffraction reference patterns for both dehydrated d-Cu-BTC [Cu3(C9H3O6)2] and hydrated h-Cu-BTC [Cu3(C9H3O6)2(H2O)6.96] using the Rietveld refinement technique. Both samples were confirmed to be cubic Fm$\bar 3$m (no. 225), with lattice parameters of a = 26.279 19(3) Å, V = 18 148.31(6) Å3 for d-Cu-BTC, and a = 26.3103(11) Å, and V = 18 213(2) Å3 for h-Cu-BTC. The structure of d-Cu-BTC contains three main pores of which the diameters are approximately, in decreasing order, 12.6, 10.6, and 5.0 Å. The free volume for d-Cu-BTC is approximately (71.85 ± 0.05)% of the total volume and is reduced to approximately (61.33 ± 0.03)% for the h-Cu-BTC structure. The d-Cu-BTC phase undergoes microstructural changes when exposed to moisture in air. The reference X-ray powder patterns for these two materials have been determined for inclusion in the Powder Diffraction File.

Barium Carboxylate Metal-Organic Framework - Synthesis, X-ray Crystal Structure, Photoluminescence and Catalytic Study

2012 ◽  
Vol 2012 (30) ◽  
pp. 4914-4920 ◽  
Author(s):  
Tanmoy Maity ◽  
Debraj Saha ◽  
Soma Das ◽  
Subratanath Koner
Keyword(s):  
Crystal Structure ◽  
Metal Organic Framework ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

Design, Synthesis, and X-Ray Crystal Structure of a Fullerene-Linked Metal-Organic Framework

2013 ◽  
Vol 126 (1) ◽  
pp. 164-167 ◽  
Author(s):  
Ping Peng ◽  
Fang-Fang Li ◽  
Venkata S. Pavan K. Neti ◽  
Alejandro J. Metta-Magana ◽  
Luis Echegoyen
Keyword(s):  
Crystal Structure ◽  
Metal Organic Framework ◽  
Design Synthesis ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework
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