Fundamentals of the Wet-Process Phosphoric Acid Production. 1. Kinetics and Mechanism of the Phosphate Rock Dissolution

1996 ◽  
Vol 35 (11) ◽  
pp. 4328-4335 ◽  
Author(s):  
Sergey V. Dorozhkin
2000 ◽  
Vol 88 (9-11) ◽  
Author(s):  
H.T. Fukuma ◽  
E.A.N. Fernandes ◽  
A.L. Quinelato

A high-uranium phosphate rock from the Itataia deposit, located in the state of Ceará, Brazil, was milled in a pilot plant for wet-process phosphoric acid production. Further processing with solvent extraction (DEHPA/TOPO) was used aiming to recover uranium from the phosphoric acid. The distribution of natural radionuclides with long physical half-life of the


2012 ◽  
Vol 14 (2) ◽  
pp. 80-87 ◽  
Author(s):  
Barbara Grzmil ◽  
Bogumił Kic ◽  
Olga Żurek ◽  
Konrad Kubiak

Studies on the transformation of calcium sulphate dihydrate to hemihydrate in the wet process phosphoric acid production The influence of the process temperature from 85°C to 95°C, the content of phosphates and sulphates in the wet process phosphoric acid (about 22-36 wt% P2O5 and about 2-9 wt% SO42-) and the addition of αCaSO4·0.5H2O crystallization nuclei (from 10% to 50% in relation to CaSO4·2H2O) on the transformation of calcium sulphate dihydrate to hemihydrate has been determined. The wet process phosphoric acid and phosphogypsum from the industrial plant was utilized. They were produced by reacting sulphuric acid with phosphate rock (Tunisia) in the DH-process. The X-ray diffraction analysis was used to determine the phase composition and fractions of various forms of calcium sulphates in the samples and the degree of conversion of CaSO4·2H2O to αCaSO4·0.5H2O and CaSO4. It was found that the transformation of CaSO4·2H2O to αCaSO4·0.5H2O should be carried out in the presence of αCaSO4·0.5H2O crystallization nuclei as an additive (in the amount of 20% in relation to CaSO4·2H2O), at temperatures 90±2°C, in the wet process phosphoric acid containing the sulphates and phosphates in the range of 4±1 wt% and 27±1 wt%, respectively.


2017 ◽  
Vol 34 (3) ◽  
pp. 146-153 ◽  
Author(s):  
H. Liang ◽  
P. Zhang ◽  
Z. Jin ◽  
D. DePaoli

Author(s):  
Guangya Zheng ◽  
Jupei Xia ◽  
Zhengjie Chen

: China primarily contains medium and low-grade phosphorus ores that are used to produce phosphoric acid. Here, we provide an overview of phosphoric acid production processes, including wet, thermal, and kiln methods, as well as the fundamental principles, major equipment, and technological aspects of each process. Progress in the kiln method using lowgrade phosphate rock is described, which involves the KPA and CDK processes. The literature shows that the addition of admixtures adds great competitiveness to kiln phosphate production methods and has considerable development prospects.


2018 ◽  
Vol 57 (20) ◽  
pp. 6968-6979
Author(s):  
Hang Ma ◽  
Xiao Feng ◽  
Chun Deng

2000 ◽  
Vol 35 (3) ◽  
pp. 395-410 ◽  
Author(s):  
H. EL-SHALL ◽  
E. A. ABDEL-AAL ◽  
B. M. MOUDGIL

1992 ◽  
Vol 4 (1) ◽  
pp. 33-44 ◽  
Author(s):  
T.F. Al-Fariss ◽  
H.O. Ozbelge ◽  
F.A. Abdel Aleem ◽  
S.M. Abdulrazik

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