On the trustability of semi-empirical methods to the calculation of gas phase formation enthalpies of inorganic compounds containing heavy metals: tin borates
Keyword(s):
<p>In the present work, are calculated the gas formation enthalpies (SE; PM3 and PM6) for tin borates: SnB<sub>2</sub>O<sub>4</sub><sup> </sup>and Sn<sub>2</sub>B<sub>2</sub>O<sub>5</sub>. The calculated values are compared with experimental ones, obtained by Knudsen effusion mass spectrometry [3]. It is shown that SE methods, besides their lower computational time consuming can, indeed, provide reliable gas phase formation enthalpy values for inorganic compounds containing heavy metals.</p>
2017 ◽
2008 ◽
Vol 854
(1-3)
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pp. 18-25
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2017 ◽
Vol 56
(3)
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pp. 1386-1401
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2014 ◽
Vol 14
(17)
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pp. 9233-9247
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2008 ◽
Vol 47
(47)
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pp. 9118-9121
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