Effect of carbon tetrachloride upon the self-association of 1-octanol. Effect of solvent on hydrogen bond formation equilibriums. Comments

The solvation of benzimidazole, 4-azabenzimidazole, purine, adenine, uracil, thymine, and cytosine in water and methanol was determined by a combination of calorimetric and spectral analysis. Specific enthalpies have been assigned to each interaction site in the first solvation shell. Calculations, based on the enthalpies of hydrogen bond formation with water, and estimates for intermolecular hydrogen bond enthalpies, show that the self-association of purine and adenine in water through hydrogen bonded interactions is enthalpically possible.

Download Full-text

Studies in hydrogen bonding: the enthalpy of hydrogen bond formation of ethanol in carbon tetrachloride solutions

Journal of Molecular Structure ◽

10.1016/0022-2860(86)85026-8 ◽

1986 ◽

Vol 145 (3-4) ◽

pp. 219-224 ◽

Cited By ~ 2

Author(s):

George Brink ◽

Leslie Glasser

Keyword(s):

Hydrogen Bond ◽

Hydrogen Bonding ◽

Carbon Tetrachloride ◽

Bond Formation ◽

Hydrogen Bond Formation

Download Full-text

1070. Studies in hydrogen-bond formation. Part X. Complex-formation between a variety of organic solutes in carbon tetrachloride

Journal of the Chemical Society (Resumed) ◽

10.1039/jr9610005434 ◽

1961 ◽

pp. 5434 ◽

Cited By ~ 3

Author(s):

C. H. Giles ◽

R. B. McKay ◽

W. Good

Keyword(s):

Hydrogen Bond ◽

Carbon Tetrachloride ◽

Complex Formation ◽

Bond Formation ◽

Organic Solutes ◽

Hydrogen Bond Formation

Download Full-text

Vapochromism induced by intermolecular electron transfer coupled with hydrogen-bond formation in zinc dithiolene complex

Journal of Materials Chemistry C ◽

10.1039/d0tc04280c ◽

2020 ◽

Vol 8 (42) ◽

pp. 14939-14947

Author(s):

So Yokomori ◽

Shun Dekura ◽

Tomoko Fujino ◽

Mitsuaki Kawamura ◽

Taisuke Ozaki ◽

...

Keyword(s):

Hydrogen Bond ◽

Electron Transfer ◽

Bond Formation ◽

Intermolecular Electron Transfer ◽

Hydrogen Bond Formation ◽

Complex Crystal

A novel vapochromic mechanism by intermolecular electron transfer coupled with hydrogen-bond formation was realized in a zinc dithiolene complex crystal.

Download Full-text

Diverse mechanisms of carbon-hydrogen bond formation through binuclear reductive elimination reactions

Journal of the American Chemical Society ◽

10.1021/ja00366a044 ◽

1982 ◽

Vol 104 (2) ◽

pp. 619-621 ◽

Cited By ~ 31

Author(s):

Mario J. Nappa ◽

Roberto Santi ◽

Steven P. Diefenbach ◽

Jack Halpern

Keyword(s):

Hydrogen Bond ◽

Bond Formation ◽

Reductive Elimination ◽

Hydrogen Bond Formation ◽

Elimination Reactions

Download Full-text

Theoretical analysis of the (HNO)2, (HNO···HNS), and (HNS)2 dimers — A case of red and blue shifts of N–H stretching frequency

Canadian Journal of Chemistry ◽

10.1139/v10-048 ◽

2010 ◽

Vol 88 (8) ◽

pp. 849-857 ◽

Cited By ~ 2

Author(s):

Nguyen Tien Trung ◽

Tran Thanh Hue ◽

Minh Tho Nguyen

Keyword(s):

Hydrogen Bond ◽

Quantum Chemical ◽

Bond Formation ◽

Blue Shift ◽

Proton Donor ◽

Basis Sets ◽

Coupled Cluster ◽

Hydrogen Bond Formation ◽

Length Contraction ◽

Moller Plesset

The hydrogen-bonded interactions in the simple (HNZ)2 dimers, with Z = O and S, were investigated using quantum chemical calculations with the second-order Møller–Plesset perturbation (MP2), coupled-cluster with single, double (CCSD), and triple excitations (CCSD(T)) methods in conjunction with the 6-311++G(2d,2p), aug-cc-pVDZ, and aug-cc-pVTZ basis sets. Six-membered cyclic structures were found to be stable complexes for the dimers (HNO)2, (HNS)2, and (HNO–HNS). The pair (HNS)2 has the largest complexation energy (–11 kJ/mol), and (HNO)2 the smallest one (–9 kJ/mol). A bond length contraction and a frequency blue shift of the N–H bond simultaneously occur upon hydrogen bond formation of the N–H···S type, which has rarely been observed before. The stronger the intramolecular hyperconjugation and the lower the polarization of the X–H bond involved as proton donor in the hydrogen bond, the more predominant is the formation of a blue-shifting hydrogen bond.

Download Full-text