Nonlinear Raman spectroscopy of ground-state intermolecular vibrations in benzene complexes

1993 ◽  
Vol 97 (19) ◽  
pp. 4882-4886 ◽  
Author(s):  
Vincent A. Venturo ◽  
Peter M. Felker
Keyword(s):  
Raman Spectroscopy ◽  
Ground State ◽  
Intermolecular Vibrations

Intermolecular vibrations of naphthalene trimer by ionization-detected stimulated Raman spectroscopy

1999 ◽  
Vol 110 (23) ◽  
pp. 11264-11276 ◽  
Author(s):  
Wousik Kim ◽  
Mark W. Schaeffer ◽  
Soohyun Lee ◽  
James S. Chung ◽  
Peter M. Felker
Keyword(s):  
Raman Spectroscopy ◽  
Intermolecular Vibrations ◽  
Stimulated Raman

HIGH RESOLUTION RAMAN SPECTROSCOPY OF GASES: IX. SPECTRA OF H2, HD, AND D2

1957 ◽  
Vol 35 (6) ◽  
pp. 730-741 ◽  
Author(s):  
B. P. Stoicheff
Keyword(s):  
Raman Spectroscopy ◽  
High Resolution ◽  
Power Series ◽  
Infrared Spectra ◽  
Ground State ◽  
Power Series Expansion ◽  
Experimental Accuracy ◽  
Vibrational Bands ◽  
Complete Set ◽  
Electronic Ground

The pure rotational lines and the Q branch lines of the 1–0 vibrational bands of H2, HD, and D2 have been photographed with a 21 ft. grating spectrograph. From these spectra, a complete set of constants for the ν = 0 and 1 levels of all three molecules have been determined. When these constants are combined with Herzberg's results of the forbidden infrared spectra of H2 and HD they lead to improved values of the electronic ground state constants of H2 and HD. The leading terms in the Dunham power series expansion of the potential are calculated for H2 and HD and are found to be mutually consistent. The isotopic relations are obeyed within experimental accuracy, and the small constants De, Be, and He, are in agreement with values given by theoretical formulae.

HIGH RESOLUTION RAMAN SPECTROSCOPY OF GASES: XII. ROTATIONAL SPECTRA OF C2H4 AND C2D4 AND THE STRUCTURE OF THE ETHYLENE MOLECULE

1959 ◽  
Vol 37 (6) ◽  
pp. 703-721 ◽  
Author(s):  
J. M. Dowling ◽  
B. P. Stoicheff
Keyword(s):  
Raman Spectroscopy ◽  
High Resolution ◽  
Electron Diffraction ◽  
Ground State ◽  
Structural Parameters ◽  
Electron Diffraction Data ◽  
Rotational Constants ◽  
Ethylene Molecule ◽  
Rotational Spectra ◽  
Asymmetric Top

The pure rotational Raman spectra of C2H4 and C2D4 were photographed in the second order of a 21-ft grating. The resolution achieved was such that several lines due to single transitions were observed (and identified) in the spectra of both molecules. An analysis of these lines based on the non-rigid asymmetric top yielded the following rotational constants for the ground states:[Formula: see text]The structural parameters obtained from these constants are r0(C=C) = 1.339 ± 0.002 Å, r0(C—H) = 1.086 ± 0.003 Å, and [Formula: see text]. These values are in agreement with the recent preliminary results of the electron diffraction data. There is also agreement between the above values and those obtained from a recent study of the rotation–vibration spectra of C2H4 and C2D4, although the agreement between the ground state rotational constants is not as satisfactory.

Nonlinear Raman spectroscopy of intermolecular vibrations in benzene-(water)n clusters

1995 ◽  
Vol 241 (5-6) ◽  
pp. 603-610 ◽  
Author(s):  
Patrick M. Maxton ◽  
Mark W. Schaeffer ◽  
Peter M. Felker
Keyword(s):  
Raman Spectroscopy ◽  
Intermolecular Vibrations
Sign in / Sign up

Export Citation Format

Share Document