Synthesis and Characterization of Linear and Square-Planar Nickel Complexes with Primary Amido Ligands

2008 ◽  
Vol 47 (9) ◽  
pp. 3468-3470 ◽  
Author(s):  
Jianfeng Li ◽  
Haibin Song ◽  
Chunming Cui ◽  
Jin-Pei Cheng
2021 ◽  
Author(s):  
Wenjing Yang ◽  
Yanhong Dong ◽  
Hongjian Sun ◽  
Xiaoyan Li

The synthesis and characterization of Fe, Co and Ni complexes supported by silylene ligands in recent ten years are summarized. Due to the decrease of electron cloud density on Si...


2013 ◽  
Vol 10 (3) ◽  
pp. 650-657
Author(s):  
Baghdad Science Journal

This research involves the preparation of new ligands 1,1,2,2- tetrakis (sodium acetate thio)ethylene(L1) and 1,1,2- tris(sodiumacetatethio) ethylene(L2), through the reaction of disodium thioglycolate) with tetra chloro ethylene or tri chloro ethylene in (1:4) or (1:3) moler ratio . Homodinucliar complexes of general formlu [M2(L1)] and [M2(L2)ClH2O] , when M= Co(II), Ni(II), Cu (II) and Zn(II) also mono nuclear complexes of general formula [M(L2)] . The prepared complexes were characterized using spectral method (UV/Visible/ IR) , metal content analysis , magnetic and atomic measurements . The spectral and magnetic measurement indicats that some complexes have tetrahedral or square planar complexes environtment .


1995 ◽  
Vol 14 (7) ◽  
pp. 3418-3422 ◽  
Author(s):  
Franco Morandini ◽  
Giuseppe Pilloni ◽  
Giambattista Consiglio ◽  
Antonio Mezzetti

2018 ◽  
Vol 47 (46) ◽  
pp. 16789-16797 ◽  
Author(s):  
Etienne A. LaPierre ◽  
Warren E. Piers ◽  
Chris Gendy

A rigidified PCalkylP ligand allowed for the synthesis and characterization of cationic and radical PCCarbeneP nickel complexes in which the carbene anchor of the pincer framework is electrophilic rather than nucleophilic.


2018 ◽  
Vol 37 (21) ◽  
pp. 3687-3697 ◽  
Author(s):  
Stephanie Felten ◽  
Sarah F. Marshall ◽  
Alisa J. Groom ◽  
Ryan T. Vanderlinden ◽  
Ryan M. Stolley ◽  
...  

2016 ◽  
Vol 15 (2) ◽  
pp. 17-32
Author(s):  
Rita Bhattacharjee

A series of palladium(II) halo complexes of the types[PdX2L2].nH2O {n = 0, X = Cl, L = L4and L6; X = Br, L = L3,L4, L5 and L6; n = 2, X = Cl, L = L3and L7, X = Br, L = L1};Pd2X4L2 {X = Cl, Br, L = L2 and L8} and Pd2X4L3 [X = Cl, L= L1; X = Br, L = L7] were prepared where L is 6-R-5,6-dihydrobenzoimidazo quinazoline (R-Diq; where R =phenyl: L1/furyl: L2/thiophenyl: L3/o- or phydroxyphenyl: L4, L5/o- or p-chlorophenyl: L6,L7/dimethylaminophenyl: L8and characterized byelemental analyses, molar conductivity measurements,TGA, infrared, electronic, NMR and mass spectraltechniques. Based on these studies, monomeric/dimericstructure with a square planar geometry around the metalion was proposed for these complexes. Anti-microbialactivity for some of the synthesized complexes wereinvestigated.Keywords: dihydrobenzoimidazoquinazoline, palladium(II),thermal analysis, mass spectra, biological activity.


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