Synthesis and Characterization of Cationic Square-Planar Iridium(I) Complexes Containing Chiral Diphosphines

1995 ◽  
Vol 14 (7) ◽  
pp. 3418-3422 ◽  
Author(s):  
Franco Morandini ◽  
Giuseppe Pilloni ◽  
Giambattista Consiglio ◽  
Antonio Mezzetti
Keyword(s):  
Synthesis And Characterization ◽  
Square Planar

scholarly journals Synthesis and characterization of new complexes of Co+2 , Ni+2 , Cu+2 and Zn+2 with (Sodium acetate thio ) ethylene ligands

2013 ◽  
Vol 10 (3) ◽  
pp. 650-657
Author(s):  
Baghdad Science Journal
Keyword(s):  
Content Analysis ◽  
General Formula ◽  
Metal Content ◽  
Sodium Acetate ◽  
Magnetic Measurement ◽  
Synthesis And Characterization ◽  
Square Planar ◽  
Square Planar Complexes ◽  
Uv Visible

This research involves the preparation of new ligands 1,1,2,2- tetrakis (sodium acetate thio)ethylene(L1) and 1,1,2- tris(sodiumacetatethio) ethylene(L2), through the reaction of disodium thioglycolate) with tetra chloro ethylene or tri chloro ethylene in (1:4) or (1:3) moler ratio . Homodinucliar complexes of general formlu [M2(L1)] and [M2(L2)ClH2O] , when M= Co(II), Ni(II), Cu (II) and Zn(II) also mono nuclear complexes of general formula [M(L2)] . The prepared complexes were characterized using spectral method (UV/Visible/ IR) , metal content analysis , magnetic and atomic measurements . The spectral and magnetic measurement indicats that some complexes have tetrahedral or square planar complexes environtment .

Synthesis and characterization of a new 4-styrylpyridine based square planar copper(II) complex: exploration of phenoxazinone synthase-mimicking activity and DFT study

2019 ◽  
Vol 72 (14) ◽  
pp. 2362-2375 ◽  
Author(s):  
Akhtaruz Zaman ◽  
Samim Khan ◽  
Basudeb Dutta ◽  
Sobhy M. Yakout ◽  
Shebl S. Ibrahim ◽  
...  
Keyword(s):  
Dft Study ◽  
Synthesis And Characterization ◽  
Phenoxazinone Synthase ◽  
Square Planar

Synthesis and Characterization of Palladium(II) Complexes with Substituted Dihydrobenzoimidazoquinazoline Derivatives

2016 ◽  
Vol 15 (2) ◽  
pp. 17-32
Author(s):  
Rita Bhattacharjee
Keyword(s):  
Thermal Analysis ◽  
Biological Activity ◽  
Mass Spectra ◽  
Molar Conductivity ◽  
Synthesis And Characterization ◽  
Planar Geometry ◽  
Conductivity Measurements ◽  
Square Planar

A series of palladium(II) halo complexes of the types[PdX2L2].nH2O {n = 0, X = Cl, L = L4and L6; X = Br, L = L3,L4, L5 and L6; n = 2, X = Cl, L = L3and L7, X = Br, L = L1};Pd2X4L2 {X = Cl, Br, L = L2 and L8} and Pd2X4L3 [X = Cl, L= L1; X = Br, L = L7] were prepared where L is 6-R-5,6-dihydrobenzoimidazo quinazoline (R-Diq; where R =phenyl: L1/furyl: L2/thiophenyl: L3/o- or phydroxyphenyl: L4, L5/o- or p-chlorophenyl: L6,L7/dimethylaminophenyl: L8and characterized byelemental analyses, molar conductivity measurements,TGA, infrared, electronic, NMR and mass spectraltechniques. Based on these studies, monomeric/dimericstructure with a square planar geometry around the metalion was proposed for these complexes. Anti-microbialactivity for some of the synthesized complexes wereinvestigated.Keywords: dihydrobenzoimidazoquinazoline, palladium(II),thermal analysis, mass spectra, biological activity.

