PHOTOCHEMICAL INTERCHANGE OF HALOGENS IN AROMATIC COMPOUNDS. II. TEMPERATURE DEPENDENCE OF SOME SUBSTITUENT EFFECTS

1962 ◽  
Vol 66 (11) ◽  
pp. 2118-2120 ◽  
Author(s):  
Barton Milligan ◽  
Ronald L. Bradow
Keyword(s):  
Temperature Dependence ◽  
Aromatic Compounds ◽  
Substituent Effects

NMR-spektroskopische Untersuchungen über zwischenmolekulare Wechselwirkungen bei Benzolderivaten und Pyrrol / NMR-Spectroscopic Investigation of the Intermolecular Reactions of Benzene Derivatives and Pyrrole

1969 ◽  
Vol 24 (11) ◽  
pp. 1365-1370 ◽  
Author(s):  
H.-H. Perkampus ◽  
U. Krüger ◽  
W. Krüger
Keyword(s):  
Dipole Moment ◽  
Temperature Dependence ◽  
Aromatic Compounds ◽  
Spectroscopic Investigation ◽  
Chemical Shifts ◽  
Benzene Derivatives ◽  
Intermolecular Reactions ◽  
Proton Chemical Shifts

The proton chemical shifts of aromatic compounds are strongly concentration dependent. Moreever, for molecules with a dipole moment a temperature dependence of the proton chemical shifts is observed. For hemellitone, p-methylanisole, o-chlortoluene, p-chlortoluene, pyrrole and N-methyl-pyrrole the enthalpies of a dipole-dipole association between -0,7 and -1,8 Kcal could be estimated by NMR measurements combined with the temperature dependence in the whole range of the molefraction (0 → 1).

Infrared spectra of aqueous sodium benzoates and salicylates in the carboxyl-stretching region: chelation in aqueous sodium salicylates

1969 ◽  
Vol 47 (24) ◽  
pp. 4577-4588 ◽  
Author(s):  
G. E. Dunn ◽  
R. S. McDonald
Keyword(s):  
Salicylic Acid ◽  
Carbon Tetrachloride ◽  
Infrared Spectra ◽  
Aromatic Compounds ◽  
Deuterium Oxide ◽  
Substituent Effects ◽  
Good Evidence ◽  
Frequency Region ◽  
Aqueous Sodium ◽  
Substituent Constants

Infrared spectra in the frequency region 1300–1760 cm−1 are reported for 41 substituted sodium benzoates and 10 substituted sodium salicylates in deuterium oxide solution, and for 9 substituted salicylic acids in chloroform and carbon tetrachloride solutions. Carboxylate stretching frequencies of benzoates and salicylates correlate poorly with substituent constants, but the asymmetric frequencies of benzoates and salicylates correlate well with each other, and the asymmetric frequencies of benzoates correlate well with the asymmetric frequencies of the corresponding nitrobenzenes. It is suggested that, among substituted aromatic compounds, group vibrations which couple with the ring vibrations may correlate well with similar vibrations of other groups, but not with coupled vibrations of different symmetry, uncoupled vibrations, or substituent constants. Chelation in chloroform solutions of salicylic acid dimers can be detected by its influence on substituent effects, but infrared spectra provide no good evidence for chelation in aqueous sodium salicylates.

Temperature dependence of the intensity of slowed-down fluorescence for aromatic compounds in n-paraffin matrices

2012 ◽  
Vol 55 (2) ◽  
pp. 236-239
Author(s):  
N. V. Zhdanova ◽  
M. I. Deryabin ◽  
V. V. Solodunov
Keyword(s):  
Temperature Dependence ◽  
Aromatic Compounds

Substituent Effects on the Luminescence of 2-Substituted 3-Methylquinoxalines in Poly (Vinyl Alcohol) Films*

1991 ◽  
Vol 46 (4) ◽  
pp. 304-306 ◽  
Author(s):  
Z. Gryczyński ◽  
A. Kawski
Keyword(s):  
Polyvinyl Alcohol ◽  
Temperature Dependence ◽  
Vinyl Alcohol ◽  
Substituent Effects ◽  
Quantum Yields ◽  
Poly Vinyl Alcohol ◽  
Band Position ◽  
Fluorescence And Phosphorescence ◽  
Polyvinyl Alcohol Films

Abstract The effect of 2-substitutions (NH2 . O, CH3O, CI. Br) in 3-methylquinoxalines on the fluorescence and phosphorescence band position and intensity at 293 K, and the temperature dependence of their fluorescence and phosphorescence quantum yields were investigated in polyvinyl alcohol) films

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