A kinetic study of the gas phase formation and decomposition reactions of nitrous acid

1977 ◽  
Vol 81 (18) ◽  
pp. 1701-1706 ◽  
Author(s):  
E. W. Kaiser ◽  
C. H. Wu
Keyword(s):  
Kinetic Study ◽  
Gas Phase ◽  
Phase Formation ◽  
Nitrous Acid ◽  
Decomposition Reactions

ChemInform Abstract: A KINETIC STUDY OF THE GAS PHASE FORMATION AND DECOMPOSITION REACTIONS OF NITROUS ACID

1977 ◽  
Vol 8 (50) ◽  
pp. no-no
Author(s):  
E. W. KAISER ◽  
C. H. WU
Keyword(s):  
Kinetic Study ◽  
Gas Phase ◽  
Phase Formation ◽  
Nitrous Acid ◽  
Decomposition Reactions

Mechanical and kinetic study on gas-phase formation of dinitro-naphthalene from 1- and 2-nitronaphthalene

Chemosphere ◽  
2016 ◽  
Vol 156 ◽  
pp. 101-110 ◽  
Author(s):  
Zixiao Huang ◽  
Qingzhu Zhang ◽  
Wenxing Wang
Keyword(s):  
Kinetic Study ◽  
Gas Phase ◽  
Phase Formation

On the trustability of semi-empirical methods to the calculation of gas phase formation enthalpies of inorganic compounds containing heavy metals: tin borates

2017 ◽  
Author(s):  
Robson de Farias
Keyword(s):  
Heavy Metals ◽  
Gas Phase ◽  
Phase Formation ◽  
Inorganic Compounds ◽  
Formation Enthalpy ◽  
Computational Time ◽  
Gas Formation ◽  
Formation Enthalpies ◽  
Knudsen Effusion Mass Spectrometry ◽  
Semi Empirical

<p>In the present work, are calculated the gas formation enthalpies (SE; PM3 and PM6) for tin borates: SnB<sub>2</sub>O<sub>4</sub><sup> </sup>and Sn<sub>2</sub>B<sub>2</sub>O<sub>5</sub>. The calculated values are compared with experimental ones, obtained by Knudsen effusion mass spectrometry [3]. It is shown that SE methods, besides their lower computational time consuming can, indeed, provide reliable gas phase formation enthalpy values for inorganic compounds containing heavy metals.</p>

Reesterification of ethyl acetate by propanol catalysed by glycidyl methacrylate copolymers containing sulphonic acid groups

1981 ◽  
Vol 46 (8) ◽  
pp. 1941-1946 ◽  
Author(s):  
Karel Setínek
Keyword(s):  
Liquid Phase ◽  
Ethyl Acetate ◽  
Kinetic Study ◽  
Gas Phase ◽  
Nonlinear Regression ◽  
Kinetic Data ◽  
Glycidyl Methacrylate ◽  
Kinetic Equations ◽  
Methacrylate Copolymers ◽  
Styrene Divinylbenzene

A series of differently crosslinked macroporous 2,3-epoxypropyl methacrylate-ethylenedimethacrylate copolymers with chemically bonded propylsulphonic acid groups were used as catalysts for the kinetic study of reesterification of ethyl acetate by n-propanol in the liquid phase at 52 °C and in the gas phase at 90 °C. Analysis of kinetic data by the method of nonlinear regression for a series of equations of the Langmuir-Hinshelwood type showed that kinetic equations which describe best the course of the reaction are the same as for the earlier studied sulphonated macroporous styrene-divinylbenzene copolymers. Compared types of catalysts differ, however, in the dependence of their activity on the degree of crosslinking of the copolymer used.

An homogeneous growth model of gallium arsenide epitaxial layers from the gas phase

1989 ◽  
Vol 54 (11) ◽  
pp. 2933-2950
Author(s):  
Emerich Erdös ◽  
Petr Voňka ◽  
Josef Stejskal ◽  
Přemysl Klíma
Keyword(s):  
Experimental Data ◽  
Gallium Arsenide ◽  
Kinetic Study ◽  
Gas Phase ◽  
Growth Model ◽  
Epitaxial Layers ◽  
Inhomogeneous Model ◽  
Homogeneous Models ◽  
Active Centres

This paper represents a continuation and ending of the kinetic study of the gallium arsenide formation, where a so-called inhomogeneous model is proposed and quantitatively formulated in five variants, in which two kinds of active centres appear. This model is compared both with the experimental data and with the previous sequence of homogeneous models.

scholarly journals Gas-Phase Formation and Isomerization Reactions of Cyanoacetaldehyde, a Prebiotic Molecule of Astrochemical Interest

2021 ◽  
Author(s):  
Bernardo Ballotta ◽  
Surajit Nandi ◽  
Vincenzo Barone ◽  
Sergio Rampino
Keyword(s):  
Gas Phase ◽  
Phase Formation ◽  
Prebiotic Molecule

Kinetic Study of Gas-Phase Reactions of Pyruvic Acid with HO2

2021 ◽  
Author(s):  
Jonathan R. Church ◽  
Veronica Vaida ◽  
Rex T. Skodje
Keyword(s):  
Kinetic Study ◽  
Gas Phase ◽  
Pyruvic Acid ◽  
Gas Phase Reactions

Gas-Phase Formation of the Gomberg-Bachmann Magnesium Ketyl

2008 ◽  
Vol 47 (47) ◽  
pp. 9118-9121 ◽  
Author(s):  
Charlene C. L. Thum ◽  
George N. Khairallah ◽  
Richard A. J. O'Hair
Keyword(s):  
Gas Phase ◽  
Phase Formation

The kinetics of the gas phase decomposition reactions of the hexafluoro-t-butoxy radical

1983 ◽  
Vol 15 (3) ◽  
pp. 293-303 ◽  
Author(s):  
Roger M. Drew ◽  
J. Alistair Kerr
Keyword(s):  
Gas Phase ◽  
Phase Decomposition ◽  
Decomposition Reactions ◽  
Butoxy Radical ◽  
Kinetics Of

Gas-Phase Formation of C5H6 Isomers via the Crossed Molecular Beam Reaction of the Methylidyne Radical (CH; X2Π) with 1,2-Butadiene (CH3CHCCH2; X1A′)

2021 ◽  
Author(s):  
Chao He ◽  
Anatoliy A. Nikolayev ◽  
Long Zhao ◽  
Aaron M. Thomas ◽  
Srinivas Doddipatla ◽  
...  
Keyword(s):  
Gas Phase ◽  
Phase Formation ◽  
Molecular Beam ◽  
Crossed Molecular Beam
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