Synthesis and Characterization of a Novel Tantalum Chalcogen-Rich Molecular Cluster with Square Planar Metal Core

2004 ◽  
Vol 43 (25) ◽  
pp. 7966-7968 ◽  
Author(s):  
Maxim N. Sokolov ◽  
Artyom L. Gushchin ◽  
Alexandr V. Virovets ◽  
Eugenia V. Peresypkina ◽  
Svetlana G. Kozlova ◽  
...  
Keyword(s):  
Molecular Cluster ◽  
Synthesis And Characterization ◽  
Metal Core ◽  
Square Planar

Synthesis and Characterization of a New Family of Square-Planar Nickel(II) Carbonyl Derivatives

2002 ◽  
Vol 8 (21) ◽  
pp. 4925-4934 ◽  
Author(s):  
Juan Forniés ◽  
Antonio Martín ◽  
L. Francisco Martín ◽  
Babil Menjón ◽  
Heather A. Kalamarides ◽  
...  
Keyword(s):  
Synthesis And Characterization ◽  
Carbonyl Derivatives ◽  
New Family ◽  
Square Planar

Synthesis and Characterization of Linear and Square-Planar Nickel Complexes with Primary Amido Ligands

2008 ◽  
Vol 47 (9) ◽  
pp. 3468-3470 ◽  
Author(s):  
Jianfeng Li ◽  
Haibin Song ◽  
Chunming Cui ◽  
Jin-Pei Cheng
Keyword(s):  
Nickel Complexes ◽  
Synthesis And Characterization ◽  
Amido Ligands ◽  
Square Planar

Synthesis and Characterization of Palladium(II) Complexes with Substituted Dihydrobenzoimidazo Quinazoline Derivatives

2017 ◽  
Vol 13 (2) ◽  
pp. 1-15
Author(s):  
Rita Bhattacharjee Virupaiah Gayathri
Keyword(s):  
Metal Ion ◽  
Synthesis And Characterization ◽  
Planar Geometry ◽  
Conductivity Measurements ◽  
Spectral Techniques ◽  
Mass Spectral ◽  
Square Planar ◽  
Elemental Analyses ◽  
Quinazoline Derivatives

A series of palladium(II) halo complexes of the types [PdX 2 L 2 ].nH 2 O {n = 0, X = Cl, L = L 2 , L 4 and L 5 ; X = Br, L = L 2 ; n = 1, X = Cl, L = L 1 and L 3 } and Pd 2 X 4 L 3 [X = Br, L = L 1 , L 3 , L 4   and L 5 ] were prepared where L is 6-R-5,6- dihydrobenzoimidazo quinazoline (R-Diq; where R = ethyl: L 1 / n or i-propyl: L 2 , L 3 / n or i-butyl: L 4 , L 5 ) and characterized by elemental analyses, conductivity measurements, TGA, infrared, electronic, NMR and mass spectral techniques. Based    on these studies monomeric/dimeric structure with a square planar geometry around the metal ion was proposed for all the complexes. Some of the complexes were investigated for anti-microbial activity.

Synthesis and characterization of a family of M2+ complexes supported by a trianionic ONO3− pincer-type ligand: towards the stabilization of high-spin square-planar complexes

2015 ◽  
Vol 44 (46) ◽  
pp. 20207-20215 ◽  
Author(s):  
M. E. Pascualini ◽  
S. A. Stoian ◽  
A. Ozarowski ◽  
N. V. Di Russo ◽  
A. E. Thuijs ◽  
...  
Keyword(s):  
High Spin ◽  
Synthesis And Characterization ◽  
Square Planar ◽  
Square Planar Complexes

A trianionic pincer-type ligand stabilizes rare Fe(ii) and Co(ii) high spin, square-planar complexes.

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