Partial molal volumes of tetraphenylarsonium tetraphenylboron in water at infinite dilution. Ionic partial molal volumes

1971 ◽  
Vol 75 (2) ◽  
pp. 280-282 ◽  
Author(s):  
Frank J. Millero
Keyword(s):  
Infinite Dilution ◽  
Partial Molal Volumes ◽  
Molal Volumes

THE PARTIAL MOLAL VOLUMES OF IONS IN AQUEOUS SOLUTION: I. DEPENDENCE ON CHARGE AND RADIUS

1956 ◽  
Vol 34 (9) ◽  
pp. 1209-1216 ◽  
Author(s):  
A. M. Couture ◽  
K. J. Laidler
Keyword(s):  
Ionic Crystal ◽  
Infinite Dilution ◽  
Hydrogen Ion ◽  
Empirical Equations ◽  
Density Data ◽  
A Value ◽  
Partial Molal Volumes ◽  
Solutions Of Electrolytes ◽  
Molal Volumes ◽  
Charge And Radius

The density data for aqueous solutions of electrolytes have been analyzed, and partial molal volumes at infinite dilution have been calculated. The values are shown to be additive, and a set of volumes for individual ions has been prepared, based arbitrarily on a value of zero for the hydrogen ion. It is shown that for a given value of the charge the volumes vary linearly with the cube of the ionic crystal radii, and for a given radius vary with the first power of the charge. In the case of cations the equation obeyed is[Formula: see text]while for anions[Formula: see text]If the volume of the hydrogen ion is taken as −6 ml. instead of zero the same equation is obeyed for both cations and anions, namely[Formula: see text]The empirical equations are discussed in terms of a simple model for ions in solution.

Partial molal volumes of some halobenzenes in carbon tetrachloride

1983 ◽  
Vol 61 (7) ◽  
pp. 1414-1416 ◽  
Author(s):  
Fereidoon Shahidi
Keyword(s):  
Carbon Tetrachloride ◽  
Infinite Dilution ◽  
Van Der Waals ◽  
Alkyl Halides ◽  
Substituted Benzenes ◽  
Halogen Atoms ◽  
Partial Molal Volumes ◽  
Molal Volumes

The partial molal volumes at infinite dilution [Formula: see text] for a number of halobenzenes are measured and related to their van der Waals volumes. Results indicate larger volume increments for halogen atoms in halobenzenes than those in alkyl halides. Possible explanations are forwarded. The effect of steric overcrowding in ortho-substituted benzenes on the [Formula: see text] values are evaluated.

Correspondling states correlations for liquid compressibility and partial molal volumes of gases at infinite dilution in liquids

AIChE Journal ◽  
1972 ◽  
Vol 18 (6) ◽  
pp. 1239-1243 ◽  
Author(s):  
S. W. Brelvi ◽  
J. P. O'Connell
Keyword(s):  
Infinite Dilution ◽  
Liquid Compressibility ◽  
Partial Molal Volumes ◽  
Molal Volumes

Partial Molal Volumes of Aqueous Ions

1957 ◽  
Vol 61 (10) ◽  
pp. 1426-1429 ◽  
Author(s):  
Loren G. Hepler
Keyword(s):  
Partial Molal Volumes ◽  
Aqueous Ions ◽  
Molal Volumes

Apparent and Partial Molal Volumes of Sodium Perchlorate and Perchloric Acid in Mixed Solutions1a

1950 ◽  
Vol 72 (11) ◽  
pp. 5292-5296 ◽  
Author(s):  
Henry E. Wirth ◽  
F. Nash Collier
Keyword(s):  
Perchloric Acid ◽  
Sodium Perchlorate ◽  
Partial Molal Volumes ◽  
Molal Volumes

Densities and partial molal volumes of water-ethylene glycol mixtures

1973 ◽  
Vol 18 (3) ◽  
pp. 309-311 ◽  
Author(s):  
Ashoka Ray ◽  
George Nemethy
Keyword(s):  
Ethylene Glycol ◽  
Partial Molal Volumes ◽  
Molal Volumes

Partial molal volumes of ions

1970 ◽  
Vol 66 ◽  
pp. 43 ◽  
Author(s):  
G. Curthoys ◽  
J. G. Mathieson
Keyword(s):  
Partial Molal Volumes ◽  
Molal Volumes
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